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Real-time monitoring of removal of trace compounds with PTR-MS: Biochar experimental investigation

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  • Papurello, Davide
  • Boschetti, Andrea
  • Silvestri, Silvia
  • Khomenko, Iuliia
  • Biasioli, Franco

Abstract

The removal of trace compounds contained in a biogas from the dry anaerobic digestion of organic waste was accomplished. The resulting data were monitored online with a direct injection mass spectrometry technique. Biochar from the pyrolysis of recovered wood waste was used as sorbent material. This material was selected to demonstrate the usefulness of recovered waste for the energy production purposes. Biochar withstands the removal of 2-butanone (158.8 mg/g), toluene (140.1 mg/g) and limonene (64 mg/g) better compared to sulfur (H2S 1.05 mg/g) and siloxane (D3, 1.28 mg/g) compounds. Hydrogen sulfide was the most abundant sulfur compound with the average concentration about 24 ppm(v). The tested sorbent material was able to withstand the H2S and siloxane concentration for almost 30 h with the biogas pilot plant conditions before toachieve the limit value for SOFC applications, 1 ppm(v) and 150 ppb(v) respectively. The performance achieved with this material are comparable to some commercial carbons, even if some more optimized and selective materials show better results especially for the removal of sulfur compounds.

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  • Papurello, Davide & Boschetti, Andrea & Silvestri, Silvia & Khomenko, Iuliia & Biasioli, Franco, 2018. "Real-time monitoring of removal of trace compounds with PTR-MS: Biochar experimental investigation," Renewable Energy, Elsevier, vol. 125(C), pages 344-355.
    • Handle: RePEc:eee:renene:v:125:y:2018:i:c:p:344-355
    DOI: 10.1016/j.renene.2018.02.122
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    References listed on IDEAS

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    1. Papurello, Davide & Lanzini, Andrea & Drago, Davide & Leone, Pierluigi & Santarelli, Massimo, 2016. "Limiting factors for planar solid oxide fuel cells under different trace compound concentrations," Energy, Elsevier, vol. 95(C), pages 67-78.
    2. Papurello, D. & Borchiellini, R. & Bareschino, P. & Chiodo, V. & Freni, S. & Lanzini, A. & Pepe, F. & Ortigoza, G.A. & Santarelli, M, 2014. "Performance of a Solid Oxide Fuel Cell short-stack with biogas feeding," Applied Energy, Elsevier, vol. 125(C), pages 254-263.
    3. Papurello, Davide & Lanzini, Andrea & Tognana, Lorenzo & Silvestri, Silvia & Santarelli, Massimo, 2015. "Waste to energy: Exploitation of biogas from organic waste in a 500 Wel solid oxide fuel cell (SOFC) stack," Energy, Elsevier, vol. 85(C), pages 145-158.
    4. Papurello, Davide & Lanzini, Andrea & Leone, Pierluigi & Santarelli, Massimo, 2016. "The effect of heavy tars (toluene and naphthalene) on the electrochemical performance of an anode-supported SOFC running on bio-syngas," Renewable Energy, Elsevier, vol. 99(C), pages 747-753.
    5. Papadias, Dionissios D. & Ahmed, Shabbir & Kumar, Romesh, 2012. "Fuel quality issues with biogas energy – An economic analysis for a stationary fuel cell system," Energy, Elsevier, vol. 44(1), pages 257-277.
    6. Maghanki, Maryam Mohammadi & Ghobadian, Barat & Najafi, Gholamhassan & Galogah, Reza Janzadeh, 2013. "Micro combined heat and power (MCHP) technologies and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 28(C), pages 510-524.
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    Cited by:

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    6. Sean O’Connor & Ehiaze Ehimen & Suresh C. Pillai & Gary Lyons & John Bartlett, 2020. "Economic and Environmental Analysis of Small-Scale Anaerobic Digestion Plants on Irish Dairy Farms," Energies, MDPI, vol. 13(3), pages 1-20, February.

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