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A novel process for CO2 capture from the flue gases to produce urea and ammonia

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  • Koohestanian, Esmaeil
  • Sadeghi, Jafar
  • Mohebbi-Kalhori, Davod
  • Shahraki, Farhad
  • Samimi, Abdolreza

Abstract

The paper addresses the production of urea from carbon dioxide and nitrogen in the flue gas of the power plants as an alternative to other proposed and suggested processes. The conventional separation process of CO2 from flue gases has been so far directed to the methanol synthesis, while nitrogen, as the main part of the combustion product, is ignored. Carelessness about and lack of use of this byproduct is led to the techno-economical failure of the process and cause environmental problems. In this research, to the best of our knowledge, for the first time, the synthesis of urea and ammonia from the combustion of oxy-fuel was investigated and the appropriate and green process was designed and proposed. To enhance economic justification, the process design was carried out using all three main components of the flue gas (CO2, N2, and H2O), along with efficiency increment of the combustion units. Considering of 2036 kg/hr oxy-fuel combustion products, direct removal of 1700 kg/hr CO2 from the carbon cycle and production of 2856 kg/hr molten urea is estimated, which the latter product worth about 3.5 × 106 US$/year.

Suggested Citation

  • Koohestanian, Esmaeil & Sadeghi, Jafar & Mohebbi-Kalhori, Davod & Shahraki, Farhad & Samimi, Abdolreza, 2018. "A novel process for CO2 capture from the flue gases to produce urea and ammonia," Energy, Elsevier, vol. 144(C), pages 279-285.
    • Handle: RePEc:eee:energy:v:144:y:2018:i:c:p:279-285
    DOI: 10.1016/j.energy.2017.12.034
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    References listed on IDEAS

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    1. Koohestanian, Esmaeil & Samimi, Abdolreza & Mohebbi-Kalhori, Davod & Sadeghi, Jafar, 2017. "Sensitivity analysis and multi-objective optimization of CO2CPU process using response surface methodology," Energy, Elsevier, vol. 122(C), pages 570-578.
    2. Jin, Bo & Zhao, Haibo & Zheng, Chuguang, 2015. "Optimization and control for CO2 compression and purification unit in oxy-combustion power plants," Energy, Elsevier, vol. 83(C), pages 416-430.
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    Cited by:

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    3. Meng, Wenliang & Wang, Dongliang & Zhou, Huairong & Yang, Yong & Li, Hongwei & Liao, Zuwei & Yang, Siyu & Hong, Xiaodong & Li, Guixian, 2023. "Carbon dioxide from oxy-fuel coal-fired power plant integrated green ammonia for urea synthesis: Process modeling, system analysis, and techno-economic evaluation," Energy, Elsevier, vol. 278(C).
    4. Zhang, Zhien & Pan, Shu-Yuan & Li, Hao & Cai, Jianchao & Olabi, Abdul Ghani & Anthony, Edward John & Manovic, Vasilije, 2020. "Recent advances in carbon dioxide utilization," Renewable and Sustainable Energy Reviews, Elsevier, vol. 125(C).
    5. Adnan, Muflih A. & Hossain, Mohammad M. & Kibria, Md Golam, 2020. "Biomass upgrading to high-value chemicals via gasification and electrolysis: A thermodynamic analysis," Renewable Energy, Elsevier, vol. 162(C), pages 1367-1379.
    6. McLaughlin, Hope & Littlefield, Anna A. & Menefee, Maia & Kinzer, Austin & Hull, Tobias & Sovacool, Benjamin K. & Bazilian, Morgan D. & Kim, Jinsoo & Griffiths, Steven, 2023. "Carbon capture utilization and storage in review: Sociotechnical implications for a carbon reliant world," Renewable and Sustainable Energy Reviews, Elsevier, vol. 177(C).
    7. Yaumi, A.L. & Bakar, M.Z. Abu & Hameed, B.H., 2018. "Melamine-nitrogenated mesoporous activated carbon derived from rice husk for carbon dioxide adsorption in fixed-bed," Energy, Elsevier, vol. 155(C), pages 46-55.
    8. Wang, Honglin & Liu, Yanrong & Laaksonen, Aatto & Krook-Riekkola, Anna & Yang, Zhuhong & Lu, Xiaohua & Ji, Xiaoyan, 2020. "Carbon recycling – An immense resource and key to a smart climate engineering: A survey of technologies, cost and impurity impact," Renewable and Sustainable Energy Reviews, Elsevier, vol. 131(C).
    9. He, Minyu & Teng, Liumei & Gao, Yuxiang & Rohani, Sohrab & Ren, Shan & Li, Jiangling & Yang, Jian & Liu, Qingcai & Liu, Weizao, 2022. "Simultaneous CO2 mineral sequestration and rutile beneficiation by using titanium-bearing blast furnace slag: Process description and optimization," Energy, Elsevier, vol. 248(C).
    10. Alirza Orujov & Kipp Coddington & Saman A. Aryana, 2023. "A Review of CCUS in the Context of Foams, Regulatory Frameworks and Monitoring," Energies, MDPI, vol. 16(7), pages 1-41, April.

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