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Rehydrogenation of Sodium Borates to Close the NaBH 4 -H 2 Cycle: A Review

Author

Listed:
  • Helder X. Nunes

    (Transport Phenomena Research Center, Chemical Engineering Department, Faculty of Engineering, University of Porto, Dr. Roberto Frias s/n, 4200-465 Porto, Portugal
    These authors contributed equally to this work.)

  • Diogo L. Silva

    (Transport Phenomena Research Center, Chemical Engineering Department, Faculty of Engineering, University of Porto, Dr. Roberto Frias s/n, 4200-465 Porto, Portugal
    These authors contributed equally to this work.)

  • Carmen M. Rangel

    (National Laboratory of Energy and Geology, Estrada da Portela, 1649-038 Lisboa, Portugal)

  • Alexandra M. F. R. Pinto

    (Transport Phenomena Research Center, Chemical Engineering Department, Faculty of Engineering, University of Porto, Dr. Roberto Frias s/n, 4200-465 Porto, Portugal)

Abstract

In 2007, the US Department of Energy recommended a no-go on NaBH 4 hydrolysis for onboard applications; however, the concept of a NaBH 4 -H 2 -PEMFC system has the potential to become a primary source for on-demand power supply. Despite the many efforts to study this technology, most of the published papers focus on catalytic performance. Nevertheless, the development of a practical reaction system to close the NaBH 4 -H 2 cycle remains a critical issue. Therefore, this work provides an overview of the research progress on the solutions for the by-product rehydrogenation leading to the regeneration of NaBH 4 with economic potential. It is the first to compare and analyze the main types of processes to regenerate NaBH 4 : thermo-, mechano-, and electrochemical. Moreover, it considers the report by Demirci et al. on the main by-product of sodium borohydride hydrolysis. The published literature already reported efficient NaBH 4 regeneration; however, the processes still need more improvements. Moreover, it is noteworthy that a transition to clean methods, through the years, was observed.

Suggested Citation

  • Helder X. Nunes & Diogo L. Silva & Carmen M. Rangel & Alexandra M. F. R. Pinto, 2021. "Rehydrogenation of Sodium Borates to Close the NaBH 4 -H 2 Cycle: A Review," Energies, MDPI, vol. 14(12), pages 1-28, June.
    • Handle: RePEc:gam:jeners:v:14:y:2021:i:12:p:3567-:d:575512
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    References listed on IDEAS

    as
    1. Chou, Chang-Chen & Hsieh, Ching-Hsuan & Chen, Bing-Hung, 2015. "Hydrogen generation from catalytic hydrolysis of sodium borohydride using bimetallic Ni–Co nanoparticles on reduced graphene oxide as catalysts," Energy, Elsevier, vol. 90(P2), pages 1973-1982.
    2. Loghmani, Mohammad Hassan & Shojaei, Abdollah Fallah, 2014. "Hydrogen production through hydrolysis of sodium borohydride: Oleic acid stabilized Co–La–Zr–B nanoparticle as a novel catalyst," Energy, Elsevier, vol. 68(C), pages 152-159.
    3. Fazelpour, Farivar & Markarian, Elin & Soltani, Nima, 2017. "Wind energy potential and economic assessment of four locations in Sistan and Balouchestan province in Iran," Renewable Energy, Elsevier, vol. 109(C), pages 646-667.
    4. Kwon, Soon-mo & Kim, Myoung Jin & Kang, Shinuang & Kim, Taegyu, 2019. "Development of a high-storage-density hydrogen generator using solid-state NaBH4 as a hydrogen source for unmanned aerial vehicles," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    5. Bozkurt, Gamze & Özer, Abdulkadir & Yurtcan, Ayşe Bayrakçeken, 2019. "Development of effective catalysts for hydrogen generation from sodium borohydride: Ru, Pt, Pd nanoparticles supported on Co3O4," Energy, Elsevier, vol. 180(C), pages 702-713.
    6. Netskina, O.V. & Tayban, E.S. & Prosvirin, I.P. & Komova, O.V. & Simagina, V.I., 2020. "Hydrogen storage systems based on solid-state NaBH4/Co composite: Effect of catalyst precursor on hydrogen generation rate," Renewable Energy, Elsevier, vol. 151(C), pages 278-285.
    7. Tamboli, Ashif H. & Chaugule, Avinash A. & Sheikh, Faheem A. & Chung, Wook-Jin & Kim, Hern, 2015. "Synthesis and application of CeO2–NiO loaded TiO2 nanofiber as novel catalyst for hydrogen production from sodium borohydride hydrolysis," Energy, Elsevier, vol. 89(C), pages 568-575.
    8. Zhang, Hongming & Xu, Guochang & Zhang, Lu & Wang, Wenfeng & Miao, Wenkang & Chen, Kangli & Cheng, Lina & Li, Yuan & Han, Shumin, 2020. "Ultrafine cobalt nanoparticles supported on carbon nanospheres for hydrolysis of sodium borohydride," Renewable Energy, Elsevier, vol. 162(C), pages 345-354.
    9. Wang, Yan & Shen, Yan & Qi, Kezhen & Cao, Zhongqiu & Zhang, Ke & Wu, Shiwei, 2016. "Nanostructured cobalt–phosphorous catalysts for hydrogen generation from hydrolysis of sodium borohydride solution," Renewable Energy, Elsevier, vol. 89(C), pages 285-294.
    10. Loghmani, Mohammad Hassan & Shojaei, Abdollah Fallah & Khakzad, Morteza, 2017. "Hydrogen generation as a clean energy through hydrolysis of sodium borohydride over Cu-Fe-B nano powders: Effect of polymers and surfactants," Energy, Elsevier, vol. 126(C), pages 830-840.
    11. Chinnappan, Amutha & Jadhav, Arvind H. & Puguan, John Marc C. & Appiah-Ntiamoah, Richard & Kim, Hern, 2015. "Fabrication of ionic liquid/polymer nanoscale networks by electrospinning and chemical cross-linking and their application in hydrogen generation from the hydrolysis of NaBH4," Energy, Elsevier, vol. 79(C), pages 482-488.
    12. Oh, Taek Hyun & Gang, Byeong Gyu & Kim, Hyuntak & Kwon, Sejin, 2015. "Sodium borohydride hydrogen generator using Co–P/Ni foam catalysts for 200 W proton exchange membrane fuel cell system," Energy, Elsevier, vol. 90(P1), pages 1163-1170.
    13. Wu, Chongbei & Guo, Jingya & Zhang, Jifang & Zhao, Yanchun & Tian, Jianniao & Isimjan, Tayirjan Taylor & Yang, Xiulin, 2019. "Palladium nanoclusters decorated partially decomposed porous ZIF-67 polyhedron with ultrahigh catalytic activity and stability on hydrogen generation," Renewable Energy, Elsevier, vol. 136(C), pages 1064-1070.
    14. Shen, Xiaochen & Wang, Qing & Wu, Qingquan & Guo, Siqi & Zhang, Zhengyan & Sun, Ziyang & Liu, Baishu & Wang, Zhibin & Zhao, Bin & Ding, Weiping, 2015. "CoB supported on Ag-activated TiO2 as a highly active catalyst for hydrolysis of alkaline NaBH4 solution," Energy, Elsevier, vol. 90(P1), pages 464-474.
    15. Tomboc, Gracita Raquel M. & Tamboli, Ashif H. & Kim, Hern, 2017. "Synthesis of Co3O4 macrocubes catalyst using novel chitosan/urea template for hydrogen generation from sodium borohydride," Energy, Elsevier, vol. 121(C), pages 238-245.
    16. Tamboli, Ashif H. & Jadhav, Amol R. & Chung, Wook-Jin & Kim, Hern, 2015. "Structurally modified cerium doped hydrotalcite-like precursor as efficient catalysts for hydrogen production from sodium borohydride hydrolysis," Energy, Elsevier, vol. 93(P1), pages 955-962.
    17. Jianfeng Mao & Duncan H. Gregory, 2015. "Recent Advances in the Use of Sodium Borohydride as a Solid State Hydrogen Store," Energies, MDPI, vol. 8(1), pages 1-24, January.
    18. Netskina, O.V. & Komova, O.V. & Simagina, V.I. & Odegova, G.V. & Prosvirin, I.P. & Bulavchenko, O.A., 2016. "Aqueous-alkaline NaBH4 solution: The influence of storage duration of solutions on reduction and activity of cobalt catalysts," Renewable Energy, Elsevier, vol. 99(C), pages 1073-1081.
    19. Santos, D.M.F. & Sequeira, C.A.C., 2011. "Sodium borohydride as a fuel for the future," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(8), pages 3980-4001.
    20. Sopian, Kamaruzzaman & Wan Daud, Wan Ramli, 2006. "Challenges and future developments in proton exchange membrane fuel cells," Renewable Energy, Elsevier, vol. 31(5), pages 719-727.
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