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Thermally conductive and form-stable phase change composite for building thermal management

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  • Wu, Minqiang
  • Li, Tingxian
  • He, Qifan
  • Du, Ruxue
  • Wang, Ruzhu

Abstract

Phase change materials (PCMs) have aroused tremendous interest in building thermal management (BTM) owing to their operational simplicity and comparable energy storage density. However, the application of PCM-based BTM is generally hindered by the bottlenecks of low thermal conductivity and liquid leakage. To solve this problem, a novel thermally conductive and form-stable phase change composite (PCC) is prepared by employing n-Octadecane (ODE) as PCM, olefin block copolymer (OBC) as supporting material, and expanded graphite (EG) as thermally conductive additives. The characterization results show that the as-synthesized PCCs exhibit good physicochemical compatibility. The introduction of EG enables PCC an enhanced and antistrophic thermal conductivity. The radial thermal conductivities of PCCs reach up to 3.8–20.6 W/m∙K with EG loading of 5–25 wt%. The thermogravimetric analyzer (TGA) and leakage-proof analysis indicate that the resultant PCCs have a good thermal stability and the combination of OBC and EG greatly alleviated the leakage problem. In addition, BTM test shows that the indoor temperature of the PCM room is more stable and the maximum temperature differences between PCM room and reference room are 2.5 °C and 3.6 °C during the heating and cooling processes. These results indicate that the as-synthesized ODE-OBC/EG composites have significant potential for BTM application.

Suggested Citation

  • Wu, Minqiang & Li, Tingxian & He, Qifan & Du, Ruxue & Wang, Ruzhu, 2022. "Thermally conductive and form-stable phase change composite for building thermal management," Energy, Elsevier, vol. 239(PA).
    • Handle: RePEc:eee:energy:v:239:y:2022:i:pa:s0360544221021861
    DOI: 10.1016/j.energy.2021.121938
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    Cited by:

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    2. Gencel, Osman & Subasi, Serkan & Ustaoglu, Abid & Sarı, Ahmet & Marasli, Muhammed & Hekimoğlu, Gökhan & Kam, Erol, 2022. "Development, characterization and thermo-regulative performance of microencapsulated phase change material included-glass fiber reinforced foam concrete as novel thermal energy effective-building mate," Energy, Elsevier, vol. 257(C).
    3. Yueliang Yu & Hongmei Qin & Shusen Ran & Jinhui Song & Wenlai Xia & Shan Wang & Chuanxi Xiong, 2023. "A Low-Density Polyethylene-Reinforced Ternary Phase-Change Composite with High Thermal Conductivity for Battery Thermal Management," Energies, MDPI, vol. 16(9), pages 1-13, April.
    4. Zhang, Pengfei & Wang, Yilin & Qiu, Yu & Yan, Hongjie & Wang, Zhaolong & Li, Qing, 2024. "Novel composite phase change materials supported by oriented carbon fibers for solar thermal energy conversion and storage," Applied Energy, Elsevier, vol. 358(C).
    5. Luo, Jie & Gu, Heng & Wang, Shuo & Wang, Hao & Zou, Deqiu, 2022. "A coupled power battery cooling system based on phase change material and its influencing factors," Applied Energy, Elsevier, vol. 326(C).
    6. Li, Jiyan & Long, Yong & Jing, Yanju & Zhang, Jiaqing & Du, Silu & Jiao, Rui & Sun, Hanxue & Zhu, Zhaoqi & Liang, Weidong & Li, An, 2024. "Superhydrophobic multi-shell hollow microsphere confined phase change materials for solar photothermal conversion and energy storage," Applied Energy, Elsevier, vol. 365(C).
    7. Sarı, Ahmet & Hekimoğlu, Gökhan & Karabayır, Yasemin & Sharma, R.K. & Arslanoğlu, Hasan & Gencel, Osman & Tyagi, V.V., 2022. "Capric-stearic acid mixture impregnated carbonized waste sugar beet pulp as leak-resistive composite phase change material with effective thermal conductivity and thermal energy storage performance," Energy, Elsevier, vol. 247(C).

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