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Excellently balanced water-intercalation-type heat-storage oxide

Author

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  • Takuya Hatakeyama

    (Tohoku University, 2-1-1 Katahira, Aoba-ku
    Tohoku University 6-6-01 Aoba, Aramaki, Aoba-ku)

  • Norihiko L. Okamoto

    (Tohoku University, 2-1-1 Katahira, Aoba-ku)

  • Satoshi Otake

    (Rigaku Corporation, 3-9-12 Matsubara-cho)

  • Hiroaki Sato

    (Rigaku Corporation, 3-9-12 Matsubara-cho)

  • Hongyi Li

    (Tohoku University, 2-1-1 Katahira, Aoba-ku)

  • Tetsu Ichitsubo

    (Tohoku University, 2-1-1 Katahira, Aoba-ku)

Abstract

Importance of heat storage materials has recently been increasing. Although various types of heat storage materials have been reported to date, there are few well-balanced energy storage materials in terms of long lifetime, reversibility, energy density, reasonably fast charge/discharge capability, and treatability. Here we report an interesting discovery that a commonly known substance, birnessite-type layered manganese dioxide with crystal water (δ-type K0.33MnO2 ⋅ nH2O), exhibits a water-intercalation mechanism and can be an excellently balanced heat storage material, from the above views, that can be operated in a solid state with water as a working pair. The volumetric energy density exceeds 1000 MJ m−3 (at n ~ 0.5), which is close to the ideally maximum value and the best among phase-change materials. The driving force for the water intercalation is also validated by the ab initio calculations. The proposed mechanism would provide an optimal solution for a heat-storage strategy towards low-grade waste-heat applications.

Suggested Citation

  • Takuya Hatakeyama & Norihiko L. Okamoto & Satoshi Otake & Hiroaki Sato & Hongyi Li & Tetsu Ichitsubo, 2022. "Excellently balanced water-intercalation-type heat-storage oxide," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-28988-0
    DOI: 10.1038/s41467-022-28988-0
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