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Reverse electrodialysis heat engine for sustainable power production

Author

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  • Tamburini, A.
  • Tedesco, M.
  • Cipollina, A.
  • Micale, G.
  • Ciofalo, M.
  • Papapetrou, M.
  • Van Baak, W.
  • Piacentino, A.

Abstract

Reverse Electrodialysis Heat Engine (REDHE) is a promising technology to convert waste heat at temperatures lower than 100°C into electric power. In the present work an overview of the possible regeneration methods is presented and the technological challenges for the development of the RED Heat Engine (REDHE) are identified. The potential of this power production cycle was investigated through a simplified mathematical model. In the first part of the work, several salts were singularly modelled as possible solutes in aqueous solutions feeding the RED unit and the corresponding optimal conditions were recognized via an optimization study. In the second part, three different RED Heat Engine scenarios were studied. Results show that power densities much higher than those relevant to NaCl-water solutions can be obtained by using different salts, especially those based on lithium ion (i.e. LiBr and LiCl). Results on the closed loop show efficiencies up to about 15% corresponding to an exergetic efficiency of about 85%, thus suggesting that the RED Heat Engine could potentially be a promising technology, with applications mainly in the industry where low-grade heat that has no alternative use can be converted into electricity.

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  • Tamburini, A. & Tedesco, M. & Cipollina, A. & Micale, G. & Ciofalo, M. & Papapetrou, M. & Van Baak, W. & Piacentino, A., 2017. "Reverse electrodialysis heat engine for sustainable power production," Applied Energy, Elsevier, vol. 206(C), pages 1334-1353.
    • Handle: RePEc:eee:appene:v:206:y:2017:i:c:p:1334-1353
    DOI: 10.1016/j.apenergy.2017.10.008
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    3. Zhang, Yongwen & Wu, Xi & Sun, Dexin & Wang, Sixue & Xu, Shiming, 2023. "Techno-economic analysis of conversing the low-grade heat to hydrogen by using reverse electrodialysis – Air gap diffusion distillation coupled method for iron and steel industry," Energy, Elsevier, vol. 283(C).
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    6. Giacalone, F. & Olkis, C. & Santori, G. & Cipollina, A. & Brandani, S. & Micale, G., 2019. "Novel solutions for closed-loop reverse electrodialysis: Thermodynamic characterisation and perspective analysis," Energy, Elsevier, vol. 166(C), pages 674-689.
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    8. Long, Rui & Zhao, Yanan & Li, Mingliang & Pan, Yao & Liu, Zhichun & Liu, Wei, 2021. "Evaluations of adsorbents and salt-methanol solutions for low-grade heat driven osmotic heat engines," Energy, Elsevier, vol. 229(C).
    9. Tong, Xin & Liu, Su & Yan, Junchen & Broesicke, Osvaldo A. & Chen, Yongsheng & Crittenden, John, 2020. "Thermolytic osmotic heat engine for low-grade heat harvesting: Thermodynamic investigation and potential application exploration," Applied Energy, Elsevier, vol. 259(C).
    10. Olkis, C. & Santori, G. & Brandani, S., 2018. "An Adsorption Reverse Electrodialysis system for the generation of electricity from low-grade heat," Applied Energy, Elsevier, vol. 231(C), pages 222-234.
    11. Vicari, Fabrizio & Galia, Alessandro & Scialdone, Onofrio, 2021. "Development of a membrane-less microfluidic thermally regenerative ammonia battery," Energy, Elsevier, vol. 225(C).
    12. Ortega-Delgado, B. & Giacalone, F. & Cipollina, A. & Papapetrou, M. & Kosmadakis, G. & Tamburini, A. & Micale, G., 2019. "Boosting the performance of a Reverse Electrodialysis – Multi-Effect Distillation Heat Engine by novel solutions and operating conditions," Applied Energy, Elsevier, vol. 253(C), pages 1-1.
    13. Luo, Qizhao & Pei, Junxian & Yun, Panfeng & Hu, Xuejiao & Cao, Bin & Shan, Kunpeng & Tang, Bin & Huang, Kaiming & Chen, Aofei & Huang, Lu & Huang, Zhi & Jiang, Haifeng, 2023. "Simultaneous water production and electricity generation driven by synergistic temperature-salinity gradient in thermo-osmosis process," Applied Energy, Elsevier, vol. 351(C).
    14. Liu, Zijian & Lu, Ding & Guo, Hao & Zhang, Jiayu & Tao, Shen & Chen, Rundong & Chen, LingYu & Gong, Maoqiong, 2023. "Experimental study and prospect analysis of LiBr-H2O reverse electrodialysis heat engine," Applied Energy, Elsevier, vol. 350(C).
    15. Tufa, Ramato Ashu & Pawlowski, Sylwin & Veerman, Joost & Bouzek, Karel & Fontananova, Enrica & di Profio, Gianluca & Velizarov, Svetlozar & Goulão Crespo, João & Nijmeijer, Kitty & Curcio, Efrem, 2018. "Progress and prospects in reverse electrodialysis for salinity gradient energy conversion and storage," Applied Energy, Elsevier, vol. 225(C), pages 290-331.
    16. Mai, Van-Phung & Yang, Ruey-Jen, 2020. "Boosting power generation from salinity gradient on high-density nanoporous membrane using thermal effect," Applied Energy, Elsevier, vol. 274(C).
    17. Simon B. B. Solberg & Pauline Zimmermann & Øivind Wilhelmsen & Jacob J. Lamb & Robert Bock & Odne S. Burheim, 2022. "Heat to Hydrogen by Reverse Electrodialysis—Using a Non-Equilibrium Thermodynamics Model to Evaluate Hydrogen Production Concepts Utilising Waste Heat," Energies, MDPI, vol. 15(16), pages 1-22, August.
    18. Zhao, Yanan & Luo, Zuoqing & Long, Rui & Liu, Zhichun & Liu, Wei, 2020. "Performance evaluations of an adsorption-based power and cooling cogeneration system under different operative conditions and working fluids," Energy, Elsevier, vol. 204(C).
    19. Patricia Palenzuela & Marina Micari & Bartolomé Ortega-Delgado & Francesco Giacalone & Guillermo Zaragoza & Diego-César Alarcón-Padilla & Andrea Cipollina & Alessandro Tamburini & Giorgio Micale, 2018. "Performance Analysis of a RED-MED Salinity Gradient Heat Engine," Energies, MDPI, vol. 11(12), pages 1-23, December.
    20. Michael Papapetrou & George Kosmadakis & Francesco Giacalone & Bartolomé Ortega-Delgado & Andrea Cipollina & Alessandro Tamburini & Giorgio Micale, 2019. "Evaluation of the Economic and Environmental Performance of Low-Temperature Heat to Power Conversion using a Reverse Electrodialysis – Multi-Effect Distillation System," Energies, MDPI, vol. 12(17), pages 1-26, August.

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