IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v104y2013icp21-41.html
   My bibliography  Save this article

Numerical simulations of carbon monoxide poisoning in high temperature proton exchange membrane fuel cells with various flow channel designs

Author

Listed:
  • Jiao, Kui
  • Zhou, Yibo
  • Du, Qing
  • Yin, Yan
  • Yu, Shuhai
  • Li, Xianguo

Abstract

The performance of high temperature proton exchange membrane fuel cell (HT-PEMFC) is significantly affected by the carbon monoxide (CO) in hydrogen fuel, and the flow channel design may influence the CO poisoning characteristics by changing the reactant flow. In this study, three-dimensional non-isothermal simulations are carried out to investigate the comprehensive flow channel design and CO poisoning effects on the performance of HT-PEMFCs. The numerical results show that when pure hydrogen is supplied, the interdigitated design produces the highest power output, the power output with serpentine design is higher than the two parallel designs, and the parallel-Z and parallel-U designs have similar power outputs. The performance degradation caused by CO poisoning is the least significant with parallel flow channel design, but the most significant with serpentine and interdigitated designs because the cross flow through the electrode is stronger. At low cell voltages (high current densities), the highest power outputs are with interdigitated and parallel flow channel designs at low and high CO fractions in the supplied hydrogen, respectively. The general distributions of absorbed hydrogen and CO coverage fractions in anode catalyst layer (CL) are similar for the different flow channel designs. The hydrogen coverage fraction is higher under the channel than under the land, and is also higher on the gas diffusion layer (GDL) side than on the membrane side; and the CO coverage distribution is opposite to the hydrogen coverage distribution.

Suggested Citation

  • Jiao, Kui & Zhou, Yibo & Du, Qing & Yin, Yan & Yu, Shuhai & Li, Xianguo, 2013. "Numerical simulations of carbon monoxide poisoning in high temperature proton exchange membrane fuel cells with various flow channel designs," Applied Energy, Elsevier, vol. 104(C), pages 21-41.
  • Handle: RePEc:eee:appene:v:104:y:2013:i:c:p:21-41
    DOI: 10.1016/j.apenergy.2012.10.059
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261912007787
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.apenergy.2012.10.059?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. J.J. Baschuk & Xianguo Li, 2003. "Mathematical model of a PEM fuel cell incorporating CO poisoning and O 2 (air) bleeding," International Journal of Global Energy Issues, Inderscience Enterprises Ltd, vol. 20(3), pages 245-276.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Wu, Qixing & Li, Haiyang & Yuan, Wenxiang & Luo, Zhongkuan & Wang, Fang & Sun, Hongyuan & Zhao, Xuxin & Fu, Huide, 2015. "Performance evaluation of an air-breathing high-temperature proton exchange membrane fuel cell," Applied Energy, Elsevier, vol. 160(C), pages 146-152.
    2. Li, Yan & Shi, Yan & Mehio, Nada & Tan, Mingsheng & Wang, Zhiyong & Hu, Xiaohong & Chen, George Z. & Dai, Sheng & Jin, Xianbo, 2016. "More sustainable electricity generation in hot and dry fuel cells with a novel hybrid membrane of Nafion/nano-silica/hydroxyl ionic liquid," Applied Energy, Elsevier, vol. 175(C), pages 451-458.
    3. Thomas, Sobi & Vang, Jakob Rabjerg & Araya, Samuel Simon & Kær, Søren Knudsen, 2017. "Experimental study to distinguish the effects of methanol slip and water vapour on a high temperature PEM fuel cell at different operating conditions," Applied Energy, Elsevier, vol. 192(C), pages 422-436.
    4. Zhang, Jun & Zhang, Caizhi & Li, Jin & Deng, Bo & Fan, Min & Ni, Meng & Mao, Zhanxin & Yuan, Honggeng, 2021. "Multi-perspective analysis of CO poisoning in high-temperature proton exchange membrane fuel cell stack via numerical investigation," Renewable Energy, Elsevier, vol. 180(C), pages 313-328.
    5. Hou, Yuze & Deng, Hao & Pan, Fengwen & Chen, Wenmiao & Du, Qing & Jiao, Kui, 2019. "Pore-scale investigation of catalyst layer ingredient and structure effect in proton exchange membrane fuel cell," Applied Energy, Elsevier, vol. 253(C), pages 1-1.
    6. Samsun, Remzi Can & Pasel, Joachim & Janßen, Holger & Lehnert, Werner & Peters, Ralf & Stolten, Detlef, 2014. "Design and test of a 5kWe high-temperature polymer electrolyte fuel cell system operated with diesel and kerosene," Applied Energy, Elsevier, vol. 114(C), pages 238-249.
    7. Thomas, Sobi & Bates, Alex & Park, Sam & Sahu, A.K. & Lee, Sang C. & Son, Byung Rak & Kim, Joo Gon & Lee, Dong-Ha, 2016. "An experimental and simulation study of novel channel designs for open-cathode high-temperature polymer electrolyte membrane fuel cells," Applied Energy, Elsevier, vol. 165(C), pages 765-776.
    8. Cho, Junhyun & Park, Jaeman & Oh, Hwanyeong & Min, Kyoungdoug & Lee, Eunsook & Jyoung, Jy-Young, 2013. "Analysis of the transient response and durability characteristics of a proton exchange membrane fuel cell with different micro-porous layer penetration thicknesses," Applied Energy, Elsevier, vol. 111(C), pages 300-309.
    9. Xu, Jiawei & Xiao, Shengying & Xu, Xinrui & Xu, Xinhai, 2022. "Numerical study of carbon monoxide poisoning effect on high temperature PEMFCs based on an elementary reaction kinetics coupled electrochemical reaction model," Applied Energy, Elsevier, vol. 318(C).
    10. Zhang, S. & Reimer, U. & Beale, S.B. & Lehnert, W. & Stolten, D., 2019. "Modeling polymer electrolyte fuel cells: A high precision analysis," Applied Energy, Elsevier, vol. 233, pages 1094-1103.
    11. Ong, Samuel & Al-Othman, Amani & Tawalbeh, Muhammad, 2023. "Emerging technologies in prognostics for fuel cells including direct hydrocarbon fuel cells," Energy, Elsevier, vol. 277(C).
    12. Abdul Rasheed, Raj Kamal & Chan, Siew Hwa, 2015. "Transient carbon monoxide poisoning kinetics during warm-up period of a high-temperature PEMFC – Physical model and parametric study," Applied Energy, Elsevier, vol. 140(C), pages 44-51.
    13. Pei, Pucheng & Chen, Huicui, 2014. "Main factors affecting the lifetime of Proton Exchange Membrane fuel cells in vehicle applications: A review," Applied Energy, Elsevier, vol. 125(C), pages 60-75.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Baschuk, J.J. & Li, Xianguo, 2009. "A comprehensive, consistent and systematic mathematical model of PEM fuel cells," Applied Energy, Elsevier, vol. 86(2), pages 181-193, February.
    2. Wang, Yun & Chen, Ken S. & Mishler, Jeffrey & Cho, Sung Chan & Adroher, Xavier Cordobes, 2011. "A review of polymer electrolyte membrane fuel cells: Technology, applications, and needs on fundamental research," Applied Energy, Elsevier, vol. 88(4), pages 981-1007, April.
    3. Dimitrova, Zlatina & Nader, Wissam Bou, 2022. "PEM fuel cell as an auxiliary power unit for range extended hybrid electric vehicles," Energy, Elsevier, vol. 239(PA).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:104:y:2013:i:c:p:21-41. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.