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Preparation and thermal properties of palmitic acid/polyaniline/exfoliated graphite nanoplatelets form-stable phase change materials

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  • Zeng, Ju-Lan
  • Zheng, Shuang-Hao
  • Yu, Sai-Bo
  • Zhu, Fu-Rong
  • Gan, Juan
  • Zhu, Ling
  • Xiao, Zhong-Liang
  • Zhu, Xin-Yu
  • Zhu, Zhen
  • Sun, Li-Xian
  • Cao, Zhong

Abstract

Exfoliated graphite nanoplatelets (xGnP) were applied to enhance the thermal conductivity of polyaniline (PANI) based form-stable phase change materials (PCMs). The xGnP was first dispersed in palmitic acid (PA) uniformly under the assistance of ultra-sonication. The xGnP/PA mixture was then applied to prepare PA/PANI/xGnP form-stable PCMs, in which PANI was obtained by means of surface polymerization of aniline and acted as supporting material. The content of PA in the prepared form-stable PCMs was fixed as 75wt%. The structure, thermal energy storage properties and thermal conductivity of the PA/PANI/xGnP form-stable PCMs were investigated. The results showed that the thermal conductivity of the prepared form-stable PCMs could be greatly improved by xGnP while the thermal energy storage capacity was maintained. The thermal conductivity and thermal energy storage capacity of the PA/PANI/xGnP form-stable PCM doped with 7.87wt% of xGnP could attain 1.08W/(mK) and 157.7J/g, respectively. The thermal conductivity was 237.5% higher than that of PA/PANI form-stable PCM. The prepared PA/PANI/xGnP form-stable PCM is expected to exhibit better performance in solar thermal energy applications.

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  • Zeng, Ju-Lan & Zheng, Shuang-Hao & Yu, Sai-Bo & Zhu, Fu-Rong & Gan, Juan & Zhu, Ling & Xiao, Zhong-Liang & Zhu, Xin-Yu & Zhu, Zhen & Sun, Li-Xian & Cao, Zhong, 2014. "Preparation and thermal properties of palmitic acid/polyaniline/exfoliated graphite nanoplatelets form-stable phase change materials," Applied Energy, Elsevier, vol. 115(C), pages 603-609.
    • Handle: RePEc:eee:appene:v:115:y:2014:i:c:p:603-609
    DOI: 10.1016/j.apenergy.2013.10.061
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