IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v18y2025i4p975-d1593529.html
   My bibliography  Save this article

Gas Production and Storage Using Hydrates Through the Replacement of Multicomponent Gases: A Critical Review

Author

Listed:
  • Zhiyuan Zhu

    (School of Energy and Power Engineering, North University of China, Taiyuan 030051, China)

  • Xiaoya Zhao

    (School of Energy and Power Engineering, North University of China, Taiyuan 030051, China)

  • Sijia Wang

    (Hebei Engineering Research Center of Advanced Energy Storage Technology and Equipment, School of Energy and Environmental Engineering, Hebei University of Technology, Tianjin 300401, China)

  • Lanlan Jiang

    (Key Laboratory of Ocean Energy Utilization and Energy Conservation of Ministry of Education, Dalian University of Technology, Dalian 116024, China)

  • Hongsheng Dong

    (School of Marine Science and Technology, Northwestern Polytechnical University, Xi’an 710072, China
    National Innovation Platform (Center) for Industry-Education Integration of Energy Storage Technology, Xi’an Jiaotong University, Xi’an 710049, China)

  • Pengfei Lv

    (School of Energy and Power Engineering, North University of China, Taiyuan 030051, China
    Key Laboratory of Shanxi Province for Solar Thermal Technology, Taiyuan 030051, China)

Abstract

With the continuous growth of global energy demand and the gradual depletion of traditional fossil energy reserves, natural gas hydrates have attracted widespread attention as a potential clean energy source due to their vast reserves and wide distribution. Although various extraction methods, including depressurization, thermal stimulation, chemical inhibitors, and displacement methods, have been proposed, there are still challenges, such as low extraction efficiency, poor sustainability, and high costs, making it difficult to achieve large-scale engineering applications. Among these, the use of gases such as CO 2 for displacement extraction of natural gas hydrates can both develop hydrate resources and sequester CO 2 , achieving a win–win situation for resource development and greenhouse gas reduction. This paper provides a detailed review of the multi-gas displacement extraction technology for natural gas hydrates, systematically summarizes the latest progress in thermodynamic and kinetic studies, analyzes the technical advantages and feasibility of combining displacement methods with traditional techniques, and explores the effects of multi-gas mixtures, such as N 2 , CO 2 , and H 2 , and their ratios on hydrate extraction efficiency. Finally, this paper summarizes the technical challenges faced by displacement extraction methods for hydrates and offers future research directions to promote the development of multi-gas displacement technology for natural gas hydrates.

Suggested Citation

  • Zhiyuan Zhu & Xiaoya Zhao & Sijia Wang & Lanlan Jiang & Hongsheng Dong & Pengfei Lv, 2025. "Gas Production and Storage Using Hydrates Through the Replacement of Multicomponent Gases: A Critical Review," Energies, MDPI, vol. 18(4), pages 1-31, February.
    • Handle: RePEc:gam:jeners:v:18:y:2025:i:4:p:975-:d:1593529
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/18/4/975/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/18/4/975/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Choi, Wonjung & Mok, Junghoon & Lee, Jonghyuk & Lee, Yohan & Lee, Jaehyoung & Sum, Amadeu K. & Seo, Yongwon, 2022. "Effective CH4 production and novel CO2 storage through depressurization-assisted replacement in natural gas hydrate-bearing sediment," Applied Energy, Elsevier, vol. 326(C).
    2. Wan, Kun & Wang, Yi & Li, Xiao-Sen & Zhang, Long-Hai & Meng, Te, 2024. "Pilot-scale experimental study on natural gas hydrate decomposition with innovation depressurization modes," Applied Energy, Elsevier, vol. 373(C).
    3. Chaturvedi, Krishna Raghav & Sinha, A.S.K. & Nair, Vishnu Chandrasekharan & Sharma, Tushar, 2021. "Enhanced carbon dioxide sequestration by direct injection of flue gas doped with hydrogen into hydrate reservoir: Possibility of natural gas production," Energy, Elsevier, vol. 227(C).
    4. Ding, Ya-Long & Xu, Chun-Gang & Yu, Yi-Song & Li, Xiao-Sen, 2017. "Methane recovery from natural gas hydrate with simulated IGCC syngas," Energy, Elsevier, vol. 120(C), pages 192-198.
    5. Kuang, Yangmin & Zhang, Lunxiang & Zheng, Yanpeng, 2022. "Enhanced CO2 sequestration based on hydrate technology with pressure oscillation in porous medium using NMR," Energy, Elsevier, vol. 252(C).
    6. Sun, Yi-Fei & Zhong, Jin-Rong & Li, Rui & Zhu, Tao & Cao, Xin-Yi & Chen, Guang-Jin & Wang, Xiao-Hui & Yang, Lan-Ying & Sun, Chang-Yu, 2018. "Natural gas hydrate exploitation by CO2/H2 continuous Injection-Production mode," Applied Energy, Elsevier, vol. 226(C), pages 10-21.
    7. Seo, Young-ju & Park, Seongmin & Kang, Hyery & Ahn, Yun-Ho & Lim, Dongwook & Kim, Se-Joon & Lee, Jaehyoung & Lee, Joo Yong & Ahn, Taewoong & Seo, Yongwon & Lee, Huen, 2016. "Isostructural and cage-specific replacement occurring in sII hydrate with external CO2/N2 gas and its implications for natural gas production and CO2 storage," Applied Energy, Elsevier, vol. 178(C), pages 579-586.
    8. Lee, Yohan & Deusner, Christian & Kossel, Elke & Choi, Wonjung & Seo, Yongwon & Haeckel, Matthias, 2020. "Influence of CH4 hydrate exploitation using depressurization and replacement methods on mechanical strength of hydrate-bearing sediment," Applied Energy, Elsevier, vol. 277(C).
    9. Koh, Dong-Yeun & Kang, Hyery & Lee, Jong-Won & Park, Youngjune & Kim, Se-Joon & Lee, Jaehyoung & Lee, Joo Yong & Lee, Huen, 2016. "Energy-efficient natural gas hydrate production using gas exchange," Applied Energy, Elsevier, vol. 162(C), pages 114-130.
    10. Wang, Xiao-Hui & Sun, Yi-Fei & Wang, Yun-Fei & Li, Nan & Sun, Chang-Yu & Chen, Guang-Jin & Liu, Bei & Yang, Lan-Ying, 2017. "Gas production from hydrates by CH4-CO2/H2 replacement," Applied Energy, Elsevier, vol. 188(C), pages 305-314.
    11. Ma, Z.W. & Zhang, P. & Bao, H.S. & Deng, S., 2016. "Review of fundamental properties of CO2 hydrates and CO2 capture and separation using hydration method," Renewable and Sustainable Energy Reviews, Elsevier, vol. 53(C), pages 1273-1302.
    12. Lee, Yohan & Kim, Yunju & Lee, Jaehyoung & Lee, Huen & Seo, Yongwon, 2015. "CH4 recovery and CO2 sequestration using flue gas in natural gas hydrates as revealed by a micro-differential scanning calorimeter," Applied Energy, Elsevier, vol. 150(C), pages 120-127.
    13. Xie, Weidong & Wang, Hua & Vandeginste, Veerle & Chen, Si & Gan, Huajun & Wang, Meng & Yu, Zhenghong, 2023. "Thermodynamic and kinetic affinity of CO2 relative to CH4 and their pressure, temperature and pore structure sensitivity in the competitive adsorption system in shale gas reservoirs," Energy, Elsevier, vol. 277(C).
    14. Sun, Yi-Fei & Wang, Yun-Fei & Zhong, Jin-Rong & Li, Wen-Zhi & Li, Rui & Cao, Bo-Jian & Kan, Jing-Yu & Sun, Chang-Yu & Chen, Guang-Jin, 2019. "Gas hydrate exploitation using CO2/H2 mixture gas by semi-continuous injection-production mode," Applied Energy, Elsevier, vol. 240(C), pages 215-225.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Wang, Xiaolin & Zhang, Fengyuan & Lipiński, Wojciech, 2020. "Research progress and challenges in hydrate-based carbon dioxide capture applications," Applied Energy, Elsevier, vol. 269(C).
    2. Gajanan, K. & Ranjith, P.G. & Yang, S.Q. & Xu, T., 2024. "Advances in research and developments on natural gas hydrate extraction with gas exchange," Renewable and Sustainable Energy Reviews, Elsevier, vol. 190(PB).
    3. Sergey Misyura & Pavel Strizhak & Anton Meleshkin & Vladimir Morozov & Olga Gaidukova & Nikita Shlegel & Maria Shkola, 2023. "A Review of Gas Capture and Liquid Separation Technologies by CO 2 Gas Hydrate," Energies, MDPI, vol. 16(8), pages 1-20, April.
    4. Xie, Yan & Zhu, Yu-Jie & Cheng, Li-Wei & Zheng, Tao & Zhong, Jin-Rong & Xiao, Peng & Sun, Chang-Yu & Chen, Guang-Jin & Feng, Jing-Chun, 2023. "The coexistence of multiple hydrates triggered by varied H2 molecule occupancy during CO2/H2 hydrate dissociation," Energy, Elsevier, vol. 262(PA).
    5. Ouyang, Q. & Pandey, J.S. & Xu, Y. & von Solms, N., 2024. "Fundamental insights into multistep depressurization of CH4/CO2 hydrates in the presence of N2 or air," Renewable and Sustainable Energy Reviews, Elsevier, vol. 203(C).
    6. Sun, Yi-Fei & Zhong, Jin-Rong & Li, Rui & Zhu, Tao & Cao, Xin-Yi & Chen, Guang-Jin & Wang, Xiao-Hui & Yang, Lan-Ying & Sun, Chang-Yu, 2018. "Natural gas hydrate exploitation by CO2/H2 continuous Injection-Production mode," Applied Energy, Elsevier, vol. 226(C), pages 10-21.
    7. Sun, Yi-Fei & Zhong, Jin-Rong & Chen, Guang-Jin & Cao, Bo-Jian & Li, Rui & Chen, Dao-Yi, 2021. "A new approach to efficient and safe gas production from unsealed marine hydrate deposits," Applied Energy, Elsevier, vol. 282(PB).
    8. Sun, Yi-Fei & Wang, Yun-Fei & Zhong, Jin-Rong & Li, Wen-Zhi & Li, Rui & Cao, Bo-Jian & Kan, Jing-Yu & Sun, Chang-Yu & Chen, Guang-Jin, 2019. "Gas hydrate exploitation using CO2/H2 mixture gas by semi-continuous injection-production mode," Applied Energy, Elsevier, vol. 240(C), pages 215-225.
    9. Zhong, Jin-Rong & Sun, Yi-Fei & Li, Wen-Zhi & Xie, Yan & Chen, Guang-Jin & Sun, Chang-Yu & Yang, Lan-Ying & Qin, Hui-Bo & Pang, Wei-Xin & Li, Qing-Ping, 2019. "Structural transition range of methane-ethane gas hydrates during decomposition below ice point," Applied Energy, Elsevier, vol. 250(C), pages 873-881.
    10. Aminnaji, Morteza & Qureshi, M Fahed & Dashti, Hossein & Hase, Alfred & Mosalanejad, Abdolali & Jahanbakhsh, Amir & Babaei, Masoud & Amiri, Amirpiran & Maroto-Valer, Mercedes, 2024. "CO2 Gas hydrate for carbon capture and storage applications – Part 1," Energy, Elsevier, vol. 300(C).
    11. Sun, You-Hong & Zhang, Guo-Biao & Carroll, John J. & Li, Sheng-Li & Jiang, Shu-Hui & Guo, Wei, 2018. "Experimental investigation into gas recovery from CH4-C2H6-C3H8 hydrates by CO2 replacement," Applied Energy, Elsevier, vol. 229(C), pages 625-636.
    12. Chen, Xuejun & Lu, Hailong & Gu, Lijuan & Shang, Shilong & Zhang, Yi & Huang, Xin & Zhang, Le, 2022. "Preliminary evaluation of the economic potential of the technologies for gas hydrate exploitation," Energy, Elsevier, vol. 243(C).
    13. Lee, Yohan & Choi, Wonjung & Seo, Young-ju & Lee, Joo Yong & Lee, Jaehyoung & Seo, Yongwon, 2018. "Structural transition induced by cage-dependent guest exchange in CH4 + C3H8 hydrates with CO2 injection for energy recovery and CO2 sequestration," Applied Energy, Elsevier, vol. 228(C), pages 229-239.
    14. Wang, Xiao-Hui & Sun, Yi-Fei & Wang, Yun-Fei & Li, Nan & Sun, Chang-Yu & Chen, Guang-Jin & Liu, Bei & Yang, Lan-Ying, 2017. "Gas production from hydrates by CH4-CO2/H2 replacement," Applied Energy, Elsevier, vol. 188(C), pages 305-314.
    15. Wang, Shuai & Sun, Huilian & Liu, Huiquan & Xi, Dezhi & Long, Jiayi & Zhang, Lunxiang & Zhao, Jiafei & Song, Yongchen & Shi, Changrui & Ling, Zheng, 2024. "Novel vermiculite/tannic acid composite aerogels with outstanding CO2 storage via enhanced gas hydrate formation," Energy, Elsevier, vol. 289(C).
    16. Zheng, Junjie & Zhang, Peng & Linga, Praveen, 2017. "Semiclathrate hydrate process for pre-combustion capture of CO2 at near ambient temperatures," Applied Energy, Elsevier, vol. 194(C), pages 267-278.
    17. Mok, Junghoon & Choi, Wonjung & Lee, Jonghyuk & Seo, Yongwon, 2022. "Effects of pressure and temperature conditions on thermodynamic and kinetic guest exchange behaviors of CH4 − CO2 + N2 replacement for energy recovery and greenhouse gas storage," Energy, Elsevier, vol. 239(PB).
    18. Olga Gaidukova & Sergey Misyura & Vladimir Morozov & Pavel Strizhak, 2023. "Gas Hydrates: Applications and Advantages," Energies, MDPI, vol. 16(6), pages 1-19, March.
    19. Zhu, Yi-Jian & Chu, Yan-Song & Huang, Xing & Wang, Ling-Ban & Wang, Xiao-Hui & Xiao, Peng & Sun, Yi-Fei & Pang, Wei-Xin & Li, Qing-Ping & Sun, Chang-Yu & Chen, Guang-Jin, 2023. "Stability of hydrate-bearing sediment during methane hydrate production by depressurization or intermittent CO2/N2 injection," Energy, Elsevier, vol. 269(C).
    20. Thakre, Niraj & Jana, Amiya K., 2017. "Modeling phase equilibrium with a modified Wong-Sandler mixing rule for natural gas hydrates: Experimental validation," Applied Energy, Elsevier, vol. 205(C), pages 749-760.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:18:y:2025:i:4:p:975-:d:1593529. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.