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The role of limestone during fluidized bed oxy-combustion of coal and biomass

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  • Lupiáñez, Carlos
  • Carmen Mayoral, M.
  • Díez, Luis I.
  • Pueyo, Eloy
  • Espatolero, Sergio
  • Manuel Andrés, J.

Abstract

The interest in bio-CCS technologies is growing due to their potential to reduce CO2 emission in power generation. Oxy-co-firing in fluidized-bed units is one of the available techniques to develop bio-CCS, offering wide fuel flexibility and low SO2 and NOx emissions. This paper discusses the results of an experimental campaign carried out in a lab-scale fluidized bed reactor. The work focuses on the influence of limestone when oxy-firing blends of lignite and corn stover. Two different types of limestone with two Ca:S molar ratios were tested, and operational conditions were selected to compare the mechanisms governing desulphurization. Emissions of SO2, NO and HCl, together with deposition rates and ash mineralogy are studied in the paper. SO2 capture increases with the Ca:S ratio and bed temperature, but to a different extent depending on the limestone fragmentation. The amount of NO emitted rises with the Ca:S ratio and the presence of calcined limestone (indirect desulphurization). The HCl concentration in the gas phase is dominated by alkali sulfation. Finally, the conditions for the highest desulphurization efficiency diminished the deposition rates, but increased the risk for chlorine-induced corrosion.

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  • Lupiáñez, Carlos & Carmen Mayoral, M. & Díez, Luis I. & Pueyo, Eloy & Espatolero, Sergio & Manuel Andrés, J., 2016. "The role of limestone during fluidized bed oxy-combustion of coal and biomass," Applied Energy, Elsevier, vol. 184(C), pages 670-680.
    • Handle: RePEc:eee:appene:v:184:y:2016:i:c:p:670-680
    DOI: 10.1016/j.apenergy.2016.11.018
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    1. Wang, Wenjing & Li, Yingjie & Xie, Xin & Sun, Rongyue, 2014. "Effect of the presence of HCl on cyclic CO2 capture of calcium-based sorbent in calcium looping process," Applied Energy, Elsevier, vol. 125(C), pages 246-253.
    2. Riaza, J. & Gil, M.V. & Álvarez, L. & Pevida, C. & Pis, J.J. & Rubiera, F., 2012. "Oxy-fuel combustion of coal and biomass blends," Energy, Elsevier, vol. 41(1), pages 429-435.
    3. de Diego, L.F. & de las Obras-Loscertales, M. & Rufas, A. & García-Labiano, F. & Gayán, P. & Abad, A. & Adánez, J., 2013. "Pollutant emissions in a bubbling fluidized bed combustor working in oxy-fuel operating conditions: Effect of flue gas recirculation," Applied Energy, Elsevier, vol. 102(C), pages 860-867.
    4. Oboirien, B.O. & Thulari, V. & North, B.C., 2016. "Enrichment of trace elements in bottom ash from coal oxy-combustion: Effect of coal types," Applied Energy, Elsevier, vol. 177(C), pages 81-86.
    5. Sandberg, Jan & Karlsson, Christer & Fdhila, Rebei Bel, 2011. "A 7Â year long measurement period investigating the correlation of corrosion, deposit and fuel in a biomass fired circulated fluidized bed boiler," Applied Energy, Elsevier, vol. 88(1), pages 99-110, January.
    6. Singh, Ravi Inder & Kumar, Rajesh, 2016. "Current status and experimental investigation of oxy-fired fluidized bed," Renewable and Sustainable Energy Reviews, Elsevier, vol. 61(C), pages 398-420.
    7. Yin, Chungen & Yan, Jinyue, 2016. "Oxy-fuel combustion of pulverized fuels: Combustion fundamentals and modeling," Applied Energy, Elsevier, vol. 162(C), pages 742-762.
    8. Bu, Changsheng & Gómez-Barea, Alberto & Chen, Xiaoping & Leckner, Bo & Liu, Daoyin & Pallarès, David & Lu, Ping, 2016. "Effect of CO2 on oxy-fuel combustion of coal-char particles in a fluidized bed: Modeling and comparison with the conventional mode of combustion," Applied Energy, Elsevier, vol. 177(C), pages 247-259.
    9. Agbor, Ezinwa & Zhang, Xiaolei & Kumar, Amit, 2014. "A review of biomass co-firing in North America," Renewable and Sustainable Energy Reviews, Elsevier, vol. 40(C), pages 930-943.
    10. Li, Shiyuan & Xu, Mingxin & Jia, Lufei & Tan, Li & Lu, Qinggang, 2016. "Influence of operating parameters on N2O emission in O2/CO2 combustion with high oxygen concentration in circulating fluidized bed," Applied Energy, Elsevier, vol. 173(C), pages 197-209.
    11. Akram, M. & Tan, C.K. & Garwood, D.R. & Fisher, M. & Gent, D.R. & Kaye, W.G., 2015. "Co-firing of pressed sugar beet pulp with coal in a laboratory-scale fluidised bed combustor," Applied Energy, Elsevier, vol. 139(C), pages 1-8.
    12. Schakel, Wouter & Meerman, Hans & Talaei, Alireza & Ramírez, Andrea & Faaij, André, 2014. "Comparative life cycle assessment of biomass co-firing plants with carbon capture and storage," Applied Energy, Elsevier, vol. 131(C), pages 441-467.
    13. Wu, Yinghai & Wang, Chunbo & Tan, Yewen & Jia, Lufei & Anthony, Edward J., 2011. "Characterization of ashes from a 100kWth pilot-scale circulating fluidized bed with oxy-fuel combustion," Applied Energy, Elsevier, vol. 88(9), pages 2940-2948.
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