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Catalyst combination strategy for hydrogen production from methanol partial oxidation

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  • Chen, Wei-Hsin
  • Chen, Kuan-Hsiang
  • Lin, Bo-Jhih
  • Guo, Yu-Zhi

Abstract

Methanol is a promising feedstock for hydrogen production. This study experimentally investigates hydrogen production from the partial oxidation of methanol (POM) in sprays and dual-catalyst bed. Two different catalysts of h-BN-Pt/Al2O3 and h-BN-Pd/Al2O3 with low Pt and Pd contents (0.2 wt%) are utilized. The effects of preheating temperatures, O2-to-methanol molar (O2/C) ratios, and Pt/Pd ratios on POM are examined. POM can be triggered at room temperature when using the Pt catalyst. In contrast, POM can occur for a preheating temperature no less than 100 °C once the Pd catalyst is used. On account of the cold start of POM by the Pt catalyst, a dual-catalyst bed strategy is proposed where the Pt catalyst serves as the upper layer. In the dual-catalyst bed with the equivalent amounts of the two catalysts, the maximum H2 yield is 1.61 mol (mol methanol)−1 developing at O2/C = 0.6. Reducing the Pt catalyst amount does not obviously affect the POM performance where methanol conversion is close to 100% and the H2 yield is between 1.55 and 1.57 mol (mol methanol)−1. Accordingly, depending on the prices of Pt and Pd costs, economic and flexible operation of POM for hydrogen production can be achieved from the catalyst combination strategy.

Suggested Citation

  • Chen, Wei-Hsin & Chen, Kuan-Hsiang & Lin, Bo-Jhih & Guo, Yu-Zhi, 2020. "Catalyst combination strategy for hydrogen production from methanol partial oxidation," Energy, Elsevier, vol. 206(C).
  • Handle: RePEc:eee:energy:v:206:y:2020:i:c:s0360544220312871
    DOI: 10.1016/j.energy.2020.118180
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    References listed on IDEAS

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    1. Chen, Wei-Hsin & Shen, Chun-Ting & Lin, Bo-Jhih & Liu, Shih-Chun, 2015. "Hydrogen production from methanol partial oxidation over Pt/Al2O3 catalyst with low Pt content," Energy, Elsevier, vol. 88(C), pages 399-407.
    2. Chen, Wei-Hsin & Shen, Chun-Ting, 2016. "Partial oxidation of methanol over a Pt/Al2O3 catalyst enhanced by sprays," Energy, Elsevier, vol. 106(C), pages 1-12.
    3. Chen, Wei-Hsin & Guo, Yu-Zhi & Chen, Chih-Chun, 2018. "Methanol partial oxidation accompanied by heat recirculation in a Swiss-roll reactor," Applied Energy, Elsevier, vol. 232(C), pages 79-88.
    4. Chen, Wei-Hsin & Lin, Bo-Jhih, 2013. "Hydrogen and synthesis gas production from activated carbon and steam via reusing carbon dioxide," Applied Energy, Elsevier, vol. 101(C), pages 551-559.
    5. Chen, Wei-Hsin & Chen, Chia-Yang, 2020. "Water gas shift reaction for hydrogen production and carbon dioxide capture: A review," Applied Energy, Elsevier, vol. 258(C).
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    Cited by:

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    3. Byun, Manhee & Kim, Heehyang & Lee, Hyunjun & Lim, Dongjun & Lim, Hankwon, 2022. "Conceptual design for methanol steam reforming in serial packed-bed reactors and membrane filters: Economic and environmental perspectives," Energy, Elsevier, vol. 241(C).

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