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Improved yield of solvent free enzymatic methanolysis of palm and jatropha oils blended with castor oil

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  • Maleki, Esmat
  • Aroua, Mohamed Kheireddine
  • Sulaiman, Nik Meriam Nik

Abstract

In this work, castor oil was blended with palm and jatropha oils to improve the yield of solvent-free enzymatic methanolysis reaction. Transesterification reactions were carried out with stoichiometric ratio of methanol to oil and using lipozyme TL IM as catalyst at 45°C and 200rpm for 24h. By adding only 10% castor oil to the reaction medium a surge in the yield of methanolysis of jatropha oil was observed (i.e. from 21.9% to 65.5%). Increasing the amount of castor oil to 20% raised the yield of methanolysis of jatropha oil to 78.3%. Blending 50% castor oil with palm oil increased the yield of enzymatic methanolysis from 11.9% to 76.2%. Mixing castor oil with jatropha and palm oils improved the yield of solvent free single-step methanolysis reaction to the higher amounts than the maximum theoretical yield of lipozyme TL IM (i.e. 67%).

Suggested Citation

  • Maleki, Esmat & Aroua, Mohamed Kheireddine & Sulaiman, Nik Meriam Nik, 2013. "Improved yield of solvent free enzymatic methanolysis of palm and jatropha oils blended with castor oil," Applied Energy, Elsevier, vol. 104(C), pages 905-909.
    • Handle: RePEc:eee:appene:v:104:y:2013:i:c:p:905-909
    DOI: 10.1016/j.apenergy.2012.12.009
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    1. Santori, Giulio & Di Nicola, Giovanni & Moglie, Matteo & Polonara, Fabio, 2012. "A review analyzing the industrial biodiesel production practice starting from vegetable oil refining," Applied Energy, Elsevier, vol. 92(C), pages 109-132.
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    1. Liu, Yun & Li, Chong & Wang, Shihui & Chen, Weiyi, 2014. "Solid-supported microorganism of Burkholderia cenocepacia cultured via solid state fermentation for biodiesel production: Optimization and kinetics," Applied Energy, Elsevier, vol. 113(C), pages 713-721.
    2. Bateni, Hamed & Karimi, Keikhosro & Zamani, Akram & Benakashani, Fatemeh, 2014. "Castor plant for biodiesel, biogas, and ethanol production with a biorefinery processing perspective," Applied Energy, Elsevier, vol. 136(C), pages 14-22.
    3. Bari, S. & Saad, Idris, 2014. "Effect of guide vane height on the performance and emissions of a compression ignition (CI) engine run with biodiesel through simulation and experiment," Applied Energy, Elsevier, vol. 136(C), pages 431-444.
    4. Sun, Shangde & Li, Kaiyue, 2020. "Biodiesel production from phoenix tree seed oil catalyzed by liquid lipozyme TL100L," Renewable Energy, Elsevier, vol. 151(C), pages 152-160.
    5. Azad, A.K. & Rasul, M.G. & Khan, M.M.K. & Sharma, Subhash C. & Mofijur, M. & Bhuiya, M.M.K., 2016. "Prospects, feedstocks and challenges of biodiesel production from beauty leaf oil and castor oil: A nonedible oil sources in Australia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 61(C), pages 302-318.
    6. Pinzi, S. & López, I. & Leiva-Candia, D.E. & Redel-Macías, M.D. & Herreros, J.M. & Cubero-Atienza, A. & Dorado, M.P., 2018. "Castor oil enhanced effect on fuel ethanol-diesel fuel blend properties," Applied Energy, Elsevier, vol. 224(C), pages 409-416.

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