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Power generation enhancement of a membrane-free thermally regenerative battery induced by the density difference of electrolytes

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Listed:
  • Shi, Yu
  • Li, Dong
  • An, Yichao
  • Zhang, Liang
  • Li, Jun
  • Fu, Qian
  • Zhu, Xun
  • Liao, Qiang

Abstract

The development of a low-cost and high-performance thermally regenerative battery is an extremely effective way for waste heat recovery. In this work, a membrane-free thermally regenerative battery (M−TRB) is designed for low-cost and high-performance low-grade thermal energy harvesting. It is exhibited that a M−TRB with a virtual membrane formed by the interface between electrolytes instead of the expensive anion exchange membrane (AEM) can achieve stable power generation successfully. And the maximum power density obtained in M−TRB is 118 W m−2 under the optimal operation condition. Moreover, a combination of M−TRB and hierarchical porous composite electrodes (PCEs) can further improve the maximum power density to 220 W m−2. The much lower cost caused by the simple structure without expensive AEM makes it more competitive in comparison to other TRBs. This indicated that the high-performance and low-cost M−TRB is a potential choice for the construction of systems in future applications.

Suggested Citation

  • Shi, Yu & Li, Dong & An, Yichao & Zhang, Liang & Li, Jun & Fu, Qian & Zhu, Xun & Liao, Qiang, 2023. "Power generation enhancement of a membrane-free thermally regenerative battery induced by the density difference of electrolytes," Applied Energy, Elsevier, vol. 344(C).
  • Handle: RePEc:eee:appene:v:344:y:2023:i:c:s0306261923006669
    DOI: 10.1016/j.apenergy.2023.121302
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    References listed on IDEAS

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    1. Forman, Clemens & Muritala, Ibrahim Kolawole & Pardemann, Robert & Meyer, Bernd, 2016. "Estimating the global waste heat potential," Renewable and Sustainable Energy Reviews, Elsevier, vol. 57(C), pages 1568-1579.
    2. Shi, Yu & Li, Yanxiang & Zhang, Liang & Li, Jun & Fu, Qian & Zhu, Xun & Liao, Qiang, 2022. "Development of a membrane-less microfluidic thermally regenerative ammonia-based battery towards small-scale low-grade thermal energy recovery," Applied Energy, Elsevier, vol. 326(C).
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    1. An, Yichao & Zhang, Yongsheng & Shi, Yu & Zhang, Liang & Li, Jun & Fu, Qian & Zhu, Xun & Liao, Qiang, 2023. "Alleviated ammonia crossover in thermally regenerative ammonia-based batteries by optimizing the introduced intermediate-chamber," Applied Energy, Elsevier, vol. 349(C).

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