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Reverse electrodialysis with NH4HCO3-water systems for heat-to-power conversion

Author

Listed:
  • Bevacqua, M.
  • Tamburini, A.
  • Papapetrou, M.
  • Cipollina, A.
  • Micale, G.
  • Piacentino, A.

Abstract

A Reverse ElectroDialysis Heat Engine (REDHE) system operating with “thermolytic” ammonium hydrogen-carbonate (NH4HCO3) aqueous solutions as working fluids is studied. The engine is constituted by (i) a RED unit to produce electric power by mixing the solutions at different salinity and (ii) a thermally-driven regeneration unit including a stripping and an absorption column to restore the initial salinity gradient thus closing the cycle. In the present work only the RED unit and the stripping column are taken into account. In particular, a simplified integrated process model for the whole cycle was developed: it consists of (i) a lumped parameter model for the RED unit validated with experimental data and (ii) a model developed via a process simulator to assess the thermal duty of the stripping column. The effect of operating conditions as solution concentrations and velocities was investigated by a sensitivity analysis. Under the best conditions (among those investigated), a power density of about 9 W/m2 of cell pair was predicted for the RED unit, and a maximum exergetic efficiency of about 22% was found for the whole cycle. A preliminary economic analysis of the process is also provided.

Suggested Citation

  • Bevacqua, M. & Tamburini, A. & Papapetrou, M. & Cipollina, A. & Micale, G. & Piacentino, A., 2017. "Reverse electrodialysis with NH4HCO3-water systems for heat-to-power conversion," Energy, Elsevier, vol. 137(C), pages 1293-1307.
    • Handle: RePEc:eee:energy:v:137:y:2017:i:c:p:1293-1307
    DOI: 10.1016/j.energy.2017.07.012
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    5. Long, Rui & Zhao, Yanan & Li, Mingliang & Pan, Yao & Liu, Zhichun & Liu, Wei, 2021. "Evaluations of adsorbents and salt-methanol solutions for low-grade heat driven osmotic heat engines," Energy, Elsevier, vol. 229(C).
    6. Tong, Xin & Liu, Su & Yan, Junchen & Broesicke, Osvaldo A. & Chen, Yongsheng & Crittenden, John, 2020. "Thermolytic osmotic heat engine for low-grade heat harvesting: Thermodynamic investigation and potential application exploration," Applied Energy, Elsevier, vol. 259(C).
    7. Ortega-Delgado, B. & Giacalone, F. & Cipollina, A. & Papapetrou, M. & Kosmadakis, G. & Tamburini, A. & Micale, G., 2019. "Boosting the performance of a Reverse Electrodialysis – Multi-Effect Distillation Heat Engine by novel solutions and operating conditions," Applied Energy, Elsevier, vol. 253(C), pages 1-1.
    8. Liu, Zijian & Lu, Ding & Guo, Hao & Zhang, Jiayu & Tao, Shen & Chen, Rundong & Chen, LingYu & Gong, Maoqiong, 2023. "Experimental study and prospect analysis of LiBr-H2O reverse electrodialysis heat engine," Applied Energy, Elsevier, vol. 350(C).
    9. Ciofalo, Michele & La Cerva, Mariagiorgia & Di Liberto, Massimiliano & Gurreri, Luigi & Cipollina, Andrea & Micale, Giorgio, 2019. "Optimization of net power density in Reverse Electrodialysis," Energy, Elsevier, vol. 181(C), pages 576-588.
    10. Simon B. B. Solberg & Pauline Zimmermann & Øivind Wilhelmsen & Jacob J. Lamb & Robert Bock & Odne S. Burheim, 2022. "Heat to Hydrogen by Reverse Electrodialysis—Using a Non-Equilibrium Thermodynamics Model to Evaluate Hydrogen Production Concepts Utilising Waste Heat," Energies, MDPI, vol. 15(16), pages 1-22, August.
    11. Giacalone, F. & Papapetrou, M. & Kosmadakis, G. & Tamburini, A. & Micale, G. & Cipollina, A., 2019. "Application of reverse electrodialysis to site-specific types of saline solutions: A techno-economic assessment," Energy, Elsevier, vol. 181(C), pages 532-547.
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