IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v208y2017icp637-654.html
   My bibliography  Save this article

Trace compounds impact on SOFC performance: Experimental and modelling approach

Author

Listed:
  • Papurello, Davide
  • Iafrate, Chiara
  • Lanzini, Andrea
  • Santarelli, Massimo

Abstract

Issues related to SOFCs performance and durability are strictly dependent on the feeding fuel quality. SOFC capability to be fed with fuels different from hydrogen opens to scenarios in which a big variety of fuels can be used at the aim. Unfortunately, problems related to anode deactivation due to the contaminants presence can arise. The present work investigates the performance of anode supported solid oxide fuel cells in case of co-feeding of different trace compounds. Electrochemical impedance spectroscopy is the investigation technique used to analyze the impedance spectra. Typical biogas from OFMSW trace contaminants that follow an initial failure in the cleaning system, such as sulphur, aromatic compounds and siloxanes, have been simultaneously tested. Tests showed that the most deleterious impact for the SOFC was due to the H2S action. This influences mostly the electrochemical losses respect to diffusion losses, even if this last are not null and can be accounted as a secondary effect. On the contrary, the co-presence of D4 and H2S mitigates in the short-term the effect that the only D4 produces when fed with biogas. The most relevant consequence produced by C7H8 was recorded in the low frequency of Nyquist plot, affecting mainly the mass transport phenomena. Experimental tests are accompanied by the implementation of the fuel cell model through COMSOL Multiphysics software to study the effect of pollutants on fuel cell performance.

Suggested Citation

  • Papurello, Davide & Iafrate, Chiara & Lanzini, Andrea & Santarelli, Massimo, 2017. "Trace compounds impact on SOFC performance: Experimental and modelling approach," Applied Energy, Elsevier, vol. 208(C), pages 637-654.
    • Handle: RePEc:eee:appene:v:208:y:2017:i:c:p:637-654
    DOI: 10.1016/j.apenergy.2017.09.090
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261917313715
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2017.09.090?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Rasi, S. & Veijanen, A. & Rintala, J., 2007. "Trace compounds of biogas from different biogas production plants," Energy, Elsevier, vol. 32(8), pages 1375-1380.
    2. Papurello, Davide & Lanzini, Andrea & Drago, Davide & Leone, Pierluigi & Santarelli, Massimo, 2016. "Limiting factors for planar solid oxide fuel cells under different trace compound concentrations," Energy, Elsevier, vol. 95(C), pages 67-78.
    3. Chen, Huili & Wang, Fen & Wang, Wei & Chen, Daifen & Li, Si-Dian & Shao, Zongping, 2016. "H2S poisoning effect and ways to improve sulfur tolerance of nickel cermet anodes operating on carbonaceous fuels," Applied Energy, Elsevier, vol. 179(C), pages 765-777.
    4. Papurello, D. & Borchiellini, R. & Bareschino, P. & Chiodo, V. & Freni, S. & Lanzini, A. & Pepe, F. & Ortigoza, G.A. & Santarelli, M, 2014. "Performance of a Solid Oxide Fuel Cell short-stack with biogas feeding," Applied Energy, Elsevier, vol. 125(C), pages 254-263.
    5. Papurello, Davide & Lanzini, Andrea & Tognana, Lorenzo & Silvestri, Silvia & Santarelli, Massimo, 2015. "Waste to energy: Exploitation of biogas from organic waste in a 500 Wel solid oxide fuel cell (SOFC) stack," Energy, Elsevier, vol. 85(C), pages 145-158.
    6. Papurello, Davide & Lanzini, Andrea & Leone, Pierluigi & Santarelli, Massimo, 2016. "The effect of heavy tars (toluene and naphthalene) on the electrochemical performance of an anode-supported SOFC running on bio-syngas," Renewable Energy, Elsevier, vol. 99(C), pages 747-753.
    7. Hajimolana, S. Ahmad & Hussain, M. Azlan & Daud, W.M. Ashri Wan & Soroush, M. & Shamiri, A., 2011. "Mathematical modeling of solid oxide fuel cells: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(4), pages 1893-1917, May.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Li, Haolong & Zhang, Tuo & Wei, Wei & Liu, Fengxia & Xu, Xiaofei & Li, Zhiyi & Liu, Zhijun, 2023. "Performance enhancement of multi-gas compatible dual-channel interconnector for planar solid oxide fuel cells," Energy, Elsevier, vol. 283(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Davide Papurello & Massimo Santarelli & Sonia Fiorilli, 2018. "Physical Activation of Waste-Derived Materials for Biogas Cleaning," Energies, MDPI, vol. 11(9), pages 1-12, September.
    2. Papurello, Davide & Chiodo, Vitaliano & Maisano, Susanna & Lanzini, Andrea & Santarelli, Massimo, 2018. "Catalytic stability of a Ni-Catalyst towards biogas reforming in the presence of deactivating trace compounds," Renewable Energy, Elsevier, vol. 127(C), pages 481-494.
    3. Papurello, Davide & Boschetti, Andrea & Silvestri, Silvia & Khomenko, Iuliia & Biasioli, Franco, 2018. "Real-time monitoring of removal of trace compounds with PTR-MS: Biochar experimental investigation," Renewable Energy, Elsevier, vol. 125(C), pages 344-355.
    4. Giovanni Coppola & Davide Papurello, 2018. "Biogas Cleaning: Activated Carbon Regeneration for H 2 S Removal," Clean Technol., MDPI, vol. 1(1), pages 1-18, June.
    5. Abdelkareem, Mohammad Ali & Tanveer, Waqas Hassan & Sayed, Enas Taha & Assad, M. El Haj & Allagui, Anis & Cha, S.W., 2019. "On the technical challenges affecting the performance of direct internal reforming biogas solid oxide fuel cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 101(C), pages 361-375.
    6. Papurello, Davide & Lanzini, Andrea & Leone, Pierluigi & Santarelli, Massimo, 2016. "The effect of heavy tars (toluene and naphthalene) on the electrochemical performance of an anode-supported SOFC running on bio-syngas," Renewable Energy, Elsevier, vol. 99(C), pages 747-753.
    7. Giarola, Sara & Forte, Ornella & Lanzini, Andrea & Gandiglio, Marta & Santarelli, Massimo & Hawkes, Adam, 2018. "Techno-economic assessment of biogas-fed solid oxide fuel cell combined heat and power system at industrial scale," Applied Energy, Elsevier, vol. 211(C), pages 689-704.
    8. Tanveer, Waqas Hassan & Rezk, Hegazy & Nassef, Ahmed & Abdelkareem, Mohammad Ali & Kolosz, Ben & Karuppasamy, K. & Aslam, Jawad & Gilani, Syed Omer, 2020. "Improving fuel cell performance via optimal parameters identification through fuzzy logic based-modeling and optimization," Energy, Elsevier, vol. 204(C).
    9. Kupecki, Jakub & Papurello, Davide & Lanzini, Andrea & Naumovich, Yevgeniy & Motylinski, Konrad & Blesznowski, Marcin & Santarelli, Massimo, 2018. "Numerical model of planar anode supported solid oxide fuel cell fed with fuel containing H2S operated in direct internal reforming mode (DIR-SOFC)," Applied Energy, Elsevier, vol. 230(C), pages 1573-1584.
    10. Lee, Sanghyeok & Park, Mansoo & Kim, Hyoungchul & Yoon, Kyung Joong & Son, Ji-Won & Lee, Jong-Ho & Kim, Byung-Kook & Choi, Wonjoon & Hong, Jongsup, 2017. "Thermal conditions and heat transfer characteristics of high-temperature solid oxide fuel cells investigated by three-dimensional numerical simulations," Energy, Elsevier, vol. 120(C), pages 293-305.
    11. Muhamed Rasit Atelge & Halil Senol & Mohammed Djaafri & Tulin Avci Hansu & David Krisa & Abdulaziz Atabani & Cigdem Eskicioglu & Hamdi Muratçobanoğlu & Sebahattin Unalan & Slimane Kalloum & Nuri Azbar, 2021. "A Critical Overview of the State-of-the-Art Methods for Biogas Purification and Utilization Processes," Sustainability, MDPI, vol. 13(20), pages 1-39, October.
    12. Papurello, Davide & Lanzini, Andrea & Drago, Davide & Leone, Pierluigi & Santarelli, Massimo, 2016. "Limiting factors for planar solid oxide fuel cells under different trace compound concentrations," Energy, Elsevier, vol. 95(C), pages 67-78.
    13. Mehrpooya, Mehdi & Sharifzadeh, Mohammad Mehdi Moftakhari, 2017. "Conceptual and basic design of a novel integrated cogeneration power plant energy system," Energy, Elsevier, vol. 127(C), pages 516-533.
    14. Cavalli, A. & Kunze, M. & Aravind, P.V., 2018. "Cross-influence of toluene as tar model compound and HCl on Solid Oxide Fuel Cell anodes in Integrated Biomass Gasifier SOFC Systems," Applied Energy, Elsevier, vol. 231(C), pages 1-11.
    15. Mehr, A.S. & Gandiglio, M. & MosayebNezhad, M. & Lanzini, A. & Mahmoudi, S.M.S. & Yari, M. & Santarelli, M., 2017. "Solar-assisted integrated biogas solid oxide fuel cell (SOFC) installation in wastewater treatment plant: Energy and economic analysis," Applied Energy, Elsevier, vol. 191(C), pages 620-638.
    16. Cristiano, Djema Maria & de A. Mohedano, Rodrigo & Nadaleti, Willian Cézar & de Castilhos Junior, Armando B. & Lourenço, Vitor Alves & Gonçalves, Débora F.H. & Filho, Paulo Belli, 2020. "H2S adsorption on nanostructured iron oxide at room temperature for biogas purification: Application of renewable energy," Renewable Energy, Elsevier, vol. 154(C), pages 151-160.
    17. Arda Hatunoglu & Alessandro Dell’Era & Luca Del Zotto & Andrea Di Carlo & Erwin Ciro & Enrico Bocci, 2021. "Deactivation Model Study of High Temperature H 2 S Wet-Desulfurization by Using ZnO," Energies, MDPI, vol. 14(23), pages 1-14, December.
    18. Krzysztof Gaska & Agnieszka Generowicz & Anna Gronba-Chyła & Józef Ciuła & Iwona Wiewiórska & Paweł Kwaśnicki & Marcin Mala & Krzysztof Chyła, 2023. "Artificial Intelligence Methods for Analysis and Optimization of CHP Cogeneration Units Based on Landfill Biogas as a Progress in Improving Energy Efficiency and Limiting Climate Change," Energies, MDPI, vol. 16(15), pages 1-19, July.
    19. Xu, Yuan-wu & Wu, Xiao-long & Zhong, Xiao-bo & Zhao, Dong-qi & Sorrentino, Marco & Jiang, Jianhua & Jiang, Chang & Fu, Xiaowei & Li, Xi, 2021. "Mechanism model-based and data-driven approach for the diagnosis of solid oxide fuel cell stack leakage," Applied Energy, Elsevier, vol. 286(C).
    20. Bharathiraja, B. & Chakravarthy, M. & Ranjith Kumar, R. & Yogendran, D. & Yuvaraj, D. & Jayamuthunagai, J. & Praveen Kumar, R. & Palani, S., 2015. "Aquatic biomass (algae) as a future feed stock for bio-refineries: A review on cultivation, processing and products," Renewable and Sustainable Energy Reviews, Elsevier, vol. 47(C), pages 634-653.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:208:y:2017:i:c:p:637-654. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.