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Highly stable graphite nanoparticle-dispersed phase change emulsions with little supercooling and high thermal conductivity for cold energy storage

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  • Wang, Fangxian
  • Zhang, Chao
  • Liu, Jian
  • Fang, Xiaoming
  • Zhang, Zhengguo

Abstract

Graphite nanoparticles used as a nucleating agent have been dispersed into a phase change emulsion containing 30wt% of OP10E, aiming at eliminating its supercooling and improving its thermal conductivity. Based on the optimizations using surface response methodology, the stable OP10E emulsion with small droplets can be prepared with the aid of the emulsifier with a HLB value of 8.9 at a loading of 5wt%. It is found that the degree of supercooling for the emulsion decreases from 9.9°C to almost 0°C after the dispersion of the graphite nanoparticles at an optimal concentration of 2wt%, suggesting a complete elimination in supercooling. The addition of the graphite nanoparticles has no effect on latent heat of the OP10E/water emulsion. The thermal conductivity of the emulsion containing 2wt% graphite is 0.578Wm−1K−1, achieving an enhancement by 88.9% as compared to the one without graphite. The viscosity of the emulsion containing 2wt% graphite is lower than 11.5mPas, meeting the transportability requirements for pumping in practical applications. No distinct changes in these properties have been observed for the emulsion after being stored for 30days or being experienced 300 heating-cooling cycles test, implying its good dispersion stability and thermal reliability. The high energy storage capacity, little supercooling, enhanced thermal conductivity, excellent thermal reliability and good fluidity make the graphite nanoparticles-dispersed OP10E/water emulsion show great potential for use as a novel cool storage fluid for high efficiency cool storage device.

Suggested Citation

  • Wang, Fangxian & Zhang, Chao & Liu, Jian & Fang, Xiaoming & Zhang, Zhengguo, 2017. "Highly stable graphite nanoparticle-dispersed phase change emulsions with little supercooling and high thermal conductivity for cold energy storage," Applied Energy, Elsevier, vol. 188(C), pages 97-106.
    • Handle: RePEc:eee:appene:v:188:y:2017:i:c:p:97-106
    DOI: 10.1016/j.apenergy.2016.11.122
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    1. Oró, E. & de Gracia, A. & Castell, A. & Farid, M.M. & Cabeza, L.F., 2012. "Review on phase change materials (PCMs) for cold thermal energy storage applications," Applied Energy, Elsevier, vol. 99(C), pages 513-533.
    2. Shao, Jingjing & Darkwa, Jo & Kokogiannakis, Georgios, 2016. "Development of a novel phase change material emulsion for cooling systems," Renewable Energy, Elsevier, vol. 87(P1), pages 509-516.
    3. Fan, Li-Wu & Yao, Xiao-Li & Wang, Xiao & Wu, Yu-Yue & Liu, Xue-Ling & Xu, Xu & Yu, Zi-Tao, 2015. "Non-isothermal crystallization of aqueous nanofluids with high aspect-ratio carbon nano-additives for cold thermal energy storage," Applied Energy, Elsevier, vol. 138(C), pages 193-201.
    4. Alizadeh, M. & Sadrameli, S.M., 2016. "Development of free cooling based ventilation technology for buildings: Thermal energy storage (TES) unit, performance enhancement techniques and design considerations – A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 58(C), pages 619-645.
    5. Zhang, P. & Ma, Z.W., 2012. "An overview of fundamental studies and applications of phase change material slurries to secondary loop refrigeration and air conditioning systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(7), pages 5021-5058.
    6. Lu, W. & Tassou, S.A., 2012. "Experimental study of the thermal characteristics of phase change slurries for active cooling," Applied Energy, Elsevier, vol. 91(1), pages 366-374.
    7. Huang, Li & Petermann, Marcus & Doetsch, Christian, 2009. "Evaluation of paraffin/water emulsion as a phase change slurry for cooling applications," Energy, Elsevier, vol. 34(9), pages 1145-1155.
    8. Mosaffa, A.H. & Garousi Farshi, L., 2016. "Exergoeconomic and environmental analyses of an air conditioning system using thermal energy storage," Applied Energy, Elsevier, vol. 162(C), pages 515-526.
    9. Akeiber, Hussein & Nejat, Payam & Majid, Muhd Zaimi Abd. & Wahid, Mazlan A. & Jomehzadeh, Fatemeh & Zeynali Famileh, Iman & Calautit, John Kaiser & Hughes, Ben Richard & Zaki, Sheikh Ahmad, 2016. "A review on phase change material (PCM) for sustainable passive cooling in building envelopes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 60(C), pages 1470-1497.
    10. Zhang, P. & Ma, Z.W. & Wang, R.Z., 2010. "An overview of phase change material slurries: MPCS and CHS," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(2), pages 598-614, February.
    11. Zhai, X.Q. & Wang, X.L. & Wang, T. & Wang, R.Z., 2013. "A review on phase change cold storage in air-conditioning system: Materials and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 22(C), pages 108-120.
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