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Encapsulation of phase change materials using rice-husk-char

Author

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  • Gondora, Wayne
  • Doudin, Khalid
  • Nowakowski, Daniel J.
  • Xiao, Bo
  • Ding, Yulong
  • Bridgwater, Tony
  • Yuan, Qingchun

Abstract

This paper explored a new approach to prepare phase change microcapsules using carbon-based particles via Pickering emulsions for energy storage applications. Rice-husk-char, a by-product in biofuel production, containing 53.58wt% of carbon was used as a model carbon-based material to encapsulate hexadecane. As a model phase change material, hexadecane was emulsified in aqueous suspensions of rice-husk-char nanoparticles. Water soluble polymers poly(diallyldimethyl-ammonium chloride) and poly(sodium styrene sulfonate) were used to fix the rice-husk-char nanoparticles on the emulsion droplets through layer-by-layer assembly to enhance the structural stability of the microcapsules. The microcapsules formed are composed of a thin shell encompassing a large core consisting of hexadecane. Thermal gravimetrical and differential scanning calorimeter analyses showed the phase change enthalpy of 80.9kJkg−1 or 120.0MJm−3. Design criteria of phase change microcapsules and preparation considerations were discussed in terms of desired applications. This work demonstrated possible utilisations of biomass-originated carbon-based material for thermal energy recovery and storage applications, which can be a new route of carbon capture and utilisation.

Suggested Citation

  • Gondora, Wayne & Doudin, Khalid & Nowakowski, Daniel J. & Xiao, Bo & Ding, Yulong & Bridgwater, Tony & Yuan, Qingchun, 2016. "Encapsulation of phase change materials using rice-husk-char," Applied Energy, Elsevier, vol. 182(C), pages 274-281.
    • Handle: RePEc:eee:appene:v:182:y:2016:i:c:p:274-281
    DOI: 10.1016/j.apenergy.2016.08.102
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    1. Palacios, Anabel & Elena Navarro, M. & Barreneche, Camila & Ding, Yulong, 2020. "Hybrid 3 in 1 thermal energy storage system – Outlook for a novel storage strategy," Applied Energy, Elsevier, vol. 274(C).
    2. Rostami, Sara & Afrand, Masoud & Shahsavar, Amin & Sheikholeslami, M. & Kalbasi, Rasool & Aghakhani, Saeed & Shadloo, Mostafa Safdari & Oztop, Hakan F., 2020. "A review of melting and freezing processes of PCM/nano-PCM and their application in energy storage," Energy, Elsevier, vol. 211(C).

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