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Non-Aqueous Solvent Mixtures for CO 2 Capture: Choline Hydroxide-Based Deep Eutectic Solvents Absorbent Performance at Various Temperatures and Pressures

Author

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  • Mohd Azlan Kassim

    (Research Centre for Carbon Dioxide Capture and Utilisation (CCDCU), School of Engineering and Technology, Sunway University, No. 5 Jalan Universiti, Bandar Sunway, Petaling Jaya 47500, Selangor, Malaysia)

  • Nor Afifah Sulaiman

    (Research Centre for Carbon Dioxide Capture and Utilisation (CCDCU), School of Engineering and Technology, Sunway University, No. 5 Jalan Universiti, Bandar Sunway, Petaling Jaya 47500, Selangor, Malaysia)

  • Rozita Yusoff

    (Chemical Engineering Department, Faculty of Engineering, University of Malaya, Kuala Lumpur 50603, Malaysia)

  • Mohamed Kheireddine Aroua

    (Research Centre for Carbon Dioxide Capture and Utilisation (CCDCU), School of Engineering and Technology, Sunway University, No. 5 Jalan Universiti, Bandar Sunway, Petaling Jaya 47500, Selangor, Malaysia
    School of Engineering, Lancaster University, Lancaster LA1 4YW, UK
    Sunway Materials Smart Science & Engineering Research Cluster (SMS2E), Sunway University, No. 5 Jalan Universiti, Bandar Sunway, Petaling Jaya 47500, Selangor, Malaysia)

Abstract

Carbon dioxide (CO 2 ) absorption in a non-aqueous solution is a potential technology for reducing greenhouse gas emissions. In this study, a non-aqueous solvent, sulfolane and dimethylsulfoxide (DMSO), was functionalized with a deep eutectic solvent (DES) consisting of choline hydroxide and polyamines diethylenetriamine (DETA) and triethylenetetramine (TETA). The non-aqueous absorbents’ CO 2 absorption ability was investigated in a high-pressure absorption reactor with a variable absorption temperature (303.15–333.15 K) and pressure (350–1400 kPa). The results showed that 2M ChOH:TETA−DMSO solution had the highest CO 2 loading capacity when compared with other screened solutions, such as 2M ChOH:TETA−Sulfolane, 2M ChOH:DETA−DMSO and 2M ChOH:DETA−Sulfolane. It was also found that the absorption capacity increased with increasing pressure and decreased with temperature. The highest CO 2 absorption by 2M ChOH:TETA−DMSO was observed at a partial pressure of 1400 kPa at 303.15 K 1.2507 mol CO 2 /mol DES. The use of a non-aqueous solvent in the mixture showed a phase separation phenomenon after the CO 2 absorption reaction due to the formation of insoluble carbamate salt, which was identified through FTIR analysis. These findings suggest that the use of a DES polyamine mixed with a non-aqueous solvent could be a promising solution for CO 2 capture.

Suggested Citation

  • Mohd Azlan Kassim & Nor Afifah Sulaiman & Rozita Yusoff & Mohamed Kheireddine Aroua, 2023. "Non-Aqueous Solvent Mixtures for CO 2 Capture: Choline Hydroxide-Based Deep Eutectic Solvents Absorbent Performance at Various Temperatures and Pressures," Sustainability, MDPI, vol. 15(12), pages 1-14, June.
    • Handle: RePEc:gam:jsusta:v:15:y:2023:i:12:p:9191-:d:1165324
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    References listed on IDEAS

    as
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