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Semiclathrate-based CO2 capture from pre-combustion fuel gas using tetra-n-butylammonium chloride: A thermodynamic, kinetic, and spectroscopic study

Author

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  • Kim, Sungwoo
  • Kim, Soyoung
  • Mok, Junghoon
  • Seo, Yongwon

Abstract

The primary objective of this study was to investigate the feasibility of pre-combustion CO2 capture using tetra-n-butylammonium chloride (TBAC) semiclathrate in a fuel gas mixture comprising CO2 (40%) + H2 (60%), with a primary focus on examining the thermodynamic, kinetic, and spectroscopic aspects of this process. Phase equilibria measured at various TBAC concentrations revealed that the CO2 + H2 + TBAC semiclathrates exhibited maximum thermodynamic stability at a stoichiometric concentration (3.3 mol%). CO2 concentrations in both the vapor and semiclathrate phases, along with gas consumption during and after semiclathrate formation, were measured to assess CO2 selectivity and gas uptake in the semiclathrate phase. Notably, CO2 enrichment was approximately 90% in the semiclathrate phase. In-situ Raman spectroscopy provided clear confirmation of the enclathration of both CO2 and H2 in the semiclathrate lattices, while powder X-ray diffraction analysis revealed the tetragonal (P42/m) structure of the CO2 + H2 + TBAC (3.3 mol%) semiclathrate. Furthermore, a high-pressure micro-differential scanning calorimeter was used to measure the dissociation enthalpies of the CO2 + H2 + TBAC (3.3 mol%) semiclathrate at various pressures. The comprehensive results obtained in this study strongly support the potential use of TBAC semiclathrate as a material for pre-combustion CO2 capture.

Suggested Citation

  • Kim, Sungwoo & Kim, Soyoung & Mok, Junghoon & Seo, Yongwon, 2024. "Semiclathrate-based CO2 capture from pre-combustion fuel gas using tetra-n-butylammonium chloride: A thermodynamic, kinetic, and spectroscopic study," Energy, Elsevier, vol. 294(C).
    • Handle: RePEc:eee:energy:v:294:y:2024:i:c:s0360544224006637
    DOI: 10.1016/j.energy.2024.130891
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    References listed on IDEAS

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    1. Lee, Hyun Ju & Lee, Ju Dong & Linga, Praveen & Englezos, Peter & Kim, Young Seok & Lee, Man Sig & Kim, Yang Do, 2010. "Gas hydrate formation process for pre-combustion capture of carbon dioxide," Energy, Elsevier, vol. 35(6), pages 2729-2733.
    2. Kim, Soyoung & Baek, Il-Hyun & You, Jong-Kyun & Seo, Yongwon, 2015. "Guest gas enclathration in tetra-n-butyl ammonium chloride (TBAC) semiclathrates: Potential application to natural gas storage and CO2 capture," Applied Energy, Elsevier, vol. 140(C), pages 107-112.
    3. Xu, Chun-Gang & Xie, Wen-Jun & Chen, Guo-Shu & Yan, Xiao-Xue & Cai, Jing & Chen, Zhao-Yang & Li, Xiao-Sen, 2020. "Study on the influencing factors of gas consumption in hydrate-based CO2 separation in the presence of CP by Raman analysis," Energy, Elsevier, vol. 198(C).
    4. Kim, Soyoung & Seo, Yongwon, 2015. "Semiclathrate-based CO2 capture from flue gas mixtures: An experimental approach with thermodynamic and Raman spectroscopic analyses," Applied Energy, Elsevier, vol. 154(C), pages 987-994.
    5. Muromachi, Sanehiro, 2021. "CO2 capture properties of semiclathrate hydrates formed with tetra-n-butylammonium and tetra-n-butylphosphonium salts from H2 + CO2 mixed gas," Energy, Elsevier, vol. 223(C).
    6. Hashimoto, Hidenori & Yamaguchi, Tsutomu & Kinoshita, Takahiro & Muromachi, Sanehiro, 2017. "Gas separation of flue gas by tetra-n-butylammonium bromide hydrates under moderate pressure conditions," Energy, Elsevier, vol. 129(C), pages 292-298.
    7. Theo, Wai Lip & Lim, Jeng Shiun & Hashim, Haslenda & Mustaffa, Azizul Azri & Ho, Wai Shin, 2016. "Review of pre-combustion capture and ionic liquid in carbon capture and storage," Applied Energy, Elsevier, vol. 183(C), pages 1633-1663.
    8. Guang J. Zhang & Ming Cai & Aixue Hu, 2013. "Energy consumption and the unexplained winter warming over northern Asia and North America," Nature Climate Change, Nature, vol. 3(5), pages 466-470, May.
    9. Zhong, Dong-Liang & Ding, Kun & Lu, Yi-Yu & Yan, Jin & Zhao, Wei-Long, 2016. "Methane recovery from coal mine gas using hydrate formation in water-in-oil emulsions," Applied Energy, Elsevier, vol. 162(C), pages 1619-1626.
    10. Xu, Chun-Gang & Zhang, Shao-Hong & Cai, Jing & Chen, Zhao-Yang & Li, Xiao-Sen, 2013. "CO2 (carbon dioxide) separation from CO2–H2 (hydrogen) gas mixtures by gas hydrates in TBAB (tetra-n-butyl ammonium bromide) solution and Raman spectroscopic analysis," Energy, Elsevier, vol. 59(C), pages 719-725.
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