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ILC (ionic liquid colloids) based on p(4-VP) (poly(4-vinyl pyridine)) microgels: Synthesis, characterization and use in hydrogen production

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  • Sahiner, Nurettin
  • Turhan, Tugce
  • Lyon, L. Andrew

Abstract

In this study for the first time p(4-VP) (poly(4-vinyl pyridine)) colloidal ionic liquid particles derived from 4-VP (4-vinyl pyridine) are reported, used in the preparation of a catalyst system by loading metal salts such as CoCl2 and NiCl2 from ethyl alcohol solutions into the modified p(4-VP) particles, and used for hydrogen generation from NaOH-free hydrolysis of NaBH4. Colloidal ionic liquids containing 0.054 mmol Co and Ni were used in NaOH-free hydrolysis of 0.30 g NaBH4 in 50 mL water at 40 °C and 1000 rpm mixing rate. The reaction rates relating to hydrolysis of NaBH4 were 3148 (mL H2) (min)−1 (g of Co)−1 for Co, and 1803 (mL H2) (min)−1 (g of Ni)−1 for Ni. The effect of metal loading time, NaBH4 concentration, temperature, and kinetic parameters were also investigated. The activation energy, enthalpy, and activation entropy for the reaction of NaBH4 in the presence of the colloidal dicationic catalyst system were calculated as 43.98 kJ/mol, 40.38 kJ/mol, and −178.22 J/mol.K, respectively.

Suggested Citation

  • Sahiner, Nurettin & Turhan, Tugce & Lyon, L. Andrew, 2014. "ILC (ionic liquid colloids) based on p(4-VP) (poly(4-vinyl pyridine)) microgels: Synthesis, characterization and use in hydrogen production," Energy, Elsevier, vol. 66(C), pages 256-263.
    • Handle: RePEc:eee:energy:v:66:y:2014:i:c:p:256-263
    DOI: 10.1016/j.energy.2013.12.053
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    References listed on IDEAS

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    1. Chinnappan, Amutha & Kang, Hyuck-Chul & Kim, Hern, 2011. "Preparation of PVDF nanofiber composites for hydrogen generation from sodium borohydride," Energy, Elsevier, vol. 36(2), pages 755-759.
    2. Turhan, Tugce & Güvenilir, Yuksel Avcıbası & Sahiner, Nurettin, 2013. "Micro poly(3-sulfopropyl methacrylate) hydrogel synthesis for in situ metal nanoparticle preparation and hydrogen generation from hydrolysis of NaBH4," Energy, Elsevier, vol. 55(C), pages 511-518.
    3. Huang, Yao-Hui & Su, Chia-Chi & Wang, Shu-Ling & Lu, Ming-Chun, 2012. "Development of Al2O3 carrier-Ru composite catalyst for hydrogen generation from alkaline NaBH4 hydrolysis," Energy, Elsevier, vol. 46(1), pages 242-247.
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    1. Loghmani, Mohammad Hassan & Shojaei, Abdollah Fallah & Khakzad, Morteza, 2017. "Hydrogen generation as a clean energy through hydrolysis of sodium borohydride over Cu-Fe-B nano powders: Effect of polymers and surfactants," Energy, Elsevier, vol. 126(C), pages 830-840.
    2. Cai, Haokun & Liu, Liping & Chen, Qiang & Lu, Ping & Dong, Jian, 2016. "Ni-polymer nanogel hybrid particles: A new strategy for hydrogen production from the hydrolysis of dimethylamine-borane and sodium borohydride," Energy, Elsevier, vol. 99(C), pages 129-135.

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    More about this item

    Keywords

    Ionic liquid colloids; Microgel ionic colloids; Nanogel ionic colloids; H2 generation; Modified p(4-VP) (poly(4-vinyl pyridine)) particles;
    All these keywords.

    JEL classification:

    • H2 - Public Economics - - Taxation, Subsidies, and Revenue

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