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Electrospun phase change fibers based on polyethylene glycol/cellulose acetate blends

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  • Chen, Changzhong
  • Wang, Linge
  • Huang, Yong

Abstract

Ultrafine phase change fibers based on polyethylene glycol (PEG)/cellulose acetate (CA) blends in which PEG acts as a model phase change material (PCM) and CA acts as a supporting material, were successfully prepared via electrospinning. The effect of PEG content on the morphology, crystalline properties, phase change behaviors and tensile properties of the composite fibers was studied systematically by field-emission scanning electron microscopy (FE-SEM), wide-angle X-ray diffraction (WAXD), differential scanning calorimetry (DSC) and a tensile tester, respectively. The SEM observation indicates that maximum PEG content in the fibers could reach up to 70wt%, and the morphology and average diameter of the composite fibers vary with PEG content. Thermal analysis results show that the latent heats of the phase change fibers increase with the increasing of PEG content in the fibers, and the PEG/CA fibers with high enthalpies have a good capability to regulate their interior temperature as the ambient temperature alters. Therefore, the developed phase change fibers have enormous applicable potentials in thermal energy storage and temperature regulation.

Suggested Citation

  • Chen, Changzhong & Wang, Linge & Huang, Yong, 2011. "Electrospun phase change fibers based on polyethylene glycol/cellulose acetate blends," Applied Energy, Elsevier, vol. 88(9), pages 3133-3139.
    • Handle: RePEc:eee:appene:v:88:y:2011:i:9:p:3133-3139
    DOI: 10.1016/j.apenergy.2011.02.026
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    1. Chen, Changzhong & Zhao, Yiyang & Liu, Wenmin, 2013. "Electrospun polyethylene glycol/cellulose acetate phase change fibers with core–sheath structure for thermal energy storage," Renewable Energy, Elsevier, vol. 60(C), pages 222-225.
    2. Gao, Wei & Liu, Feifan & Yu, Cheng & Chen, Yongping & Liu, Xiangdong, 2023. "Microfluidic method–based encapsulated phase change materials: Fundamentals, progress, and prospects," Renewable and Sustainable Energy Reviews, Elsevier, vol. 171(C).
    3. Sarı, Ahmet & Alkan, Cemil & Bilgin, Cahit, 2014. "Micro/nano encapsulation of some paraffin eutectic mixtures with poly(methyl methacrylate) shell: Preparation, characterization and latent heat thermal energy storage properties," Applied Energy, Elsevier, vol. 136(C), pages 217-227.
    4. Chen, Weiwang & Weng, Wenguo, 2016. "Ultrafine lauric–myristic acid eutectic/poly (meta-phenylene isophthalamide) form-stable phase change fibers for thermal energy storage by electrospinning," Applied Energy, Elsevier, vol. 173(C), pages 168-176.
    5. Ajiv Alam Khan & Syed Mohd Yahya & Masood Ashraf Ali, 2022. "Synthesis and Characterization of Titania–MXene-Based Phase Change Material for Sustainable Thermal Energy Storage," Sustainability, MDPI, vol. 15(1), pages 1-14, December.
    6. Qian, Yong & Wei, Ping & Jiang, Pingkai & Li, Zhi & Yan, Yonggang & Liu, Jiping, 2013. "Preparation of a novel PEG composite with halogen-free flame retardant supporting matrix for thermal energy storage application," Applied Energy, Elsevier, vol. 106(C), pages 321-327.
    7. Huanmei Yuan & Sitong Liu & Tonghe Li & Liyun Yang & Dehong Li & Hao Bai & Xiaodong Wang, 2024. "Review on Thermal Properties with Influence Factors of Solid–Liquid Organic Phase-Change Micro/Nanocapsules," Energies, MDPI, vol. 17(3), pages 1-51, January.
    8. Gutierrez, Andrea & Ushak, Svetlana & Galleguillos, Hector & Fernandez, Angel & Cabeza, Luisa F. & Grágeda, Mario, 2015. "Use of polyethylene glycol for the improvement of the cycling stability of bischofite as thermal energy storage material," Applied Energy, Elsevier, vol. 154(C), pages 616-621.
    9. Cai, Yibing & Gao, Chuntao & Zhang, Ting & Zhang, Zhen & Wei, Qufu & Du, Jinmei & Hu, Yuan & Song, Lei, 2013. "Influences of expanded graphite on structural morphology and thermal performance of composite phase change materials consisting of fatty acid eutectics and electrospun PA6 nanofibrous mats," Renewable Energy, Elsevier, vol. 57(C), pages 163-170.
    10. Wu, Yang & Chen, Changzhong & Jia, Yifan & Wu, Jie & Huang, Yong & Wang, Linge, 2018. "Review on electrospun ultrafine phase change fibers (PCFs) for thermal energy storage," Applied Energy, Elsevier, vol. 210(C), pages 167-181.
    11. Suárez-García, Andrés & Arce, Elena & Alford, Laura & Luhrs, Claudia C., 2023. "Electrospun composite fibers containing organic phase change materials for thermo-regulation: Trends," Renewable and Sustainable Energy Reviews, Elsevier, vol. 187(C).

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