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Theoretical modeling of the gas humidification effect on the characteristics of proton ceramic fuel cells

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  • Putilov, L.P.
  • Demin, A.K.
  • Tsidilkovski, V.I.
  • Tsiakaras, P.

Abstract

Proton ceramic fuel cells are promising electrochemical converters that produce electrical energy by oxidizing hydrogen. Understanding the impact of gas humidification on the characteristics of such fuel cells is pivotal for the development of high-performance devices. This study develops a theory elucidating the effect of hydrogen and air humidity on the output characteristics of fuel cells based on proton-conducting oxide membrane with mixed (proton and hole) conductivity. The theory is based on a self-consistent description of the strong non-uniform distribution of charge carriers inside the membrane and the variation of the gas phase composition along the fuel and air channels. It is shown that the total current density significantly and nonmonotonously depends on humidity of the inlet hydrogen fuel, while humidification of the inlet air has minor effect on the fuel cell characteristics. The influence of the anode and cathode gas humidity on the distribution of the various fuel cell parameters (current densities, resistivity, etc.) along the membrane is also determined. The obtained results reveal the possibility of enhancing the performance of the proton ceramic fuel cells with low polarization losses by optimizing the composition of the inlet hydrogen fuel.

Suggested Citation

  • Putilov, L.P. & Demin, A.K. & Tsidilkovski, V.I. & Tsiakaras, P., 2019. "Theoretical modeling of the gas humidification effect on the characteristics of proton ceramic fuel cells," Applied Energy, Elsevier, vol. 242(C), pages 1448-1459.
  • Handle: RePEc:eee:appene:v:242:y:2019:i:c:p:1448-1459
    DOI: 10.1016/j.apenergy.2019.03.096
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    References listed on IDEAS

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    1. Andersson, Martin & Yuan, Jinliang & Sundén, Bengt, 2010. "Review on modeling development for multiscale chemical reactions coupled transport phenomena in solid oxide fuel cells," Applied Energy, Elsevier, vol. 87(5), pages 1461-1476, May.
    2. Shaikh, Shabana P.S. & Muchtar, Andanastuti & Somalu, Mahendra R., 2015. "A review on the selection of anode materials for solid-oxide fuel cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 51(C), pages 1-8.
    3. Menon, Vikram & Banerjee, Aayan & Dailly, Julian & Deutschmann, Olaf, 2015. "Numerical analysis of mass and heat transport in proton-conducting SOFCs with direct internal reforming," Applied Energy, Elsevier, vol. 149(C), pages 161-175.
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    1. Lei, Libin & Mo, Yingyu & Huang, Yue & Qiu, Ruiming & Tian, Zhipeng & Wang, Junyao & Liu, Jianping & Chen, Ying & Zhang, Jihao & Tao, Zetian & Liang, Bo & Wang, Chao, 2023. "Revealing and quantifying the role of oxygen-ionic current in proton-conducting solid oxide fuel cells: A modeling study," Energy, Elsevier, vol. 276(C).

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