IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v308y2022ics0306261921016330.html
   My bibliography  Save this article

An electrical resistivity-based method for measuring semi-clathrate hydrate formation kinetics: Application for cold storage and transport

Author

Listed:
  • Kim, Hyunho
  • Zheng, Junjie
  • Yin, Zhenyuan
  • Kumar, Sreekala
  • Tee, Jackson
  • Seo, Yutaek
  • Linga, Praveen

Abstract

Tetra-n-butylammonium bromide (TBAB) semi-clathrate hydrate has a large latent heat and suitable phase transition temperatures to be used as a phase change material for cold energy storage and transport. The mass fraction of hydrates in the semi-clathrate hydrate slurry is a key parameter determining the cold carrying capacity and flow properties. We developed a new experimental methodology based on electrical resistivity to quantify the hydrate fraction in semi-clathrate hydrate slurry during hydrate formation. Relationship between electrical resistivity and hydrate fraction of semi-clathrate hydrate slurry was established based on Bruggeman’s effective-medium approximation. After validation, this method was employed to quantitatively investigate the effect of temperature on TBAB hydrate formation from 20 wt% TBAB/water system. As the temperature was lowered from 278.2 K to 274.2 K, the induction time was reduced by 97.8% and the hydrate growth rate was enhanced by over 2.5 times. At 274.2 K and 276.2 K, type A hydrates were preferentially formed followed by a structural transition to type B. At 278.2 K, only type A hydrates were observed. Furthermore, given an appropriate concentration, amino acid L-tryptophan was identified to be a good kinetic promoter for TBAB hydrate formation. The presence of 500 ppm L-tryptophan reduced the induction time by 60% and boost the hydrate growth rate by more than 32%. The electrical resistivity-based method developed in this work has shown simplicity, low cost, high accuracy, and repeatability. It would enable precise investigation of semi-clathrate hydrate kinetics in the future for cold energy applications and beyond.

Suggested Citation

  • Kim, Hyunho & Zheng, Junjie & Yin, Zhenyuan & Kumar, Sreekala & Tee, Jackson & Seo, Yutaek & Linga, Praveen, 2022. "An electrical resistivity-based method for measuring semi-clathrate hydrate formation kinetics: Application for cold storage and transport," Applied Energy, Elsevier, vol. 308(C).
    • Handle: RePEc:eee:appene:v:308:y:2022:i:c:s0306261921016330
    DOI: 10.1016/j.apenergy.2021.118397
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261921016330
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2021.118397?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Zhang, Qiang & Zheng, Junjie & Zhang, Baoyong & Linga, Praveen, 2021. "Coal mine gas separation of methane via clathrate hydrate process aided by tetrahydrofuran and amino acids," Applied Energy, Elsevier, vol. 287(C).
    2. He, Tianbiao & Chong, Zheng Rong & Zheng, Junjie & Ju, Yonglin & Linga, Praveen, 2019. "LNG cold energy utilization: Prospects and challenges," Energy, Elsevier, vol. 170(C), pages 557-568.
    3. Beatrice Castellani & Elena Morini & Mirko Filipponi & Andrea Nicolini & Massimo Palombo & Franco Cotana & Federico Rossi, 2014. "Clathrate Hydrates for Thermal Energy Storage in Buildings: Overview of Proper Hydrate-Forming Compounds," Sustainability, MDPI, vol. 6(10), pages 1-15, September.
    4. Shukla, Anant & Buddhi, D. & Sawhney, R.L., 2009. "Solar water heaters with phase change material thermal energy storage medium: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(8), pages 2119-2125, October.
    5. Cho, Jinkyun & Kim, Yundeok, 2016. "Improving energy efficiency of dedicated cooling system and its contribution towards meeting an energy-optimized data center," Applied Energy, Elsevier, vol. 165(C), pages 967-982.
    6. Nie, Binjian & Palacios, Anabel & Zou, Boyang & Liu, Jiaxu & Zhang, Tongtong & Li, Yunren, 2020. "Review on phase change materials for cold thermal energy storage applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 134(C).
    7. Yi, Jie & Zhong, Dong-Liang & Yan, Jin & Lu, Yi-Yu, 2019. "Impacts of the surfactant sulfonated lignin on hydrate based CO2 capture from a CO2/CH4 gas mixture," Energy, Elsevier, vol. 171(C), pages 61-68.
    8. Zhang, P. & Ma, Z.W. & Bai, Z.Y. & Ye, J., 2016. "Rheological and energy transport characteristics of a phase change material slurry," Energy, Elsevier, vol. 106(C), pages 63-72.
    9. Bhattacharjee, Gaurav & Prakash Veluswamy, Hari & Kumar, Rajnish & Linga, Praveen, 2020. "Rapid methane storage via sII hydrates at ambient temperature," Applied Energy, Elsevier, vol. 269(C).
    10. Li, Shuang-Fei & Liu, Zhen-hua & Wang, Xue-Jiao, 2019. "A comprehensive review on positive cold energy storage technologies and applications in air conditioning with phase change materials," Applied Energy, Elsevier, vol. 255(C).
    11. Zhang, P. & Ma, Z.W. & Wang, R.Z., 2010. "An overview of phase change material slurries: MPCS and CHS," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(2), pages 598-614, February.
    12. Kumar, Asheesh & Veluswamy, Hari Prakash & Kumar, Rajnish & Linga, Praveen, 2019. "Direct use of seawater for rapid methane storage via clathrate (sII) hydrates," Applied Energy, Elsevier, vol. 235(C), pages 21-30.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Kim, Hyunho & Zheng, Junjie & Yin, Zhenyuan & Babu, Ponnivalavan & Kumar, Sreekala & Tee, Jackson & Linga, Praveen, 2023. "Semi-clathrate hydrate slurry as a cold energy storage and transport medium: Rheological study, energy analysis and enhancement by amino acid," Energy, Elsevier, vol. 264(C).
    2. Emiliano Borri & Nan Hua & Adriano Sciacovelli & Dawei Wu & Yulong Ding & Yongliang Li & Vincenza Brancato & Yannan Zhang & Andrea Frazzica & Wenguang Li & Zhibin Yu & Yanio E. Milian & Svetlana Ushak, 2022. "Phase Change Slurries for Cooling and Storage: An Overview of Research Trends and Gaps," Energies, MDPI, vol. 15(19), pages 1-17, September.
    3. Yang, Kairan & Chen, Zuozhou & Zhang, Peng, 2024. "State-of-the-art of cold energy storage, release and transport using CO2 double hydrate slurry," Applied Energy, Elsevier, vol. 358(C).
    4. Aminnaji, Morteza & Qureshi, M Fahed & Dashti, Hossein & Hase, Alfred & Mosalanejad, Abdolali & Jahanbakhsh, Amir & Babaei, Masoud & Amiri, Amirpiran & Maroto-Valer, Mercedes, 2024. "CO2 Gas hydrate for carbon capture and storage applications – Part 1," Energy, Elsevier, vol. 300(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Omran, Ahmed & Nesterenko, Nikolay & Valtchev, Valentin, 2022. "Zeolitic ice: A route toward net zero emissions," Renewable and Sustainable Energy Reviews, Elsevier, vol. 168(C).
    2. Kim, Hyunho & Zheng, Junjie & Yin, Zhenyuan & Babu, Ponnivalavan & Kumar, Sreekala & Tee, Jackson & Linga, Praveen, 2023. "Semi-clathrate hydrate slurry as a cold energy storage and transport medium: Rheological study, energy analysis and enhancement by amino acid," Energy, Elsevier, vol. 264(C).
    3. Cheng, Zucheng & Sun, Lintao & Liu, Yingying & Jiang, Lanlan & Chen, Bingbing & Song, Yongchen, 2023. "Study on the micro-macro kinetic and amino acid-enhanced separation of CO2-CH4 via sII hydrate," Renewable Energy, Elsevier, vol. 218(C).
    4. Catrini, P. & Panno, D. & Cardona, F. & Piacentino, A., 2020. "Characterization of cooling loads in the wine industry and novel seasonal indicator for reliable assessment of energy saving through retrofit of chillers," Applied Energy, Elsevier, vol. 266(C).
    5. Heier, Johan & Bales, Chris & Martin, Viktoria, 2015. "Combining thermal energy storage with buildings – a review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 1305-1325.
    6. He, Tianbiao & Chong, Zheng Rong & Zheng, Junjie & Ju, Yonglin & Linga, Praveen, 2019. "LNG cold energy utilization: Prospects and challenges," Energy, Elsevier, vol. 170(C), pages 557-568.
    7. Foroutan, Shima & Mohsenzade, Hanie & Dashti, Ali & Roosta, Hadi, 2021. "New insights into the evaluation of kinetic hydrate inhibitors and energy consumption in rocking and stirred cells," Energy, Elsevier, vol. 218(C).
    8. Salunkhe, Pramod B. & Shembekar, Prashant S., 2012. "A review on effect of phase change material encapsulation on the thermal performance of a system," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(8), pages 5603-5616.
    9. Cheng, Zucheng & Li, Shaohua & Liu, Yu & Zhang, Yi & Ling, Zheng & Yang, Mingjun & Jiang, Lanlan & Song, Yongchen, 2022. "Post-combustion CO2 capture and separation in flue gas based on hydrate technology：A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 154(C).
    10. Ge, Bin-Bin & Li, Xi-Yue & Zhong, Dong-Liang & Lu, Yi-Yu, 2022. "Investigation of natural gas storage and transportation by gas hydrate formation in the presence of bio-surfactant sulfonated lignin," Energy, Elsevier, vol. 244(PA).
    11. Ma, Fei & Zhang, Peng, 2020. "A review of thermo-fluidic performance and application of shellless phase change slurry: Part 2 – Flow and heat transfer characteristics," Energy, Elsevier, vol. 192(C).
    12. Satoshi Takeya & Sanehiro Muromachi & Tatsuo Maekawa & Yoshitaka Yamamoto & Hiroko Mimachi & Takahiro Kinoshita & Tetsuro Murayama & Hiroki Umeda & Dong-Hyuk Ahn & Yasunaga Iwasaki & Hidenori Hashimot, 2017. "Design of Ecological CO 2 Enrichment System for Greenhouse Production using TBAB + CO 2 Semi-Clathrate Hydrate," Energies, MDPI, vol. 10(7), pages 1-12, July.
    13. Yang, Lizhong & Villalobos, Uver & Akhmetov, Bakytzhan & Gil, Antoni & Khor, Jun Onn & Palacios, Anabel & Li, Yongliang & Ding, Yulong & Cabeza, Luisa F. & Tan, Wooi Leong & Romagnoli, Alessandro, 2021. "A comprehensive review on sub-zero temperature cold thermal energy storage materials, technologies, and applications: State of the art and recent developments," Applied Energy, Elsevier, vol. 288(C).
    14. Xinghui Zhang & Qili Shi & Lingai Luo & Yilin Fan & Qian Wang & Guanguan Jia, 2021. "Research Progress on the Phase Change Materials for Cold Thermal Energy Storage," Energies, MDPI, vol. 14(24), pages 1-46, December.
    15. Zhang, Ye & Bhattacharjee, Gaurav & Dharshini Vijayakumar, Mohana & Linga, Praveen, 2022. "Rapid and energy-dense methane hydrate formation at near ambient temperature using 1,3-dioxolane as a dual-function promoter," Applied Energy, Elsevier, vol. 311(C).
    16. Krzysztof Dutkowski & Marcin Kruzel & Bartosz Zajączkowski, 2020. "Determining the Heat of Fusion and Specific Heat of Microencapsulated Phase Change Material Slurry by Thermal Delay Method," Energies, MDPI, vol. 14(1), pages 1-14, December.
    17. Yiwei Wang & Lin Wang & Zhen Hu & Youli Li & Qiang Sun & Aixian Liu & Lanying Yang & Jing Gong & Xuqiang Guo, 2021. "The Thermodynamic and Kinetic Effects of Sodium Lignin Sulfonate on Ethylene Hydrate Formation," Energies, MDPI, vol. 14(11), pages 1-19, June.
    18. Qi, Meng & Park, Jinwoo & Lee, Inkyu & Moon, Il, 2022. "Liquid air as an emerging energy vector towards carbon neutrality: A multi-scale systems perspective," Renewable and Sustainable Energy Reviews, Elsevier, vol. 159(C).
    19. Ebrahimi, Armin & Ghorbani, Bahram & Ziabasharhagh, Masoud, 2020. "Introducing a novel integrated cogeneration system of power and cooling using stored liquefied natural gas as a cryogenic energy storage system," Energy, Elsevier, vol. 206(C).
    20. Heo, SungKu & Byun, Jaewon & Ifaei, Pouya & Ko, Jaerak & Ha, Byeongmin & Hwangbo, Soonho & Yoo, ChangKyoo, 2024. "Towards mega-scale decarbonized industrial park (Mega-DIP): Generative AI-driven techno-economic and environmental assessment of renewable and sustainable energy utilization in petrochemical industry," Renewable and Sustainable Energy Reviews, Elsevier, vol. 189(PA).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:308:y:2022:i:c:s0306261921016330. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.