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Performance of sulfolane/DETA hybrids for CO2 absorption: Phase splitting behavior, kinetics and thermodynamics

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  • Wang, Lidong
  • Yu, Songhua
  • Li, Qiangwei
  • Zhang, Yifeng
  • An, Shanlong
  • Zhang, Shihan

Abstract

The phase splitting solvent as a promising alternative to MEA for CO2 capture has received an increasing attention due to its low energy consumption. In this paper, the mixture of diethylenetriamine (DETA) and sulfolane was employed to absorb CO2 from the simulated flue gas. Its phase splitting behavior was investigated. The species in each separated phase were identified using nuclear magnetic resonance (NMR), revealing that the upper layer was a CO2-rich phase and mainly consisted of DETA and DETA-carbamate. Whereas, the lower layer was CO2-lean phase with the sulfolane presented individually. The CO2 absorption kinetics was also measured in a wetted-wall column as a function of temperatures, CO2 loadings, and gas flow rate. Their impacts on the enhancement factor and mass transfer resistance were calculated by the Vapor-Liquid Equilibria (VLE) model, implying that the main CO2 mass transfer resistance gradually transferred from the gas side to the liquid side with the CO2 loading increasing from 0 to 2.21 mol L−1. During the CO2 absorption process, sulfolane acted as an inert solvent for substituting the role of water and separated from the absorption product. Consequently, the sensible heat and vaporization heat were substantially decreased by 59% and 12%, respectively. Hence the total heat duty was lowered by 19% which might noticeably advance the CO2 capture technology.

Suggested Citation

  • Wang, Lidong & Yu, Songhua & Li, Qiangwei & Zhang, Yifeng & An, Shanlong & Zhang, Shihan, 2018. "Performance of sulfolane/DETA hybrids for CO2 absorption: Phase splitting behavior, kinetics and thermodynamics," Applied Energy, Elsevier, vol. 228(C), pages 568-576.
    • Handle: RePEc:eee:appene:v:228:y:2018:i:c:p:568-576
    DOI: 10.1016/j.apenergy.2018.06.077
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    1. Chu, Fengming & Liu, Yifang & Yang, Lijun & Du, Xiaoze & Yang, Yongping, 2017. "Ammonia escape mass transfer and heat transfer characteristics of CO2 absorption in packed absorbing column," Applied Energy, Elsevier, vol. 205(C), pages 1596-1604.
    2. Chu, Fengming & Yang, Lijun & Du, Xiaoze & Yang, Yongping, 2017. "Mass transfer and energy consumption for CO2 absorption by ammonia solution in bubble column," Applied Energy, Elsevier, vol. 190(C), pages 1068-1080.
    3. Zhang, Weidong & Jin, Xianhang & Tu, Weiwei & Ma, Qian & Mao, Menglin & Cui, Chunhua, 2017. "Development of MEA-based CO2 phase change absorbent," Applied Energy, Elsevier, vol. 195(C), pages 316-323.
    4. Oh, Se-Young & Binns, Michael & Cho, Habin & Kim, Jin-Kuk, 2016. "Energy minimization of MEA-based CO2 capture process," Applied Energy, Elsevier, vol. 169(C), pages 353-362.
    5. Zhang, Xiaowen & Zhang, Xin & Liu, Helei & Li, Wensheng & Xiao, Min & Gao, Hongxia & Liang, Zhiwu, 2017. "Reduction of energy requirement of CO2 desorption from a rich CO2-loaded MEA solution by using solid acid catalysts," Applied Energy, Elsevier, vol. 202(C), pages 673-684.
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