IDEAS home Printed from https://ideas.repec.org/a/gam/jsusta/v15y2023i12p9191-d1165324.html
   My bibliography  Save this article

Non-Aqueous Solvent Mixtures for CO 2 Capture: Choline Hydroxide-Based Deep Eutectic Solvents Absorbent Performance at Various Temperatures and Pressures

Author

Listed:
  • Mohd Azlan Kassim

    (Research Centre for Carbon Dioxide Capture and Utilisation (CCDCU), School of Engineering and Technology, Sunway University, No. 5 Jalan Universiti, Bandar Sunway, Petaling Jaya 47500, Selangor, Malaysia)

  • Nor Afifah Sulaiman

    (Research Centre for Carbon Dioxide Capture and Utilisation (CCDCU), School of Engineering and Technology, Sunway University, No. 5 Jalan Universiti, Bandar Sunway, Petaling Jaya 47500, Selangor, Malaysia)

  • Rozita Yusoff

    (Chemical Engineering Department, Faculty of Engineering, University of Malaya, Kuala Lumpur 50603, Malaysia)

  • Mohamed Kheireddine Aroua

    (Research Centre for Carbon Dioxide Capture and Utilisation (CCDCU), School of Engineering and Technology, Sunway University, No. 5 Jalan Universiti, Bandar Sunway, Petaling Jaya 47500, Selangor, Malaysia
    School of Engineering, Lancaster University, Lancaster LA1 4YW, UK
    Sunway Materials Smart Science & Engineering Research Cluster (SMS2E), Sunway University, No. 5 Jalan Universiti, Bandar Sunway, Petaling Jaya 47500, Selangor, Malaysia)

Abstract

Carbon dioxide (CO 2 ) absorption in a non-aqueous solution is a potential technology for reducing greenhouse gas emissions. In this study, a non-aqueous solvent, sulfolane and dimethylsulfoxide (DMSO), was functionalized with a deep eutectic solvent (DES) consisting of choline hydroxide and polyamines diethylenetriamine (DETA) and triethylenetetramine (TETA). The non-aqueous absorbents’ CO 2 absorption ability was investigated in a high-pressure absorption reactor with a variable absorption temperature (303.15–333.15 K) and pressure (350–1400 kPa). The results showed that 2M ChOH:TETA−DMSO solution had the highest CO 2 loading capacity when compared with other screened solutions, such as 2M ChOH:TETA−Sulfolane, 2M ChOH:DETA−DMSO and 2M ChOH:DETA−Sulfolane. It was also found that the absorption capacity increased with increasing pressure and decreased with temperature. The highest CO 2 absorption by 2M ChOH:TETA−DMSO was observed at a partial pressure of 1400 kPa at 303.15 K 1.2507 mol CO 2 /mol DES. The use of a non-aqueous solvent in the mixture showed a phase separation phenomenon after the CO 2 absorption reaction due to the formation of insoluble carbamate salt, which was identified through FTIR analysis. These findings suggest that the use of a DES polyamine mixed with a non-aqueous solvent could be a promising solution for CO 2 capture.

Suggested Citation

  • Mohd Azlan Kassim & Nor Afifah Sulaiman & Rozita Yusoff & Mohamed Kheireddine Aroua, 2023. "Non-Aqueous Solvent Mixtures for CO 2 Capture: Choline Hydroxide-Based Deep Eutectic Solvents Absorbent Performance at Various Temperatures and Pressures," Sustainability, MDPI, vol. 15(12), pages 1-14, June.
    • Handle: RePEc:gam:jsusta:v:15:y:2023:i:12:p:9191-:d:1165324
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/2071-1050/15/12/9191/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/2071-1050/15/12/9191/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Syed Awais Ali & Waqad Ul Mulk & Zahoor Ullah & Haris Khan & Afrah Zahid & Mansoor Ul Hassan Shah & Syed Nasir Shah, 2022. "Recent Advances in the Synthesis, Application and Economic Feasibility of Ionic Liquids and Deep Eutectic Solvents for CO 2 Capture: A Review," Energies, MDPI, vol. 15(23), pages 1-31, November.
    2. Zhou, Xiaobin & Liu, Chao & Fan, Yinming & Zhang, Lihao & Tang, Shen & Mo, Shengpeng & Zhu, Yinian & Zhu, Zongqiang, 2022. "Energy-efficient carbon dioxide capture using a novel low-viscous secondary amine-based nonaqueous biphasic solvent: Performance, mechanism, and thermodynamics," Energy, Elsevier, vol. 255(C).
    3. Wang, Lidong & Yu, Songhua & Li, Qiangwei & Zhang, Yifeng & An, Shanlong & Zhang, Shihan, 2018. "Performance of sulfolane/DETA hybrids for CO2 absorption: Phase splitting behavior, kinetics and thermodynamics," Applied Energy, Elsevier, vol. 228(C), pages 568-576.
    4. Jiang, L. & Gonzalez-Diaz, A. & Ling-Chin, J. & Roskilly, A.P. & Smallbone, A.J., 2019. "Post-combustion CO2 capture from a natural gas combined cycle power plant using activated carbon adsorption," Applied Energy, Elsevier, vol. 245(C), pages 1-15.
    5. Guo, Hui & Li, Chenxu & Shi, Xiaoqin & Li, Hui & Shen, Shufeng, 2019. "Nonaqueous amine-based absorbents for energy efficient CO2 capture," Applied Energy, Elsevier, vol. 239(C), pages 725-734.
    6. Paweł Madejski & Karolina Chmiel & Navaneethan Subramanian & Tomasz Kuś, 2022. "Methods and Techniques for CO 2 Capture: Review of Potential Solutions and Applications in Modern Energy Technologies," Energies, MDPI, vol. 15(3), pages 1-21, January.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Meng, Fanli & Fu, Kun & Wang, Xueli & Ye, Bonan & Zhang, Pan & Wang, Lemeng & Fu, Dong, 2024. "Performance of a new water lean absorbent composed of EHA and DEGDEE in CO2 capture and regeneration," Energy, Elsevier, vol. 304(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Yin, Xin & Shen, Shufeng, 2023. "Water-lean monophasic absorbents containing secondary alkanolamines and dimethyl sulfoxide for energy-efficient CO2 capture," Energy, Elsevier, vol. 281(C).
    2. Wang, Lidong & Fang, Jie & Ma, Haojun & Wang, Chuhuan & Wang, Rujie & Li, Qiangwei & Zhang, Shihan, 2023. "Super-low energy consuming CO2 capture triggered by weak hydrogen bonds in solid-liquid phase separation," Energy, Elsevier, vol. 272(C).
    3. Alivand, Masood S. & Mazaheri, Omid & Wu, Yue & Stevens, Geoffrey W. & Scholes, Colin A. & Mumford, Kathryn A., 2019. "Development of aqueous-based phase change amino acid solvents for energy-efficient CO2 capture: The role of antisolvent," Applied Energy, Elsevier, vol. 256(C).
    4. Bihong, Lv & Kexuan, Yang & Xiaobin, Zhou & Zuoming, Zhou & Guohua, Jing, 2020. "2-Amino-2-methyl-1-propanol based non-aqueous absorbent for energy-efficient and non-corrosive carbon dioxide capture," Applied Energy, Elsevier, vol. 264(C).
    5. Li, Qiangwei & Huang, Xin & Li, Nuo & Qi, Tieyue & Wang, Rujie & Wang, Lidong & An, Shanlong, 2024. "Energy-efficient biphasic solvents for industrial CO2 capture: Absorption mechanism and stability characteristics," Energy, Elsevier, vol. 293(C).
    6. Meng, Fanli & Fu, Kun & Wang, Xueli & Ye, Bonan & Zhang, Pan & Wang, Lemeng & Fu, Dong, 2024. "Performance of a new water lean absorbent composed of EHA and DEGDEE in CO2 capture and regeneration," Energy, Elsevier, vol. 304(C).
    7. Wang, Rujie & Jiang, Lei & Li, Qiangwei & Gao, Ge & Zhang, Shihan & Wang, Lidong, 2020. "Energy-saving CO2 capture using sulfolane-regulated biphasic solvent," Energy, Elsevier, vol. 211(C).
    8. Meng, Fanli & Fu, Kun & Wang, Xueli & Wang, Yixiao & Wang, Lemeng & Fu, Dong, 2024. "Study on absorption and regeneration performance of EHA-DMSO non-aqueous absorbent for CO2 capture from flue gas," Energy, Elsevier, vol. 286(C).
    9. Zhang, Weifeng & Xu, Yuanlong & Wang, Qiuhua, 2022. "Coupled CO2 absorption and mineralization with low-concentration monoethanolamine," Energy, Elsevier, vol. 241(C).
    10. Vega, F. & Baena-Moreno, F.M. & Gallego Fernández, Luz M. & Portillo, E. & Navarrete, B. & Zhang, Zhien, 2020. "Current status of CO2 chemical absorption research applied to CCS: Towards full deployment at industrial scale," Applied Energy, Elsevier, vol. 260(C).
    11. Zhao, Jun & Fu, Jianxin & Deng, Shuai & Wang, Junyao & Xu, Yaofeng, 2020. "Decoupled thermal-driven absorption-based CO2 capture into heat engine plus carbon pump: A new understanding with the case study," Energy, Elsevier, vol. 210(C).
    12. Subramanian, Navaneethan & Madejski, Paweł, 2023. "Analysis of CO2 capture process from flue-gases in combined cycle gas turbine power plant using post-combustion capture technology," Energy, Elsevier, vol. 282(C).
    13. Pashchenko, Dmitry, 2023. "Hydrogen-rich gas as a fuel for the gas turbines: A pathway to lower CO2 emission," Renewable and Sustainable Energy Reviews, Elsevier, vol. 173(C).
    14. Wang, Rujie & Zhao, Huajun & Qi, Cairao & Yang, Xiaotong & Zhang, Shihan & Li, Ming & Wang, Lidong, 2022. "Novel tertiary amine-based biphasic solvent for energy-efficient CO2 capture with low corrosivity," Energy, Elsevier, vol. 260(C).
    15. Xiao Sun & Qi Cheng & Jiren Tang & Xing Guo & Yunzhong Jia & Jingfu Mu & Guilin Zhao & Yalu Liu, 2023. "Assessment of the CO 2 Geological Storage Potential of Yanchang Shale Gas Formation (Chang7 Member) Considering the Capillary Sealing Capability of Caprock," Sustainability, MDPI, vol. 15(20), pages 1-15, October.
    16. Lambert, Jerry & Hanel, Andreas & Fendt, Sebastian & Spliethoff, Hartmut, 2023. "Evaluation of sector-coupled energy systems using different foresight horizons," Renewable and Sustainable Energy Reviews, Elsevier, vol. 184(C).
    17. Guo, Juncheng & Tan, Chaohuan & Li, Zhexu & Chen, Bo & Yang, Hanxin & Luo, Rongxiang & Gonzalez-Ayala, Julian & Hernández, A. Calvo, 2024. "New insights into energy conversion mechanism, optimal absorbent selection criteria, and operation strategies of absorption carbon capture systems," Energy, Elsevier, vol. 304(C).
    18. Liu, Li & Jiang, Peng & Qian, Hongliang & Mu, Liwen & Lu, Xiaohua & Zhu, Jiahua, 2022. "CO2-negative biomass conversion: An economic route with co-production of green hydrogen and highly porous carbon," Applied Energy, Elsevier, vol. 311(C).
    19. Nguyen, Ngoc N. & La, Vinh T. & Huynh, Chinh D. & Nguyen, Anh V., 2022. "Technical and economic perspectives of hydrate-based carbon dioxide capture," Applied Energy, Elsevier, vol. 307(C).
    20. Zhou, Xiaobin & Liu, Chao & Fan, Yinming & Zhang, Lihao & Tang, Shen & Mo, Shengpeng & Zhu, Yinian & Zhu, Zongqiang, 2022. "Energy-efficient carbon dioxide capture using a novel low-viscous secondary amine-based nonaqueous biphasic solvent: Performance, mechanism, and thermodynamics," Energy, Elsevier, vol. 255(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jsusta:v:15:y:2023:i:12:p:9191-:d:1165324. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.