IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v240y2019icp215-225.html
   My bibliography  Save this article

Gas hydrate exploitation using CO2/H2 mixture gas by semi-continuous injection-production mode

Author

Listed:
  • Sun, Yi-Fei
  • Wang, Yun-Fei
  • Zhong, Jin-Rong
  • Li, Wen-Zhi
  • Li, Rui
  • Cao, Bo-Jian
  • Kan, Jing-Yu
  • Sun, Chang-Yu
  • Chen, Guang-Jin

Abstract

The CO2 replacement technique is considered as a promising approach for both gas hydrate recovery and CO2 sequestration. Based on this technique, the continuous CO2/H2 injection-production mode had been studied in our previous work. However, there are limitations on this continuous mode, such as lower CH4 recovery and CO2 sequestration ratios, lower CH4 concentration in produced gas and higher injection-production ratio caused by the fast breakthrough of injected gas. Here we proposed a so called semi-continuous injection-production mode, in which continuous injection-production process is interrupted periodically by stopping injection and production operations for letting injected gas diffuse sufficiently, delaying its breakthrough and increasing its effective sweep region. A series of experimental simulations were performed with respect to this mode in a three-dimensional simulator with a volume of 10.6 L. The results indicated that for the injected gas with low CO2 concentration, the CH4 recovery and concentration in the produced gas could be enhanced dramatically by the semi-continuous gas injection method. Additionally, the fast decomposition stage of CH4 hydrate could be retained separately in the replacement process, thereby effectively improving production efficiency. However, the corresponding CH4 concentration in the produced gas decreased and the injection production ratio increased. Notably, the process combining the CH4 steam reforming with cyclic injection-production was first simulated. The results showed an excellent CO2 storage capability and CH4 hydrate recovery ratio, which was mainly controlled by the gas composition of the re-injected gas. Through systematically comparing and analyzing the CH4 concentration, recovery ratio, production efficiency and injection-production ratio, it is demonstrated that the semi-continuous injection-production mode is superior to the continuous one. The results obtained in this work are of significance for guiding future NGHs exploitation.

Suggested Citation

  • Sun, Yi-Fei & Wang, Yun-Fei & Zhong, Jin-Rong & Li, Wen-Zhi & Li, Rui & Cao, Bo-Jian & Kan, Jing-Yu & Sun, Chang-Yu & Chen, Guang-Jin, 2019. "Gas hydrate exploitation using CO2/H2 mixture gas by semi-continuous injection-production mode," Applied Energy, Elsevier, vol. 240(C), pages 215-225.
    • Handle: RePEc:eee:appene:v:240:y:2019:i:c:p:215-225
    DOI: 10.1016/j.apenergy.2019.01.209
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261919302302
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2019.01.209?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Xu, Chun-Gang & Cai, Jing & Yu, Yi-Song & Yan, Ke-Feng & Li, Xiao-Sen, 2018. "Effect of pressure on methane recovery from natural gas hydrates by methane-carbon dioxide replacement," Applied Energy, Elsevier, vol. 217(C), pages 527-536.
    2. Huen Lee & Jong-won Lee & Do Youn Kim & Jeasung Park & Yu-Taek Seo & Huang Zeng & Igor L. Moudrakovski & Christopher I. Ratcliffe & John A. Ripmeester, 2005. "Tuning clathrate hydrates for hydrogen storage," Nature, Nature, vol. 434(7034), pages 743-746, April.
    3. Veluswamy, Hari Prakash & Kumar, Asheesh & Seo, Yutaek & Lee, Ju Dong & Linga, Praveen, 2018. "A review of solidified natural gas (SNG) technology for gas storage via clathrate hydrates," Applied Energy, Elsevier, vol. 216(C), pages 262-285.
    4. Wang, Xiao-Hui & Sun, Yi-Fei & Wang, Yun-Fei & Li, Nan & Sun, Chang-Yu & Chen, Guang-Jin & Liu, Bei & Yang, Lan-Ying, 2017. "Gas production from hydrates by CH4-CO2/H2 replacement," Applied Energy, Elsevier, vol. 188(C), pages 305-314.
    5. Yuan, Qing & Sun, Chang-Yu & Yang, Xin & Ma, Ping-Chuan & Ma, Zheng-Wei & Liu, Bei & Ma, Qing-Lan & Yang, Lan-Ying & Chen, Guang-Jin, 2012. "Recovery of methane from hydrate reservoir with gaseous carbon dioxide using a three-dimensional middle-size reactor," Energy, Elsevier, vol. 40(1), pages 47-58.
    6. E. Dendy Sloan, 2003. "Fundamental principles and applications of natural gas hydrates," Nature, Nature, vol. 426(6964), pages 353-359, November.
    7. Lee, Yohan & Kim, Yunju & Lee, Jaehyoung & Lee, Huen & Seo, Yongwon, 2015. "CH4 recovery and CO2 sequestration using flue gas in natural gas hydrates as revealed by a micro-differential scanning calorimeter," Applied Energy, Elsevier, vol. 150(C), pages 120-127.
    8. Li, Bo & Liu, Sheng-Dong & Liang, Yun-Pei & Liu, Hang, 2018. "The use of electrical heating for the enhancement of gas recovery from methane hydrate in porous media," Applied Energy, Elsevier, vol. 227(C), pages 694-702.
    9. Sun, Yi-Fei & Zhong, Jin-Rong & Li, Rui & Zhu, Tao & Cao, Xin-Yi & Chen, Guang-Jin & Wang, Xiao-Hui & Yang, Lan-Ying & Sun, Chang-Yu, 2018. "Natural gas hydrate exploitation by CO2/H2 continuous Injection-Production mode," Applied Energy, Elsevier, vol. 226(C), pages 10-21.
    10. Chong, Zheng Rong & Yin, Zhenyuan & Tan, Jun Hao Clifton & Linga, Praveen, 2017. "Experimental investigations on energy recovery from water-saturated hydrate bearing sediments via depressurization approach," Applied Energy, Elsevier, vol. 204(C), pages 1513-1525.
    11. Seo, Young-ju & Park, Seongmin & Kang, Hyery & Ahn, Yun-Ho & Lim, Dongwook & Kim, Se-Joon & Lee, Jaehyoung & Lee, Joo Yong & Ahn, Taewoong & Seo, Yongwon & Lee, Huen, 2016. "Isostructural and cage-specific replacement occurring in sII hydrate with external CO2/N2 gas and its implications for natural gas production and CO2 storage," Applied Energy, Elsevier, vol. 178(C), pages 579-586.
    12. Chong, Zheng Rong & Yang, She Hern Bryan & Babu, Ponnivalavan & Linga, Praveen & Li, Xiao-Sen, 2016. "Review of natural gas hydrates as an energy resource: Prospects and challenges," Applied Energy, Elsevier, vol. 162(C), pages 1633-1652.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Ren, Liang-Liang & Jiang, Min & Wang, Ling-Ban & Zhu, Yi-Jian & Li, Zhi & Sun, Chang-Yu & Chen, Guang-Jin, 2020. "Gas hydrate exploitation and carbon dioxide sequestration under maintaining the stiffness of hydrate-bearing sediments," Energy, Elsevier, vol. 194(C).
    2. Wang, Xiaolin & Zhang, Fengyuan & Lipiński, Wojciech, 2020. "Research progress and challenges in hydrate-based carbon dioxide capture applications," Applied Energy, Elsevier, vol. 269(C).
    3. Sun, Yi-Fei & Zhong, Jin-Rong & Chen, Guang-Jin & Cao, Bo-Jian & Li, Rui & Chen, Dao-Yi, 2021. "A new approach to efficient and safe gas production from unsealed marine hydrate deposits," Applied Energy, Elsevier, vol. 282(PB).
    4. Xie, Yan & Zhu, Yu-Jie & Cheng, Li-Wei & Zheng, Tao & Zhong, Jin-Rong & Xiao, Peng & Sun, Chang-Yu & Chen, Guang-Jin & Feng, Jing-Chun, 2023. "The coexistence of multiple hydrates triggered by varied H2 molecule occupancy during CO2/H2 hydrate dissociation," Energy, Elsevier, vol. 262(PA).
    5. Aminnaji, Morteza & Qureshi, M Fahed & Dashti, Hossein & Hase, Alfred & Mosalanejad, Abdolali & Jahanbakhsh, Amir & Babaei, Masoud & Amiri, Amirpiran & Maroto-Valer, Mercedes, 2024. "CO2 Gas hydrate for carbon capture and storage applications – Part 1," Energy, Elsevier, vol. 300(C).
    6. Yulia Zaripova & Vladimir Yarkovoi & Mikhail Varfolomeev & Rail Kadyrov & Andrey Stoporev, 2021. "Influence of Water Saturation, Grain Size of Quartz Sand and Hydrate-Former on the Gas Hydrate Formation," Energies, MDPI, vol. 14(5), pages 1-15, February.
    7. Chaturvedi, Krishna Raghav & Sinha, A.S.K. & Nair, Vishnu Chandrasekharan & Sharma, Tushar, 2021. "Enhanced carbon dioxide sequestration by direct injection of flue gas doped with hydrogen into hydrate reservoir: Possibility of natural gas production," Energy, Elsevier, vol. 227(C).
    8. Xie, Yan & Zheng, Tao & Zhong, Jin-Rong & Zhu, Yu-Jie & Wang, Yun-Fei & Zhang, Yu & Li, Rui & Yuan, Qing & Sun, Chang-Yu & Chen, Guang-Jin, 2020. "Experimental research on self-preservation effect of methane hydrate in porous sediments," Applied Energy, Elsevier, vol. 268(C).
    9. Li, Bo & Zhang, Ting-Ting & Wan, Qing-Cui & Feng, Jing-Chun & Chen, Ling-Ling & Wei, Wen-Na, 2021. "Kinetic study of methane hydrate development involving the role of self-preservation effect in frozen sandy sediments," Applied Energy, Elsevier, vol. 300(C).
    10. Zhong, Jin-Rong & Sun, Yi-Fei & Li, Wen-Zhi & Xie, Yan & Chen, Guang-Jin & Sun, Chang-Yu & Yang, Lan-Ying & Qin, Hui-Bo & Pang, Wei-Xin & Li, Qing-Ping, 2019. "Structural transition range of methane-ethane gas hydrates during decomposition below ice point," Applied Energy, Elsevier, vol. 250(C), pages 873-881.
    11. Aminnaji, Morteza & Qureshi, M Fahed & Dashti, Hossein & Hase, Alfred & Mosalanejad, Abdolali & Jahanbakhsh, Amir & Babaei, Masoud & Amiri, Amirpiran & Maroto-Valer, Mercedes, 2024. "CO2 gas hydrate for carbon capture and storage applications – Part 2," Energy, Elsevier, vol. 300(C).
    12. Zhu, Yi-Jian & Chu, Yan-Song & Huang, Xing & Wang, Ling-Ban & Wang, Xiao-Hui & Xiao, Peng & Sun, Yi-Fei & Pang, Wei-Xin & Li, Qing-Ping & Sun, Chang-Yu & Chen, Guang-Jin, 2023. "Stability of hydrate-bearing sediment during methane hydrate production by depressurization or intermittent CO2/N2 injection," Energy, Elsevier, vol. 269(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Ren, Liang-Liang & Qi, Ya-Hui & Chen, Jun-Li & Sun, Yi-Fei & Sun, Chang-Yu & Wang, Xiao-Hui & Chen, Guang-Jin & Yuan, Qing & Pang, Wei-Xin & Li, Qing-Ping, 2020. "Dependence of acoustic properties on hydrate-bearing sediments with heterogeneous distribution," Applied Energy, Elsevier, vol. 275(C).
    2. Sergey Misyura & Pavel Strizhak & Anton Meleshkin & Vladimir Morozov & Olga Gaidukova & Nikita Shlegel & Maria Shkola, 2023. "A Review of Gas Capture and Liquid Separation Technologies by CO 2 Gas Hydrate," Energies, MDPI, vol. 16(8), pages 1-20, April.
    3. Gajanan, K. & Ranjith, P.G. & Yang, S.Q. & Xu, T., 2024. "Advances in research and developments on natural gas hydrate extraction with gas exchange," Renewable and Sustainable Energy Reviews, Elsevier, vol. 190(PB).
    4. Sun, Yi-Fei & Zhong, Jin-Rong & Li, Rui & Zhu, Tao & Cao, Xin-Yi & Chen, Guang-Jin & Wang, Xiao-Hui & Yang, Lan-Ying & Sun, Chang-Yu, 2018. "Natural gas hydrate exploitation by CO2/H2 continuous Injection-Production mode," Applied Energy, Elsevier, vol. 226(C), pages 10-21.
    5. Sun, You-Hong & Zhang, Guo-Biao & Carroll, John J. & Li, Sheng-Li & Jiang, Shu-Hui & Guo, Wei, 2018. "Experimental investigation into gas recovery from CH4-C2H6-C3H8 hydrates by CO2 replacement," Applied Energy, Elsevier, vol. 229(C), pages 625-636.
    6. Zhu, Yi-Jian & Chu, Yan-Song & Huang, Xing & Wang, Ling-Ban & Wang, Xiao-Hui & Xiao, Peng & Sun, Yi-Fei & Pang, Wei-Xin & Li, Qing-Ping & Sun, Chang-Yu & Chen, Guang-Jin, 2023. "Stability of hydrate-bearing sediment during methane hydrate production by depressurization or intermittent CO2/N2 injection," Energy, Elsevier, vol. 269(C).
    7. Wang, Xiaolin & Zhang, Fengyuan & Lipiński, Wojciech, 2020. "Research progress and challenges in hydrate-based carbon dioxide capture applications," Applied Energy, Elsevier, vol. 269(C).
    8. Olga Gaidukova & Sergey Misyura & Vladimir Morozov & Pavel Strizhak, 2023. "Gas Hydrates: Applications and Advantages," Energies, MDPI, vol. 16(6), pages 1-19, March.
    9. Chen, Xuyue & Yang, Jin & Gao, Deli & Hong, Yuqun & Zou, Yiqi & Du, Xu, 2020. "Unlocking the deepwater natural gas hydrate's commercial potential with extended reach wells from shallow water: Review and an innovative method," Renewable and Sustainable Energy Reviews, Elsevier, vol. 134(C).
    10. Ma, Shihui & Zheng, Jia-nan & Tang, Dawei & Lv, Xin & Li, Qingping & Yang, Mingjun, 2019. "Experimental investigation on the decomposition characteristics of natural gas hydrates in South China Sea sediments by a micro-differential scanning calorimeter," Applied Energy, Elsevier, vol. 254(C).
    11. Xie, Yan & Zhu, Yu-Jie & Cheng, Li-Wei & Zheng, Tao & Zhong, Jin-Rong & Xiao, Peng & Sun, Chang-Yu & Chen, Guang-Jin & Feng, Jing-Chun, 2023. "The coexistence of multiple hydrates triggered by varied H2 molecule occupancy during CO2/H2 hydrate dissociation," Energy, Elsevier, vol. 262(PA).
    12. Sun, Yi-Fei & Zhong, Jin-Rong & Chen, Guang-Jin & Cao, Bo-Jian & Li, Rui & Chen, Dao-Yi, 2021. "A new approach to efficient and safe gas production from unsealed marine hydrate deposits," Applied Energy, Elsevier, vol. 282(PB).
    13. Wang, Yiwei & Deng, Ye & Guo, Xuqiang & Sun, Qiang & Liu, Aixian & Zhang, Guangqing & Yue, Gang & Yang, Lanying, 2018. "Experimental and modeling investigation on separation of methane from coal seam gas (CSG) using hydrate formation," Energy, Elsevier, vol. 150(C), pages 377-395.
    14. Wan, Qing-Cui & Yin, Zhenyuan & Gao, Qiang & Si, Hu & Li, Bo & Linga, Praveen, 2022. "Fluid production behavior from water-saturated hydrate-bearing sediments below the quadruple point of CH4 + H2O," Applied Energy, Elsevier, vol. 305(C).
    15. Ren, Liang-Liang & Jiang, Min & Wang, Ling-Ban & Zhu, Yi-Jian & Li, Zhi & Sun, Chang-Yu & Chen, Guang-Jin, 2020. "Gas hydrate exploitation and carbon dioxide sequestration under maintaining the stiffness of hydrate-bearing sediments," Energy, Elsevier, vol. 194(C).
    16. Yin, Zhenyuan & Zhang, Shuyu & Koh, Shanice & Linga, Praveen, 2020. "Estimation of the thermal conductivity of a heterogeneous CH4-hydrate bearing sample based on particle swarm optimization," Applied Energy, Elsevier, vol. 271(C).
    17. Wang, Xiao-Hui & Sun, Yi-Fei & Wang, Yun-Fei & Li, Nan & Sun, Chang-Yu & Chen, Guang-Jin & Liu, Bei & Yang, Lan-Ying, 2017. "Gas production from hydrates by CH4-CO2/H2 replacement," Applied Energy, Elsevier, vol. 188(C), pages 305-314.
    18. Cui, Jin-Long & Cheng, Li-Wei & Kan, Jing-Yu & Pang, Wei-Xin & Gu, Jun-Nan & Li, Kun & Wang, Ling-Ban & Sun, Chang-Yu & Wang, Xiao-Hui & Chen, Guang-Jin & Li, Xing-Xun, 2021. "Study on the spatial differences of methane hydrate dissociation process by depressurization using an L-shape simulator," Energy, Elsevier, vol. 228(C).
    19. Thakre, Niraj & Jana, Amiya K., 2017. "Modeling phase equilibrium with a modified Wong-Sandler mixing rule for natural gas hydrates: Experimental validation," Applied Energy, Elsevier, vol. 205(C), pages 749-760.
    20. Xu, Chun-Gang & Cai, Jing & Yu, Yi-Song & Yan, Ke-Feng & Li, Xiao-Sen, 2018. "Effect of pressure on methane recovery from natural gas hydrates by methane-carbon dioxide replacement," Applied Energy, Elsevier, vol. 217(C), pages 527-536.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:240:y:2019:i:c:p:215-225. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.