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A standalone solar thermochemical water splitting hydrogen plant with high-temperature molten salt: Thermodynamic and economic analyses and multi-objective optimization

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  • Sadeghi, Shayan
  • Ghandehariun, Samane

Abstract

Alternative methods for clean production of hydrogen have been proposed recently. Some of these methods utilize water instead of hydrocarbons as the hydrogen source. The copper-chlorine (Cu–Cl) thermochemical cycle is one of the most promising methods that attracted the attention of numerous researchers and organizations in recent years. In this paper, the design and integration of a standalone solar power tower (SPT) system with LiNaK high-temperature carbonate molten salt with a four-step Cu–Cl cycle is investigated. The integrated system does not rely on external or auxiliary energy sources such as grid electricity or natural gas. The proposed system is investigated in terms of thermodynamic and economic analyses, and the system performance and hydrogen production cost are determined. For the base case, the thermal efficiencies of the Cu–Cl cycle, supercritical steam Rankine cycle, and overall system are 40.4%, 45.74%, and 28.77%, respectively. The hydrogen capacity of the system is 1530.4 kg/h, and the total capital investment is 811.04 million dollars. The levelized cost of hydrogen is estimated as $9.47/kg H2. Based on the multi-objective optimization results, the optimal system design has an overall thermal efficiency and levelized cost of hydrogen of 29.18% and $7.58/kg H2, respectively.

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  • Sadeghi, Shayan & Ghandehariun, Samane, 2022. "A standalone solar thermochemical water splitting hydrogen plant with high-temperature molten salt: Thermodynamic and economic analyses and multi-objective optimization," Energy, Elsevier, vol. 240(C).
    • Handle: RePEc:eee:energy:v:240:y:2022:i:c:s0360544221029728
    DOI: 10.1016/j.energy.2021.122723
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    References listed on IDEAS

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    1. Rosen, Marc A., 2010. "Advances in hydrogen production by thermochemical water decomposition: A review," Energy, Elsevier, vol. 35(2), pages 1068-1076.
    2. Xiaoru Zhuang & Xinhai Xu & Wenrui Liu & Wenfu Xu, 2019. "LCOE Analysis of Tower Concentrating Solar Power Plants Using Different Molten-Salts for Thermal Energy Storage in China," Energies, MDPI, vol. 12(7), pages 1-17, April.
    3. Yilmaz, Fatih & Selbaş, Reşat, 2017. "Thermodynamic performance assessment of solar based Sulfur-Iodine thermochemical cycle for hydrogen generation," Energy, Elsevier, vol. 140(P1), pages 520-529.
    4. Yadav, Deepak & Banerjee, Rangan, 2016. "A review of solar thermochemical processes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 54(C), pages 497-532.
    5. Ozbilen, Ahmet & Dincer, Ibrahim & Rosen, Marc A., 2014. "Development of new heat exchanger network designs for a four-step Cu–Cl cycle for hydrogen production," Energy, Elsevier, vol. 77(C), pages 338-351.
    6. Guo, Liejin & Chen, Yubin & Su, Jinzhan & Liu, Maochang & Liu, Ya, 2019. "Obstacles of solar-powered photocatalytic water splitting for hydrogen production: A perspective from energy flow and mass flow," Energy, Elsevier, vol. 172(C), pages 1079-1086.
    7. Xiao, Lan & Wu, Shuang-Ying & Li, You-Rong, 2012. "Advances in solar hydrogen production via two-step water-splitting thermochemical cycles based on metal redox reactions," Renewable Energy, Elsevier, vol. 41(C), pages 1-12.
    8. Mastropasqua, Luca & Pecenati, Ilaria & Giostri, Andrea & Campanari, Stefano, 2020. "Solar hydrogen production: Techno-economic analysis of a parabolic dish-supported high-temperature electrolysis system," Applied Energy, Elsevier, vol. 261(C).
    9. Vignarooban, K. & Xu, Xinhai & Arvay, A. & Hsu, K. & Kannan, A.M., 2015. "Heat transfer fluids for concentrating solar power systems – A review," Applied Energy, Elsevier, vol. 146(C), pages 383-396.
    10. Sadeghi, Shayan & Ghandehariun, Samane & Rosen, Marc A., 2020. "Comparative economic and life cycle assessment of solar-based hydrogen production for oil and gas industries," Energy, Elsevier, vol. 208(C).
    11. Ghandehariun, S. & Wang, Z. & Naterer, G.F. & Rosen, M.A., 2015. "Experimental investigation of molten salt droplet quenching and solidification processes of heat recovery in thermochemical hydrogen production," Applied Energy, Elsevier, vol. 157(C), pages 267-275.
    12. Ma, Yuegeng & Morozyuk, Tatiana & Liu, Ming & Yan, Junjie & Liu, Jiping, 2019. "Optimal integration of recompression supercritical CO2 Brayton cycle with main compression intercooling in solar power tower system based on exergoeconomic approach," Applied Energy, Elsevier, vol. 242(C), pages 1134-1154.
    13. Chitgar, Nazanin & Moghimi, Mahdi, 2020. "Design and evaluation of a novel multi-generation system based on SOFC-GT for electricity, fresh water and hydrogen production," Energy, Elsevier, vol. 197(C).
    14. Li, Xin & Kong, Weiqiang & Wang, Zhifeng & Chang, Chun & Bai, Fengwu, 2010. "Thermal model and thermodynamic performance of molten salt cavity receiver," Renewable Energy, Elsevier, vol. 35(5), pages 981-988.
    15. Nikolaidis, Pavlos & Poullikkas, Andreas, 2017. "A comparative overview of hydrogen production processes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 67(C), pages 597-611.
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    4. Sun, Xue & Li, Xiaofei & Zeng, Jingxin & Song, Qiang & Yang, Zhen & Duan, Yuanyuan, 2023. "Energy and exergy analysis of a novel solar-hydrogen production system with S–I thermochemical cycle," Energy, Elsevier, vol. 283(C).
    5. Liu, Huan & Guo, Wei & Liu, Shuqin, 2022. "Comparative techno-economic performance analysis of underground coal gasification and surface coal gasification based coal-to-hydrogen process," Energy, Elsevier, vol. 258(C).
    6. Ghandehariun, Samane & Ghandehariun, Amir M. & Ziabari, Nima Bahrami, 2023. "Performance prediction and optimization of a hybrid renewable-energy-based multigeneration system using machine learning," Energy, Elsevier, vol. 282(C).
    7. Sadeghi, Shayan & Ghandehariun, Samane & Rosen, Marc A., 2023. "Waste heat recovery potential in the thermochemical copper–chlorine cycle for hydrogen production: Development of an efficient and cost-effective heat exchanger network," Energy, Elsevier, vol. 282(C).

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