IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v235y2019icp379-390.html
   My bibliography  Save this article

Low-viscosity and efficient regeneration of carbon dioxide capture using a biphasic solvent regulated by 2-amino-2-methyl-1-propanol

Author

Listed:
  • Zhou, Xiaobin
  • Jing, Guohua
  • Lv, Bihong
  • Liu, Fan
  • Zhou, Zuoming

Abstract

Biphasic solvents have attracted increasing attention in recent years due to their great potential to reduce the energy consumption of carbon dioxide (CO2) capture. In the present work, 2-amino-2-methyl-1-propanol (AMP) was used as a regulator to overcome the defects of a diethylenetriamine and pentamethyldiethylenetriamine (DETA-PMDETA) biphasic solvent—particularly, its high viscosity and inferior regenerability. The viscosity of the CO2-saturated biphasic solvent significantly decreased from 541.0 to 152.0 mPa·s and the CO2 cyclic capacity increased from 1.85 to 4.28 mol·L−1 (M) when the formula of the biphasic solvent was changed from 2 M DETA + 3 M PMDETA (2D3P) to 0.5 M DETA + 1.5 M AMP + 3 M PMDETA (0.5D1.5A3P). The sensible heat requirement for the regeneration of the solvent 0.5D1.5A3P could be reduced by 58.9% compared with that of 2D3P. The results indicated the positive regulatory effects of AMP on the biphasic solvent. Based on the characterizations and quantum chemical calculation, the regulatory mechanism of AMP in the biphasic system was elucidated. In the DETA-PMDETA system, CO2 was absorbed to mainly form DETA-carbamate. In the DETA-AMP-PMDETA system, CO2 was first absorbed to form DETA-carbamate and AMP-carbamate, while AMP-carbamate was rapidly hydrolyzed to HCO3−/CO32−, resulting in fewer carbamate products in the saturated solvent. Since HCO3−/CO32− did not tend to form hydrogen bonds and decomposed more easily than DETA-carbamate, the DETA-AMP-PMDETA system presented a lower viscosity and better regeneration performance. Moreover, in the presence of AMP, free protons were easily generated by multiple pathways to facilitate the dissociation of DETA-carbamate, which resulted in a deep CO2 stripping. Therefore, an AMP-regulated DETA-PMDETA biphasic solvent for low-viscosity and efficient regeneration of CO2 capture would further reduce the associated energy consumption.

Suggested Citation

  • Zhou, Xiaobin & Jing, Guohua & Lv, Bihong & Liu, Fan & Zhou, Zuoming, 2019. "Low-viscosity and efficient regeneration of carbon dioxide capture using a biphasic solvent regulated by 2-amino-2-methyl-1-propanol," Applied Energy, Elsevier, vol. 235(C), pages 379-390.
    • Handle: RePEc:eee:appene:v:235:y:2019:i:c:p:379-390
    DOI: 10.1016/j.apenergy.2018.10.118
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S030626191831674X
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2018.10.118?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Zhang, Weidong & Jin, Xianhang & Tu, Weiwei & Ma, Qian & Mao, Menglin & Cui, Chunhua, 2017. "Development of MEA-based CO2 phase change absorbent," Applied Energy, Elsevier, vol. 195(C), pages 316-323.
    2. Fu, Dong & Zhang, Pan & Wang, LeMeng, 2016. "Absorption performance of CO2 in high concentrated [Bmim][Lys]-MDEA aqueous solution," Energy, Elsevier, vol. 113(C), pages 1-8.
    3. Wang, Xianfeng & Akhmedov, Novruz G. & Hopkinson, David & Hoffman, James & Duan, Yuhua & Egbebi, Adefemi & Resnik, Kevin & Li, Bingyun, 2016. "Phase change amino acid salt separates into CO2-rich and CO2-lean phases upon interacting with CO2," Applied Energy, Elsevier, vol. 161(C), pages 41-47.
    4. Cheng, Chin-hung & Li, Kangkang & Yu, Hai & Jiang, Kaiqi & Chen, Jian & Feron, Paul, 2018. "Amine-based post-combustion CO2 capture mediated by metal ions: Advancement of CO2 desorption using copper ions," Applied Energy, Elsevier, vol. 211(C), pages 1030-1038.
    5. Xiao, Min & Liu, Helei & Idem, Raphael & Tontiwachwuthikul, Paitoon & Liang, Zhiwu, 2016. "A study of structure–activity relationships of commercial tertiary amines for post-combustion CO2 capture," Applied Energy, Elsevier, vol. 184(C), pages 219-229.
    6. Zhang, Xiaowen & Zhang, Xin & Liu, Helei & Li, Wensheng & Xiao, Min & Gao, Hongxia & Liang, Zhiwu, 2017. "Reduction of energy requirement of CO2 desorption from a rich CO2-loaded MEA solution by using solid acid catalysts," Applied Energy, Elsevier, vol. 202(C), pages 673-684.
    7. Shen, Yao & Jiang, Chenkai & Zhang, Shihan & Chen, Jun & Wang, Lidong & Chen, Jianmeng, 2018. "Biphasic solvent for CO2 capture: Amine property-performance and heat duty relationship," Applied Energy, Elsevier, vol. 230(C), pages 726-733.
    8. Barzagli, Francesco & Giorgi, Claudia & Mani, Fabrizio & Peruzzini, Maurizio, 2018. "Reversible carbon dioxide capture by aqueous and non-aqueous amine-based absorbents: A comparative analysis carried out by 13C NMR spectroscopy," Applied Energy, Elsevier, vol. 220(C), pages 208-219.
    9. Zhang, Xiaowen & Zhang, Rui & Liu, Helei & Gao, Hongxia & Liang, Zhiwu, 2018. "Evaluating CO2 desorption performance in CO2-loaded aqueous tri-solvent blend amines with and without solid acid catalysts," Applied Energy, Elsevier, vol. 218(C), pages 417-429.
    10. Xie, Yujiao & Zhang, Yingying & Lu, Xiaohua & Ji, Xiaoyan, 2014. "Energy consumption analysis for CO2 separation using imidazolium-based ionic liquids," Applied Energy, Elsevier, vol. 136(C), pages 325-335.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Wang, Rujie & Yang, Yuying & Wang, Mengfan & Lin, Jinshan & Zhang, Shihan & An, Shanlong & Wang, Lidong, 2021. "Energy efficient diethylenetriamine–1-propanol biphasic solvent for CO2 capture: Experimental and theoretical study," Applied Energy, Elsevier, vol. 290(C).
    2. Shen, Yao & Chen, Han & Wang, Junliang & Zhang, Shihan & Jiang, Chenkai & Ye, Jiexu & Wang, Lidong & Chen, Jianmeng, 2020. "Two-stage interaction performance of CO2 absorption into biphasic solvents: Mechanism analysis, quantum calculation and energy consumption," Applied Energy, Elsevier, vol. 260(C).
    3. Wang, Rujie & Liu, Shanshan & Li, Qiangwei & Zhang, Shihan & Wang, Lidong & An, Shanlong, 2021. "CO2 capture performance and mechanism of blended amine solvents regulated by N-methylcyclohexyamine," Energy, Elsevier, vol. 215(PB).
    4. Wang, Rujie & Zhao, Huajun & Yang, Xiaotong & Qi, Cairao & Zhao, Haonan & Zhang, Shihan & Li, Qiangwei & Li, Ping & Wang, Lidong, 2023. "Energy-efficient non-aqueous biphasic solvent for carbon capture: Absorption mechanism, phase evolution process, and non-corrosiveness," Energy, Elsevier, vol. 281(C).
    5. Liu, Xuebing & Niu, Xiaowei & Zhan, Guoxiong & Xing, Lei & Huang, Zhoulan & Yuan, Bingling & Peng, Yue & Chen, Zhen & Li, Junhua, 2024. "Dynamic phase-splitting behaviour of biphasic solvent for carbon capture in a novel annular phase separator," Applied Energy, Elsevier, vol. 360(C).
    6. Wang, Rujie & Zhao, Huajun & Qi, Cairao & Yang, Xiaotong & Zhang, Shihan & Li, Ming & Wang, Lidong, 2022. "Novel tertiary amine-based biphasic solvent for energy-efficient CO2 capture with low corrosivity," Energy, Elsevier, vol. 260(C).
    7. Zhou, Xiaobin & Liu, Chao & Zhang, Jie & Fan, Yinming & Zhu, Yinian & Zhang, Lihao & Tang, Shen & Mo, Shengpeng & Zhu, Hongxiang & Zhu, Zongqiang, 2023. "Novel 2-amino-2-methyl-1-propanol-based biphasic solvent for energy-efficient carbon dioxide capture using tetraethylenepentamine as a phase change regulator," Energy, Elsevier, vol. 270(C).
    8. Bihong, Lv & Kexuan, Yang & Xiaobin, Zhou & Zuoming, Zhou & Guohua, Jing, 2020. "2-Amino-2-methyl-1-propanol based non-aqueous absorbent for energy-efficient and non-corrosive carbon dioxide capture," Applied Energy, Elsevier, vol. 264(C).
    9. Wang, Rujie & Liu, Shanshan & Wang, Lidong & Li, Qiangwei & Zhang, Shihan & Chen, Bo & Jiang, Lei & Zhang, Yifeng, 2019. "Superior energy-saving splitter in monoethanolamine-based biphasic solvents for CO2 capture from coal-fired flue gas," Applied Energy, Elsevier, vol. 242(C), pages 302-310.
    10. Jin, Lijian & Hou, Xueyan & Zhan, Lingxiao & Hou, Dawei & Gu, Lina & Zhang, Daguang & Shen, Jianchong & Zheng, Zhihao & Lv, Chao & Liu, Shaoqing & Yang, Linjun, 2024. "Tuning and optimization of two-phase absorbents (DEEA/AEEA/H2O) with hybrid phase splitter (n-butanol/DEEA) for several properties: Carbon capture, phase separation, physical properties," Energy, Elsevier, vol. 288(C).
    11. Lai, Qinghua & Kong, Lingli & Gong, Weibo & Russell, Armistead G & Fan, Maohong, 2019. "Low-energy-consumption and environmentally friendly CO2 capture via blending alcohols into amine solution," Applied Energy, Elsevier, vol. 254(C).
    12. Zhou, Xiaobin & Liu, Chao & Fan, Yinming & Zhang, Lihao & Tang, Shen & Mo, Shengpeng & Zhu, Yinian & Zhu, Zongqiang, 2022. "Energy-efficient carbon dioxide capture using a novel low-viscous secondary amine-based nonaqueous biphasic solvent: Performance, mechanism, and thermodynamics," Energy, Elsevier, vol. 255(C).
    13. Hu, Hangtian & Fang, Mengxiang & Liu, Fei & Wang, Tao & Xia, Zhixiang & Zhang, Wei & Ge, Chunliang & Yuan, Jingjuan, 2022. "Novel alkanolamine-based biphasic solvent for CO2 capture with low energy consumption and phase change mechanism analysis," Applied Energy, Elsevier, vol. 324(C).
    14. Wang, Rujie & Jiang, Lei & Li, Qiangwei & Gao, Ge & Zhang, Shihan & Wang, Lidong, 2020. "Energy-saving CO2 capture using sulfolane-regulated biphasic solvent," Energy, Elsevier, vol. 211(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Wang, Rujie & Liu, Shanshan & Wang, Lidong & Li, Qiangwei & Zhang, Shihan & Chen, Bo & Jiang, Lei & Zhang, Yifeng, 2019. "Superior energy-saving splitter in monoethanolamine-based biphasic solvents for CO2 capture from coal-fired flue gas," Applied Energy, Elsevier, vol. 242(C), pages 302-310.
    2. Alivand, Masood S. & Mazaheri, Omid & Wu, Yue & Stevens, Geoffrey W. & Scholes, Colin A. & Mumford, Kathryn A., 2019. "Development of aqueous-based phase change amino acid solvents for energy-efficient CO2 capture: The role of antisolvent," Applied Energy, Elsevier, vol. 256(C).
    3. Zhang, Xiaowen & Huang, Yufei & Gao, Hongxia & Luo, Xiao & Liang, Zhiwu & Tontiwachwuthikul, Paitoon, 2019. "Zeolite catalyst-aided tri-solvent blend amine regeneration: An alternative pathway to reduce the energy consumption in amine-based CO2 capture process," Applied Energy, Elsevier, vol. 240(C), pages 827-841.
    4. Shen, Yao & Jiang, Chenkai & Zhang, Shihan & Chen, Jun & Wang, Lidong & Chen, Jianmeng, 2018. "Biphasic solvent for CO2 capture: Amine property-performance and heat duty relationship," Applied Energy, Elsevier, vol. 230(C), pages 726-733.
    5. Zhang, Xiaowen & Liu, Helei & Liang, Zhiwu & Idem, Raphael & Tontiwachwuthikul, Paitoon & Jaber Al-Marri, Mohammed & Benamor, Abdelbaki, 2018. "Reducing energy consumption of CO2 desorption in CO2-loaded aqueous amine solution using Al2O3/HZSM-5 bifunctional catalysts," Applied Energy, Elsevier, vol. 229(C), pages 562-576.
    6. Xiao, Min & Liu, Helei & Gao, Hongxia & Olson, Wilfred & Liang, Zhiwu, 2019. "CO2 capture with hybrid absorbents of low viscosity imidazolium-based ionic liquids and amine," Applied Energy, Elsevier, vol. 235(C), pages 311-319.
    7. Wang, Rujie & Zhao, Huajun & Qi, Cairao & Yang, Xiaotong & Zhang, Shihan & Li, Ming & Wang, Lidong, 2022. "Novel tertiary amine-based biphasic solvent for energy-efficient CO2 capture with low corrosivity," Energy, Elsevier, vol. 260(C).
    8. Guo, Hui & Li, Chenxu & Shi, Xiaoqin & Li, Hui & Shen, Shufeng, 2019. "Nonaqueous amine-based absorbents for energy efficient CO2 capture," Applied Energy, Elsevier, vol. 239(C), pages 725-734.
    9. Wang, Rujie & Yang, Yuying & Wang, Mengfan & Lin, Jinshan & Zhang, Shihan & An, Shanlong & Wang, Lidong, 2021. "Energy efficient diethylenetriamine–1-propanol biphasic solvent for CO2 capture: Experimental and theoretical study," Applied Energy, Elsevier, vol. 290(C).
    10. Liu, Fei & Fang, Mengxiang & Dong, Wenfeng & Wang, Tao & Xia, Zhixiang & Wang, Qinhui & Luo, Zhongyang, 2019. "Carbon dioxide absorption in aqueous alkanolamine blends for biphasic solvents screening and evaluation," Applied Energy, Elsevier, vol. 233, pages 468-477.
    11. Zhou, Xiaobin & Liu, Chao & Zhang, Jie & Fan, Yinming & Zhu, Yinian & Zhang, Lihao & Tang, Shen & Mo, Shengpeng & Zhu, Hongxiang & Zhu, Zongqiang, 2023. "Novel 2-amino-2-methyl-1-propanol-based biphasic solvent for energy-efficient carbon dioxide capture using tetraethylenepentamine as a phase change regulator," Energy, Elsevier, vol. 270(C).
    12. Liu, Xuebing & Niu, Xiaowei & Zhan, Guoxiong & Xing, Lei & Huang, Zhoulan & Yuan, Bingling & Peng, Yue & Chen, Zhen & Li, Junhua, 2024. "Dynamic phase-splitting behaviour of biphasic solvent for carbon capture in a novel annular phase separator," Applied Energy, Elsevier, vol. 360(C).
    13. Ji, Long & Yu, Hai & Li, Kangkang & Yu, Bing & Grigore, Mihaela & Yang, Qi & Wang, Xiaolong & Chen, Zuliang & Zeng, Ming & Zhao, Shuaifei, 2018. "Integrated absorption-mineralisation for low-energy CO2 capture and sequestration," Applied Energy, Elsevier, vol. 225(C), pages 356-366.
    14. Liu, Sen & Gao, Hongxia & He, Chuan & Liang, Zhiwu, 2019. "Experimental evaluation of highly efficient primary and secondary amines with lower energy by a novel method for post-combustion CO2 capture," Applied Energy, Elsevier, vol. 233, pages 443-452.
    15. Zhang, Shihan & Shen, Yao & Wang, Lidong & Chen, Jianmeng & Lu, Yongqi, 2019. "Phase change solvents for post-combustion CO2 capture: Principle, advances, and challenges," Applied Energy, Elsevier, vol. 239(C), pages 876-897.
    16. Meng, Fanzhi & Meng, Yuan & Ju, Tongyao & Han, Siyu & Lin, Li & Jiang, Jianguo, 2022. "Research progress of aqueous amine solution for CO2 capture: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 168(C).
    17. Zhang, Xiaowen & Zhang, Rui & Liu, Helei & Gao, Hongxia & Liang, Zhiwu, 2018. "Evaluating CO2 desorption performance in CO2-loaded aqueous tri-solvent blend amines with and without solid acid catalysts," Applied Energy, Elsevier, vol. 218(C), pages 417-429.
    18. Li, Qiangwei & Huang, Xin & Li, Nuo & Qi, Tieyue & Wang, Rujie & Wang, Lidong & An, Shanlong, 2024. "Energy-efficient biphasic solvents for industrial CO2 capture: Absorption mechanism and stability characteristics," Energy, Elsevier, vol. 293(C).
    19. Zhang, Rui & Zhang, Xiaowen & Yang, Qi & Yu, Hai & Liang, Zhiwu & Luo, Xiao, 2017. "Analysis of the reduction of energy cost by using MEA-MDEA-PZ solvent for post-combustion carbon dioxide capture (PCC)," Applied Energy, Elsevier, vol. 205(C), pages 1002-1011.
    20. Gao, Hongxia & Huang, Yufei & Zhang, Xiaowen & Bairq, Zain Ali Saleh & Huang, Yangqiang & Tontiwachwuthikul, Paitoon & Liang, Zhiwu, 2020. "Catalytic performance and mechanism of SO42−/ZrO2/SBA-15 catalyst for CO2 desorption in CO2-loaded monoethanolamine solution," Applied Energy, Elsevier, vol. 259(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:235:y:2019:i:c:p:379-390. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.