IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v235y2019icp21-30.html
   My bibliography  Save this article

Direct use of seawater for rapid methane storage via clathrate (sII) hydrates

Author

Listed:
  • Kumar, Asheesh
  • Veluswamy, Hari Prakash
  • Kumar, Rajnish
  • Linga, Praveen

Abstract

Storing natural gas in the form of clathrate hydrates (termed as Solidified Natural Gas, SNG) is highly advantageous as it is non-explosive, environmentally benign and offers compact mode of natural gas storage with high volumetric storage capacity. In this work, we demonstrate rapid methane storage in saline water (1.1 mol% NaCl solution) and seawater via clathrate hydrates aided by 5.56 mol% THF in a simple unstirred tank reactor. We report extremely fast hydrate formation kinetics with methane uptake of 89.2 (±2.4) v/v in 13.8 (±2.4) minutes with saline water and 86.3 (±4.3) v/v in 15.1 (±0.8) minutes with natural seawater (t90). This uptake corresponds to an yield of 77.6 (±2.2)% for saline water and 75.0 (±3.4)% for natural seawater system respectively for the stated hydrate growth time. Further, molecular insights of the mixed hydrate formation in presence of NaCl is derived through high-pressure calorimetry, in-situ Raman, and powder X-ray diffraction analysis. Finally, we demonstrate the stability of the hydrate pellet formed employing direct seawater in presence of THF for two weeks. The direct use of natural seawater makes the SNG technology highly attractive to store/transport methane for large-scale storage needs and for low capacity natural gas production facilities like biogas manufacturing plants.

Suggested Citation

  • Kumar, Asheesh & Veluswamy, Hari Prakash & Kumar, Rajnish & Linga, Praveen, 2019. "Direct use of seawater for rapid methane storage via clathrate (sII) hydrates," Applied Energy, Elsevier, vol. 235(C), pages 21-30.
    • Handle: RePEc:eee:appene:v:235:y:2019:i:c:p:21-30
    DOI: 10.1016/j.apenergy.2018.10.085
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261918316544
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2018.10.085?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Takeya, Satoshi & Mimachi, Hiroko & Murayama, Tetsuro, 2018. "Methane storage in water frameworks: Self-preservation of methane hydrate pellets formed from NaCl solutions," Applied Energy, Elsevier, vol. 230(C), pages 86-93.
    2. Huen Lee & Jong-won Lee & Do Youn Kim & Jeasung Park & Yu-Taek Seo & Huang Zeng & Igor L. Moudrakovski & Christopher I. Ratcliffe & John A. Ripmeester, 2005. "Tuning clathrate hydrates for hydrogen storage," Nature, Nature, vol. 434(7034), pages 743-746, April.
    3. Veluswamy, Hari Prakash & Kumar, Asheesh & Seo, Yutaek & Lee, Ju Dong & Linga, Praveen, 2018. "A review of solidified natural gas (SNG) technology for gas storage via clathrate hydrates," Applied Energy, Elsevier, vol. 216(C), pages 262-285.
    4. E. Dendy Sloan, 2003. "Fundamental principles and applications of natural gas hydrates," Nature, Nature, vol. 426(6964), pages 353-359, November.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Cui, Gan & Dong, Zengrui & Wang, Shun & Xing, Xiao & Shan, Tianxiang & Li, Zili, 2020. "Effect of the water on the flame characteristics of methane hydrate combustion," Applied Energy, Elsevier, vol. 259(C).
    2. Bhattacharjee, Gaurav & Prakash Veluswamy, Hari & Kumar, Rajnish & Linga, Praveen, 2020. "Rapid methane storage via sII hydrates at ambient temperature," Applied Energy, Elsevier, vol. 269(C).
    3. Zhang, Ye & Bhattacharjee, Gaurav & Dharshini Vijayakumar, Mohana & Linga, Praveen, 2022. "Rapid and energy-dense methane hydrate formation at near ambient temperature using 1,3-dioxolane as a dual-function promoter," Applied Energy, Elsevier, vol. 311(C).
    4. Qureshi, M Fahed & Khandelwal, Himanshu & Usadi, Adam & Barckholtz, Timothy A. & Mhadeshwar, Ashish B. & Linga, Praveen, 2022. "CO2 hydrate stability in oceanic sediments under brine conditions," Energy, Elsevier, vol. 256(C).
    5. Fang, Bin & Lü, Tao & Li, Wei & Moultos, Othonas A. & Vlugt, Thijs J.H. & Ning, Fulong, 2024. "Microscopic insights into poly- and mono-crystalline methane hydrate dissociation in Na-montmorillonite pores at static and dynamic fluid conditions," Energy, Elsevier, vol. 288(C).
    6. Sa, Jeong-Hoon & Sum, Amadeu K., 2019. "Promoting gas hydrate formation with ice-nucleating additives for hydrate-based applications," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    7. Xiao, Peng & Dong, Bao-Can & Li, Jia & Zhang, Hong-Liang & Chen, Guang-Jin & Sun, Chang-Yu & Huang, Xing, 2022. "An approach to highly efficient filtration of methane hydrate slurry for the continuous hydrate production," Energy, Elsevier, vol. 259(C).
    8. Veluswamy, Hari Prakash & Kumar, Asheesh & Kumar, Rajnish & Linga, Praveen, 2019. "Investigation of the kinetics of mixed methane hydrate formation kinetics in saline and seawater," Applied Energy, Elsevier, vol. 253(C), pages 1-1.
    9. Bhattacharjee, Gaurav & Veluswamy, Hari Prakash & Kumar, Rajnish & Linga, Praveen, 2020. "Seawater based mixed methane-THF hydrate formation at ambient temperature conditions," Applied Energy, Elsevier, vol. 271(C).
    10. Kim, Hyunho & Zheng, Junjie & Yin, Zhenyuan & Kumar, Sreekala & Tee, Jackson & Seo, Yutaek & Linga, Praveen, 2022. "An electrical resistivity-based method for measuring semi-clathrate hydrate formation kinetics: Application for cold storage and transport," Applied Energy, Elsevier, vol. 308(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Sun, Yi-Fei & Wang, Yun-Fei & Zhong, Jin-Rong & Li, Wen-Zhi & Li, Rui & Cao, Bo-Jian & Kan, Jing-Yu & Sun, Chang-Yu & Chen, Guang-Jin, 2019. "Gas hydrate exploitation using CO2/H2 mixture gas by semi-continuous injection-production mode," Applied Energy, Elsevier, vol. 240(C), pages 215-225.
    2. Chen, Siyuan & Wang, Yanhong & Lang, Xuemei & Fan, Shuanshi & Li, Gang, 2023. "Rapid and high hydrogen storage in epoxycyclopentane hydrate at moderate pressure," Energy, Elsevier, vol. 268(C).
    3. Han Xue & Linhai Li & Yiqun Wang & Youhua Lu & Kai Cui & Zhiyuan He & Guoying Bai & Jie Liu & Xin Zhou & Jianjun Wang, 2024. "Probing the critical nucleus size in tetrahydrofuran clathrate hydrate formation using surface-anchored nanoparticles," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    4. Fang, Bin & Lü, Tao & Li, Wei & Moultos, Othonas A. & Vlugt, Thijs J.H. & Ning, Fulong, 2024. "Microscopic insights into poly- and mono-crystalline methane hydrate dissociation in Na-montmorillonite pores at static and dynamic fluid conditions," Energy, Elsevier, vol. 288(C).
    5. Mu, Liang & Tan, Qiqi & Li, Xianlong & Zhang, Qingyun & Cui, Qingyan, 2023. "A novel method to store methane by forming hydrate in the high water-oil ratio emulsions," Energy, Elsevier, vol. 264(C).
    6. Xie, Yan & Zheng, Tao & Zhong, Jin-Rong & Zhu, Yu-Jie & Wang, Yun-Fei & Zhang, Yu & Li, Rui & Yuan, Qing & Sun, Chang-Yu & Chen, Guang-Jin, 2020. "Experimental research on self-preservation effect of methane hydrate in porous sediments," Applied Energy, Elsevier, vol. 268(C).
    7. Wang, Pengfei & Teng, Ying & Zhu, Jinlong & Bao, Wancheng & Han, Songbai & Li, Yun & Zhao, Yusheng & Xie, Heping, 2022. "Review on the synergistic effect between metal–organic frameworks and gas hydrates for CH4 storage and CO2 separation applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 167(C).
    8. Xiao, Peng & Dong, Bao-Can & Li, Jia & Zhang, Hong-Liang & Chen, Guang-Jin & Sun, Chang-Yu & Huang, Xing, 2022. "An approach to highly efficient filtration of methane hydrate slurry for the continuous hydrate production," Energy, Elsevier, vol. 259(C).
    9. Veluswamy, Hari Prakash & Kumar, Asheesh & Kumar, Rajnish & Linga, Praveen, 2017. "An innovative approach to enhance methane hydrate formation kinetics with leucine for energy storage application," Applied Energy, Elsevier, vol. 188(C), pages 190-199.
    10. Wang, Yiwei & Deng, Ye & Guo, Xuqiang & Sun, Qiang & Liu, Aixian & Zhang, Guangqing & Yue, Gang & Yang, Lanying, 2018. "Experimental and modeling investigation on separation of methane from coal seam gas (CSG) using hydrate formation," Energy, Elsevier, vol. 150(C), pages 377-395.
    11. Jyoti Shanker Pandey & Saad Khan & Nicolas von Solms, 2021. "Chemically Influenced Self-Preservation Kinetics of CH 4 Hydrates below the Sub-Zero Temperature," Energies, MDPI, vol. 14(20), pages 1-28, October.
    12. Zhang, Yajin & Dong, Bo & Wang, Ping & Geng, Feifan & Zhang, Lunxiang & Qin, Yan & Chen, Cong & Li, Weizhong, 2023. "Investigation of ice evolution during methane hydrate dissociation at different initial temperatures in microporous media," Energy, Elsevier, vol. 266(C).
    13. Olga Gaidukova & Sergei Misyura & Pavel Strizhak, 2022. "Key Areas of Gas Hydrates Study: Review," Energies, MDPI, vol. 15(5), pages 1-18, February.
    14. Thakre, Niraj & Jana, Amiya K., 2021. "Physical and molecular insights to Clathrate hydrate thermodynamics," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).
    15. Kang, Dong Woo & Lee, Wonhyeong & Ahn, Yun-Ho & Kim, Kwangbum & Lee, Jae W., 2024. "Facile and sustainable methane storage via clathrate hydrate formation with low dosage promoters in a sponge matrix," Energy, Elsevier, vol. 292(C).
    16. Yin, Zhenyuan & Zhang, Shuyu & Koh, Shanice & Linga, Praveen, 2020. "Estimation of the thermal conductivity of a heterogeneous CH4-hydrate bearing sample based on particle swarm optimization," Applied Energy, Elsevier, vol. 271(C).
    17. Ge, Bin-Bin & Li, Xi-Yue & Zhong, Dong-Liang & Lu, Yi-Yu, 2022. "Investigation of natural gas storage and transportation by gas hydrate formation in the presence of bio-surfactant sulfonated lignin," Energy, Elsevier, vol. 244(PA).
    18. Judit Farrando-Perez & Rafael Balderas-Xicohtencatl & Yongqiang Cheng & Luke Daemen & Carlos Cuadrado-Collados & Manuel Martinez-Escandell & Anibal J. Ramirez-Cuesta & Joaquin Silvestre-Albero, 2022. "Rapid and efficient hydrogen clathrate hydrate formation in confined nanospace," Nature Communications, Nature, vol. 13(1), pages 1-6, December.
    19. Bhattacharjee, Gaurav & Prakash Veluswamy, Hari & Kumar, Rajnish & Linga, Praveen, 2020. "Rapid methane storage via sII hydrates at ambient temperature," Applied Energy, Elsevier, vol. 269(C).
    20. Xu, Jiuping & Tang, Min & Liu, Tingting & Fan, Lurong, 2024. "Technological paradigm-based development strategy towards natural gas hydrate technology," Energy, Elsevier, vol. 289(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:235:y:2019:i:c:p:21-30. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.