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Novel 2-amino-2-methyl-1-propanol-based biphasic solvent for energy-efficient carbon dioxide capture using tetraethylenepentamine as a phase change regulator

Author

Listed:
  • Zhou, Xiaobin
  • Liu, Chao
  • Zhang, Jie
  • Fan, Yinming
  • Zhu, Yinian
  • Zhang, Lihao
  • Tang, Shen
  • Mo, Shengpeng
  • Zhu, Hongxiang
  • Zhu, Zongqiang

Abstract

Biphasic solvents are regarded as promising candidates for CO2 capture but still suffer from the deficiency of inferior regenerability, which negatively affects their energy-saving potential. 2-Amino-2-methyl-1-propanol (AMP)-based absorbents have superior regenerability but poor phase-change performance. In this study, an effective strategy that using tetraethylenepentamine (TEPA) to regulate the phase change behavior of an AMP-pentamethyldiethylenetriamine (PMDETA) aqueous solution was proposed, aiming to develop a novel AMP-PMDETA-TEPA (A-P-T) biphasic solvent with good regenerability and excellent phase separation performance. The A-P-T biphasic solvent could realize a high CO2 loading of 0.73 mol mol−1 and a high desorption efficiency of 75.3%. Its sensible heat requirement significantly decreased to 0.14 GJ·ton−1 CO2, 78.1% less than the monoethanolamine solution. The 13C NMR characterization and quantum chemistry calculations indicated that with the introduction of TEPA, high polar TEPA-associated products were generated, which broke the original assimilation state of the A-P-T system and drove it to undergo phase change. Since the TEPA-associated products had a strong affinity to other CO2-captured products and H2O, they gathered together to form the CO2-rich phase. In contrast, less polar PMDETA showed a relatively weak affinity to the TEPA-associated products and was solely separated from the solution to form the CO2-lean phase.

Suggested Citation

  • Zhou, Xiaobin & Liu, Chao & Zhang, Jie & Fan, Yinming & Zhu, Yinian & Zhang, Lihao & Tang, Shen & Mo, Shengpeng & Zhu, Hongxiang & Zhu, Zongqiang, 2023. "Novel 2-amino-2-methyl-1-propanol-based biphasic solvent for energy-efficient carbon dioxide capture using tetraethylenepentamine as a phase change regulator," Energy, Elsevier, vol. 270(C).
  • Handle: RePEc:eee:energy:v:270:y:2023:i:c:s0360544223003249
    DOI: 10.1016/j.energy.2023.126930
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    References listed on IDEAS

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    1. Wang, Rujie & Yang, Yuying & Wang, Mengfan & Lin, Jinshan & Zhang, Shihan & An, Shanlong & Wang, Lidong, 2021. "Energy efficient diethylenetriamine–1-propanol biphasic solvent for CO2 capture: Experimental and theoretical study," Applied Energy, Elsevier, vol. 290(C).
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    4. Zhang, Shihan & Shen, Yao & Wang, Lidong & Chen, Jianmeng & Lu, Yongqi, 2019. "Phase change solvents for post-combustion CO2 capture: Principle, advances, and challenges," Applied Energy, Elsevier, vol. 239(C), pages 876-897.
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    6. Zhou, Xiaobin & Jing, Guohua & Lv, Bihong & Liu, Fan & Zhou, Zuoming, 2019. "Low-viscosity and efficient regeneration of carbon dioxide capture using a biphasic solvent regulated by 2-amino-2-methyl-1-propanol," Applied Energy, Elsevier, vol. 235(C), pages 379-390.
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    1. Wang, Rujie & Zhao, Huajun & Yang, Xiaotong & Qi, Cairao & Zhao, Haonan & Zhang, Shihan & Li, Qiangwei & Li, Ping & Wang, Lidong, 2023. "Energy-efficient non-aqueous biphasic solvent for carbon capture: Absorption mechanism, phase evolution process, and non-corrosiveness," Energy, Elsevier, vol. 281(C).

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