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Modeling of power generation from the mixing of simulated saline and freshwater with a reverse electrodialysis system: The effect of monovalent and multivalent ions

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  • Hong, Jin Gi
  • Zhang, Wen
  • Luo, Jian
  • Chen, Yongsheng

Abstract

A reverse electrodialysis (RED) system utilizes the transport of cations and anions from controlled mixing of saline water (e.g., seawater) and freshwater (e.g., river water) through selective ion exchange membranes for power generation. Sodium chloride alone has been widely used to create power via salinity gradients in lab-scale RED systems. In an effort to simulate realistic salinity conditions in the natural water environment, in this study a new RED model was developed to quantify the power generation with coexisting monovalent and multivalent salt ions. The effects of different flow rate ratios (saline water flow, ØS, over freshwater flow, ØF) and intermembrane distance ratios on power density (amount of power per unit membrane area) were investigated. Our results indicated that magnesium sulfate, sodium sulfate, and magnesium chloride in the feed solutions of the RED system led to a 9–20% lower power density than when sodium chloride was the single ion source, largely because of the higher internal stack resistance of the multivalent ions. Higher power densities could be achieved with higher flow rates in the saline water compartment and shorter intermembrane distances in the freshwater compartment. For example, the power density increased by approximately 11% when the flow rate ratio was 5 compared with 1; similarly, an intermembrane distance ratio of 8 yielded an approximately 85% increase in power density compared with a ratio of 1. The goal of the present work is to advance our understanding of RED systems working in realistic salinity environments.

Suggested Citation

  • Hong, Jin Gi & Zhang, Wen & Luo, Jian & Chen, Yongsheng, 2013. "Modeling of power generation from the mixing of simulated saline and freshwater with a reverse electrodialysis system: The effect of monovalent and multivalent ions," Applied Energy, Elsevier, vol. 110(C), pages 244-251.
  • Handle: RePEc:eee:appene:v:110:y:2013:i:c:p:244-251
    DOI: 10.1016/j.apenergy.2013.04.015
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    1. Farrell, Eanna & Hassan, Mohamed I. & Tufa, Ramato A. & Tuomiranta, Arttu & Avci, Ahmet H. & Politano, Antonio & Curcio, Efrem & Arafat, Hassan A., 2017. "Reverse electrodialysis powered greenhouse concept for water- and energy-self-sufficient agriculture," Applied Energy, Elsevier, vol. 187(C), pages 390-409.
    2. Kim, Deok Han & Park, Byung Ho & Kwon, Kilsung & Li, Longnan & Kim, Daejoong, 2017. "Modeling of power generation with thermolytic reverse electrodialysis for low-grade waste heat recovery," Applied Energy, Elsevier, vol. 189(C), pages 201-210.
    3. Tufa, Ramato Ashu & Noviello, Ylenia & Di Profio, Gianluca & Macedonio, Francesca & Ali, Aamer & Drioli, Enrico & Fontananova, Enrica & Bouzek, Karel & Curcio, Efrem, 2019. "Integrated membrane distillation-reverse electrodialysis system for energy-efficient seawater desalination," Applied Energy, Elsevier, vol. 253(C), pages 1-1.
    4. Tamburini, A. & Tedesco, M. & Cipollina, A. & Micale, G. & Ciofalo, M. & Papapetrou, M. & Van Baak, W. & Piacentino, A., 2017. "Reverse electrodialysis heat engine for sustainable power production," Applied Energy, Elsevier, vol. 206(C), pages 1334-1353.
    5. Tufa, Ramato Ashu & Pawlowski, Sylwin & Veerman, Joost & Bouzek, Karel & Fontananova, Enrica & di Profio, Gianluca & Velizarov, Svetlozar & Goulão Crespo, João & Nijmeijer, Kitty & Curcio, Efrem, 2018. "Progress and prospects in reverse electrodialysis for salinity gradient energy conversion and storage," Applied Energy, Elsevier, vol. 225(C), pages 290-331.
    6. Mai, Van-Phung & Yang, Ruey-Jen, 2020. "Boosting power generation from salinity gradient on high-density nanoporous membrane using thermal effect," Applied Energy, Elsevier, vol. 274(C).
    7. Patricia Palenzuela & Marina Micari & Bartolomé Ortega-Delgado & Francesco Giacalone & Guillermo Zaragoza & Diego-César Alarcón-Padilla & Andrea Cipollina & Alessandro Tamburini & Giorgio Micale, 2018. "Performance Analysis of a RED-MED Salinity Gradient Heat Engine," Energies, MDPI, vol. 11(12), pages 1-23, December.
    8. Long, Rui & Li, Baode & Liu, Zhichun & Liu, Wei, 2018. "Reverse electrodialysis: Modelling and performance analysis based on multi-objective optimization," Energy, Elsevier, vol. 151(C), pages 1-10.

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