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Carbon dioxide from oxy-fuel coal-fired power plant integrated green ammonia for urea synthesis: Process modeling, system analysis, and techno-economic evaluation

Author

Listed:
  • Meng, Wenliang
  • Wang, Dongliang
  • Zhou, Huairong
  • Yang, Yong
  • Li, Hongwei
  • Liao, Zuwei
  • Yang, Siyu
  • Hong, Xiaodong
  • Li, Guixian

Abstract

A high proportion of renewable energy integration will be one of the significant characteristics of future electric power grid, and power-to-NH3 technologies will become an important approach for inter-quarter long-term energy storage. Meanwhile, as an important method of peak regulation in power systems, coal-based power plant is necessary to implement CO2 capture. This study constructed a novel urea synthesis process based on renewable energy, including water electrolyzers, air separation, green ammonia, oxy-fuel combustion power plant, CO2 purification, and urea synthesis units. Coal- and natural gas-based urea synthesis processes were selected as the contrasting processes.The results showed that CO2 emissions from the novel process proposed in this work were 0.124–0.174 t CO2/t urea, which was much lower than that of the coal and natural gas-based urea processes (1.4 and 0.8 t CO2/t urea, respectively). In the current technical economy (with coal and natural gas prices of 450 CNY/t and 1.7 CNY/m3, respectively), the production cost of this new process was about 1.0–2.2 times higher than that of traditional processes. When the carbon tax values were 121 and 371 CNY/t, the total production costs of the natural gas- and coal-based urea process would exceed that of the new process, respectively. This study will provide a promising method for urea production based on renewable energy to realize CO2 utilization from coal-fired power plant.

Suggested Citation

  • Meng, Wenliang & Wang, Dongliang & Zhou, Huairong & Yang, Yong & Li, Hongwei & Liao, Zuwei & Yang, Siyu & Hong, Xiaodong & Li, Guixian, 2023. "Carbon dioxide from oxy-fuel coal-fired power plant integrated green ammonia for urea synthesis: Process modeling, system analysis, and techno-economic evaluation," Energy, Elsevier, vol. 278(C).
    • Handle: RePEc:eee:energy:v:278:y:2023:i:c:s0360544223009313
    DOI: 10.1016/j.energy.2023.127537
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