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Reduction of energy requirement of CO2 desorption from a rich CO2-loaded MEA solution by using solid acid catalysts

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  • Zhang, Xiaowen
  • Zhang, Xin
  • Liu, Helei
  • Li, Wensheng
  • Xiao, Min
  • Gao, Hongxia
  • Liang, Zhiwu

Abstract

In this work, the regeneration of rich CO2-loaded monoethanolamine (MEA) solvent with two catalysts (e.g. SAPO-34 and SO42−/TiO2) was investigated in order to reduce the energy requirement for solvent regeneration. The regeneration behavior with and without catalyst of a 5M MEA solution with an initial CO2 loading of 0.5molCO2/mol amine at 96°C was studied to compare their CO2 desorption rate and heat duties. The results show that the two solid acid catalysts can reduce the heat duty for solvent regeneration and increase the CO2 desorption rate in comparison with blank test. The mechanism of CO2 desorption with catalyst in 5M MEA was proposed based on the result of catalyst characterization (e.g. N2 absorption/desorption experiment, Py-IR, NH3-TPD, FT-IR and XRD) to better understand the desorption process. The results indicate that SAPO-34 with the higher joint value of Brϕnsted/Lewis acid sites ratio (B/L) and mesopore surface area (MSA) shows the faster CO2 desorption rate and lower heat duty than SO42−/TiO2. Based on the experimental results, the addition of solid acid catalysts into amine solution could be considered as one of choices to reduce the heat duty for CO2 desorption from CO2-loaded amine solvent.

Suggested Citation

  • Zhang, Xiaowen & Zhang, Xin & Liu, Helei & Li, Wensheng & Xiao, Min & Gao, Hongxia & Liang, Zhiwu, 2017. "Reduction of energy requirement of CO2 desorption from a rich CO2-loaded MEA solution by using solid acid catalysts," Applied Energy, Elsevier, vol. 202(C), pages 673-684.
    • Handle: RePEc:eee:appene:v:202:y:2017:i:c:p:673-684
    DOI: 10.1016/j.apenergy.2017.05.135
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    15. Barzagli, Francesco & Giorgi, Claudia & Mani, Fabrizio & Peruzzini, Maurizio, 2018. "Reversible carbon dioxide capture by aqueous and non-aqueous amine-based absorbents: A comparative analysis carried out by 13C NMR spectroscopy," Applied Energy, Elsevier, vol. 220(C), pages 208-219.
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    17. Zhang, Xiaowen & Huang, Yufei & Gao, Hongxia & Luo, Xiao & Liang, Zhiwu & Tontiwachwuthikul, Paitoon, 2019. "Zeolite catalyst-aided tri-solvent blend amine regeneration: An alternative pathway to reduce the energy consumption in amine-based CO2 capture process," Applied Energy, Elsevier, vol. 240(C), pages 827-841.
    18. Muhammad Asif & Muhammad Suleman & Ihtishamul Haq & Syed Asad Jamal, 2018. "Post‐combustion CO2 capture with chemical absorption and hybrid system: current status and challenges," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 8(6), pages 998-1031, December.
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    21. He, Xinwei & He, Hang & Barzagli, Francesco & Amer, Mohammad Waleed & Li, Chao'en & Zhang, Rui, 2023. "Analysis of the energy consumption in solvent regeneration processes using binary amine blends for CO2 capture," Energy, Elsevier, vol. 270(C).
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    25. Zhang, Rui & Zhang, Xiaowen & Yang, Qi & Yu, Hai & Liang, Zhiwu & Luo, Xiao, 2017. "Analysis of the reduction of energy cost by using MEA-MDEA-PZ solvent for post-combustion carbon dioxide capture (PCC)," Applied Energy, Elsevier, vol. 205(C), pages 1002-1011.

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