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Experimental study of the thermal characteristics of phase change slurries for active cooling

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  • Lu, W.
  • Tassou, S.A.

Abstract

Phase change materials (PCMs) are increasingly being used for thermal energy storage in buildings and industry to produce energy savings and reduce carbon dioxide emissions. PCM slurries are also being investigated for active thermal energy storage or as alternatives to conventional single phase fluids because they are pumpable and have advanced heat transport performance with phase change. The present study investigates several types of phase change materials for the preparation of PCM slurries which have potential for cooling applications. The thermophysical properties of paraffin in water emulsions, such as latent heat of fusion, melting and freezing temperature ranges, viscosity and the effect of surfactants, have been tested using appropriate experimental techniques. It has been identified that the use of small quantities of higher melting temperature paraffin and surfactants in the emulsion can reduce the effect of supercooling and increase the useful heat of fusion. However there are negative impacts on viscosity which should be considered in heat transport applications.

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  • Lu, W. & Tassou, S.A., 2012. "Experimental study of the thermal characteristics of phase change slurries for active cooling," Applied Energy, Elsevier, vol. 91(1), pages 366-374.
    • Handle: RePEc:eee:appene:v:91:y:2012:i:1:p:366-374
    DOI: 10.1016/j.apenergy.2011.10.004
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    6. Vorbeck, Laura & Gschwander, Stefan & Thiel, Peter & Lüdemann, Bruno & Schossig, Peter, 2013. "Pilot application of phase change slurry in a 5m3 storage," Applied Energy, Elsevier, vol. 109(C), pages 538-543.
    7. Shivangi Sharma & Nazmi Sellami & Asif A. Tahir & Tapas K. Mallick & Rohit Bhakar, 2021. "Performance Improvement of a CPV System: Experimental Investigation into Passive Cooling with Phase Change Materials," Energies, MDPI, vol. 14(12), pages 1-13, June.
    8. Giro-Paloma, Jessica & Barreneche, Camila & Martínez, Mònica & Šumiga, Boštjan & Cabeza, Luisa F. & Fernández, A. Inés, 2015. "Comparison of phase change slurries: Physicochemical and thermal properties," Energy, Elsevier, vol. 87(C), pages 223-227.
    9. Giro-Paloma, Jessica & Barreneche, Camila & Martínez, Mònica & Šumiga, Boštjan & Fernández, Ana Inés & Cabeza, Luisa F., 2016. "Mechanical response evaluation of microcapsules from different slurries," Renewable Energy, Elsevier, vol. 85(C), pages 732-739.
    10. Wang, Fangxian & Zhang, Chao & Liu, Jian & Fang, Xiaoming & Zhang, Zhengguo, 2017. "Highly stable graphite nanoparticle-dispersed phase change emulsions with little supercooling and high thermal conductivity for cold energy storage," Applied Energy, Elsevier, vol. 188(C), pages 97-106.
    11. Vitorino, Nuno & Abrantes, João C.C. & Frade, Jorge Ribeiro, 2013. "Gelled graphite/gelatin composites for latent heat cold storage," Applied Energy, Elsevier, vol. 104(C), pages 890-897.
    12. Li, Min, 2013. "A nano-graphite/paraffin phase change material with high thermal conductivity," Applied Energy, Elsevier, vol. 106(C), pages 25-30.
    13. Liu, Shengchun & Hao, Ling & Rao, Zhiming & Zhang, Xingxing, 2017. "Experimental study on crystallization process and prediction for the latent heat of ice slurry generation based sodium chloride solution," Applied Energy, Elsevier, vol. 185(P2), pages 1948-1953.
    14. Tang, Xiaofen & Li, Wei & Zhang, Xingxiang & Shi, Haifeng, 2014. "Fabrication and characterization of microencapsulated phase change material with low supercooling for thermal energy storage," Energy, Elsevier, vol. 68(C), pages 160-166.
    15. Chen, J. & Zhang, P., 2017. "Preparation and characterization of nano-sized phase change emulsions as thermal energy storage and transport media," Applied Energy, Elsevier, vol. 190(C), pages 868-879.
    16. Lu, W. & Tassou, S.A., 2013. "Characterization and experimental investigation of phase change materials for chilled food refrigerated cabinet applications," Applied Energy, Elsevier, vol. 112(C), pages 1376-1382.
    17. Giro-Paloma, Jessica & Martínez, Mònica & Cabeza, Luisa F. & Fernández, A. Inés, 2016. "Types, methods, techniques, and applications for microencapsulated phase change materials (MPCM): A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 53(C), pages 1059-1075.
    18. Shi, X.J. & Zhang, P., 2013. "A comparative study of different methods for the generation of tetra-n-butyl ammonium bromide clathrate hydrate slurry in a cold storage air-conditioning system," Applied Energy, Elsevier, vol. 112(C), pages 1393-1402.
    19. Zhang, Zhaoli & Yuan, Yanping & Zhang, Nan & Cao, Xiaoling, 2015. "Experimental investigation on thermophysical properties of capric acid–lauric acid phase change slurries for thermal storage system," Energy, Elsevier, vol. 90(P1), pages 359-368.
    20. David Cabaleiro & Samah Hamze & Filippo Agresti & Patrice Estellé & Simona Barison & Laura Fedele & Sergio Bobbo, 2019. "Dynamic Viscosity, Surface Tension and Wetting Behavior Studies of Paraffin–in–Water Nano–Emulsions," Energies, MDPI, vol. 12(17), pages 1-19, August.

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