IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v143y2015icp383-394.html
   My bibliography  Save this article

Temperature-dependent thermal properties of solid/liquid phase change even-numbered n-alkanes: n-Hexadecane, n-octadecane and n-eicosane

Author

Listed:
  • Vélez, C.
  • Khayet, M.
  • Ortiz de Zárate, J.M.

Abstract

The thermal conductivity (λ) and thermal diffusivity (aT) of the solid/liquid phase change linear n-alkanes were measured simultaneously by the transient multi-current hot wire technique at atmospheric pressure in the range 258–348K. The same set-up was used to measure λ and aT of the liquid and the solid states at different electrical currents. Three n-alkanes, n-hexadecane (C16H34), n-octadecane (C18H38) and n-eicosane (C20H42) were studied. Differential scanning calorimetry was applied at the temperature range 248–348K to determine the melting/crystallization temperature, the heat of melting/crystallization and the specific heat of both the solid and liquid phases. Some results were compared with available literature data. The density of the n-alkanes at liquid state was also measured at different temperatures and their thermal diffusivity was estimated and compared to that obtained by the hot wire technique. The cumulative energy stored was estimated over a definite range of temperature for the three n-alkanes and this was found to be higher for eicosane.

Suggested Citation

  • Vélez, C. & Khayet, M. & Ortiz de Zárate, J.M., 2015. "Temperature-dependent thermal properties of solid/liquid phase change even-numbered n-alkanes: n-Hexadecane, n-octadecane and n-eicosane," Applied Energy, Elsevier, vol. 143(C), pages 383-394.
    • Handle: RePEc:eee:appene:v:143:y:2015:i:c:p:383-394
    DOI: 10.1016/j.apenergy.2015.01.054
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261915000707
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2015.01.054?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Oró, E. & de Gracia, A. & Castell, A. & Farid, M.M. & Cabeza, L.F., 2012. "Review on phase change materials (PCMs) for cold thermal energy storage applications," Applied Energy, Elsevier, vol. 99(C), pages 513-533.
    2. Zhou, D. & Zhao, C.Y. & Tian, Y., 2012. "Review on thermal energy storage with phase change materials (PCMs) in building applications," Applied Energy, Elsevier, vol. 92(C), pages 593-605.
    3. Sarı, Ahmet & Alkan, Cemil & Bilgin, Cahit, 2014. "Micro/nano encapsulation of some paraffin eutectic mixtures with poly(methyl methacrylate) shell: Preparation, characterization and latent heat thermal energy storage properties," Applied Energy, Elsevier, vol. 136(C), pages 217-227.
    4. Jegadheeswaran, S. & Pohekar, Sanjay D., 2009. "Performance enhancement in latent heat thermal storage system: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(9), pages 2225-2244, December.
    5. Jiang, Fuyun & Wang, Xiaodong & Wu, Dezhen, 2014. "Design and synthesis of magnetic microcapsules based on n-eicosane core and Fe3O4/SiO2 hybrid shell for dual-functional phase change materials," Applied Energy, Elsevier, vol. 134(C), pages 456-468.
    6. Regin, A. Felix & Solanki, S.C. & Saini, J.S., 2008. "Heat transfer characteristics of thermal energy storage system using PCM capsules: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 12(9), pages 2438-2458, December.
    7. Fan, Liwu & Khodadadi, J.M., 2011. "Thermal conductivity enhancement of phase change materials for thermal energy storage: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(1), pages 24-46, January.
    8. Cabeza, L.F. & Castell, A. & Barreneche, C. & de Gracia, A. & Fernández, A.I., 2011. "Materials used as PCM in thermal energy storage in buildings: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(3), pages 1675-1695, April.
    9. Karaipekli, Ali & Sarı, Ahmet & Kaygusuz, Kamil, 2007. "Thermal conductivity improvement of stearic acid using expanded graphite and carbon fiber for energy storage applications," Renewable Energy, Elsevier, vol. 32(13), pages 2201-2210.
    10. Zhang, P. & Ma, Z.W. & Wang, R.Z., 2010. "An overview of phase change material slurries: MPCS and CHS," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(2), pages 598-614, February.
    11. Sharma, Atul & Tyagi, V.V. & Chen, C.R. & Buddhi, D., 2009. "Review on thermal energy storage with phase change materials and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(2), pages 318-345, February.
    12. O’Connor, William E. & Warzoha, Ronald & Weigand, Rebecca & Fleischer, Amy S. & Wemhoff, Aaron P., 2014. "Thermal property prediction and measurement of organic phase change materials in the liquid phase near the melting point," Applied Energy, Elsevier, vol. 132(C), pages 496-506.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Lee, Seunghoon & Lee, Hyoseong & Jun, Yong Joo & Lee, Hoseong, 2024. "Hybrid battery thermal management system coupled with paraffin/copper foam composite phase change material," Applied Energy, Elsevier, vol. 353(PA).
    2. Liu, Huan & Niu, Jinfei & Wang, Xiaodong & Wu, Dezhen, 2019. "Design and construction of mesoporous silica/n-eicosane phase-change nanocomposites for supercooling depression and heat transfer enhancement," Energy, Elsevier, vol. 188(C).
    3. Madruga, Santiago & Mendoza, Carolina, 2022. "Introducing a new concept for enhanced micro-energy harvesting of thermal fluctuations through the Marangoni effect," Applied Energy, Elsevier, vol. 306(PA).
    4. Moritz Faden & Andreas König-Haagen & Dieter Brüggemann, 2019. "An Optimum Enthalpy Approach for Melting and Solidification with Volume Change," Energies, MDPI, vol. 12(5), pages 1-21, March.
    5. Zhao, C.Y. & Tao, Y.B. & Yu, Y.S., 2022. "Thermal conductivity enhancement of phase change material with charged nanoparticle: A molecular dynamics simulation," Energy, Elsevier, vol. 242(C).
    6. Kahwaji, Samer & Johnson, Michel B. & Kheirabadi, Ali C. & Groulx, Dominic & White, Mary Anne, 2018. "A comprehensive study of properties of paraffin phase change materials for solar thermal energy storage and thermal management applications," Energy, Elsevier, vol. 162(C), pages 1169-1182.
    7. Ma, Zhesong & Wang, Yanhui & Wang, Shuxin & Yang, Yanan, 2016. "Ocean thermal energy harvesting with phase change material for underwater glider," Applied Energy, Elsevier, vol. 178(C), pages 557-566.
    8. Cottrill, Anton L. & Zhang, Ge & Liu, Albert Tianxiang & Bakytbekov, Azamat & Silmore, Kevin S. & Koman, Volodymyr B. & Shamim, Atif & Strano, Michael S., 2019. "Persistent energy harvesting in the harsh desert environment using a thermal resonance device: Design, testing, and analysis," Applied Energy, Elsevier, vol. 235(C), pages 1514-1523.
    9. Jung, Hyunjun & Subban, Chinmayee V. & McTigue, Joshua Dominic & Martinez, Jayson J. & Copping, Andrea E. & Osorio, Julian & Liu, Jian & Deng, Z. Daniel, 2022. "Extracting energy from ocean thermal and salinity gradients to power unmanned underwater vehicles: State of the art, current limitations, and future outlook," Renewable and Sustainable Energy Reviews, Elsevier, vol. 160(C).
    10. Yiyi Li & Haochun Zhang & Yingjie Chen & Jian Zhang, 2023. "Design and Analysis of a Temperature-Sensitive Thermal Meta-Regulator Possessing Different Heat Distribution Modes," Energies, MDPI, vol. 16(15), pages 1-22, August.
    11. Zhao, Rui & Gu, Junjie & Liu, Jie, 2017. "Optimization of a phase change material based internal cooling system for cylindrical Li-ion battery pack and a hybrid cooling design," Energy, Elsevier, vol. 135(C), pages 811-822.
    12. Liu, Huan & Wang, Xiaodong & Wu, Dezhen & Ji, Shengfu, 2019. "Morphology-controlled synthesis of microencapsulated phase change materials with TiO2 shell for thermal energy harvesting and temperature regulation," Energy, Elsevier, vol. 172(C), pages 599-617.
    13. Soares, N. & Matias, T. & Durães, L. & Simões, P.N. & Costa, J.J., 2023. "Thermophysical characterization of paraffin-based PCMs for low temperature thermal energy storage applications for buildings," Energy, Elsevier, vol. 269(C).
    14. Tong, Xuan & Li, Nianqi & Zeng, Min & Wang, Qiuwang, 2019. "Organic phase change materials confined in carbon-based materials for thermal properties enhancement: Recent advancement and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 108(C), pages 398-422.
    15. Abdelwaheb Trigui & Makki Abdelmouleh, 2023. "Improving the Heat Transfer of Phase Change Composites for Thermal Energy Storage by Adding Copper: Preparation and Thermal Properties," Sustainability, MDPI, vol. 15(3), pages 1-19, January.
    16. Qaderi, Alireza & Veysi, Farzad, 2022. "Investigation of a water-NEPCM cooling thermal management system for cylindrical 18650 Li-ion batteries," Energy, Elsevier, vol. 244(PA).
    17. Kawanami, Tsuyoshi & Togashi, Kenichi & Fumoto, Koji & Hirano, Shigeki & Zhang, Peng & Shirai, Katsuaki & Hirasawa, Shigeki, 2016. "Thermophysical properties and thermal characteristics of phase change emulsion for thermal energy storage media," Energy, Elsevier, vol. 117(P2), pages 562-568.
    18. Manfrida, Giampaolo & Secchi, Riccardo & Stańczyk, Kamil, 2016. "Modelling and simulation of phase change material latent heat storages applied to a solar-powered Organic Rankine Cycle," Applied Energy, Elsevier, vol. 179(C), pages 378-388.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Memon, Shazim Ali, 2014. "Phase change materials integrated in building walls: A state of the art review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 31(C), pages 870-906.
    2. Soares, N. & Bastos, J. & Pereira, L. Dias & Soares, A. & Amaral, A.R. & Asadi, E. & Rodrigues, E. & Lamas, F.B. & Monteiro, H. & Lopes, M.A.R. & Gaspar, A.R., 2017. "A review on current advances in the energy and environmental performance of buildings towards a more sustainable built environment," Renewable and Sustainable Energy Reviews, Elsevier, vol. 77(C), pages 845-860.
    3. Kenisarin, Murat & Mahkamov, Khamid, 2016. "Passive thermal control in residential buildings using phase change materials," Renewable and Sustainable Energy Reviews, Elsevier, vol. 55(C), pages 371-398.
    4. Ge, Haoshan & Li, Haiyan & Mei, Shengfu & Liu, Jing, 2013. "Low melting point liquid metal as a new class of phase change material: An emerging frontier in energy area," Renewable and Sustainable Energy Reviews, Elsevier, vol. 21(C), pages 331-346.
    5. Seddegh, Saeid & Wang, Xiaolin & Henderson, Alan D. & Xing, Ziwen, 2015. "Solar domestic hot water systems using latent heat energy storage medium: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 49(C), pages 517-533.
    6. Soares, N. & Gaspar, A.R. & Santos, P. & Costa, J.J., 2015. "Experimental study of the heat transfer through a vertical stack of rectangular cavities filled with phase change materials," Applied Energy, Elsevier, vol. 142(C), pages 192-205.
    7. Zeinelabdein, Rami & Omer, Siddig & Gan, Guohui, 2018. "Critical review of latent heat storage systems for free cooling in buildings," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 2843-2868.
    8. Rostami, Sara & Afrand, Masoud & Shahsavar, Amin & Sheikholeslami, M. & Kalbasi, Rasool & Aghakhani, Saeed & Shadloo, Mostafa Safdari & Oztop, Hakan F., 2020. "A review of melting and freezing processes of PCM/nano-PCM and their application in energy storage," Energy, Elsevier, vol. 211(C).
    9. Salunkhe, Pramod B. & Shembekar, Prashant S., 2012. "A review on effect of phase change material encapsulation on the thermal performance of a system," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(8), pages 5603-5616.
    10. Jankowski, Nicholas R. & McCluskey, F. Patrick, 2014. "A review of phase change materials for vehicle component thermal buffering," Applied Energy, Elsevier, vol. 113(C), pages 1525-1561.
    11. Tatsidjodoung, Parfait & Le Pierrès, Nolwenn & Luo, Lingai, 2013. "A review of potential materials for thermal energy storage in building applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 18(C), pages 327-349.
    12. Johra, Hicham & Heiselberg, Per, 2017. "Influence of internal thermal mass on the indoor thermal dynamics and integration of phase change materials in furniture for building energy storage: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 69(C), pages 19-32.
    13. Huang, Xiang & Alva, Guruprasad & Jia, Yuting & Fang, Guiyin, 2017. "Morphological characterization and applications of phase change materials in thermal energy storage: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 72(C), pages 128-145.
    14. Ioan Sarbu & Calin Sebarchievici, 2018. "A Comprehensive Review of Thermal Energy Storage," Sustainability, MDPI, vol. 10(1), pages 1-32, January.
    15. Nie, Binjian & Palacios, Anabel & Zou, Boyang & Liu, Jiaxu & Zhang, Tongtong & Li, Yunren, 2020. "Review on phase change materials for cold thermal energy storage applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 134(C).
    16. Ibrahim, Nasiru I. & Al-Sulaiman, Fahad A. & Rahman, Saidur & Yilbas, Bekir S. & Sahin, Ahmet Z., 2017. "Heat transfer enhancement of phase change materials for thermal energy storage applications: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 74(C), pages 26-50.
    17. Soares, N. & Santos, P. & Gervásio, H. & Costa, J.J. & Simões da Silva, L., 2017. "Energy efficiency and thermal performance of lightweight steel-framed (LSF) construction: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 78(C), pages 194-209.
    18. Zhang, Ying & Wang, Xiaodong & Wu, Dezhen, 2016. "Microencapsulation of n-dodecane into zirconia shell doped with rare earth: Design and synthesis of bifunctional microcapsules for photoluminescence enhancement and thermal energy storage," Energy, Elsevier, vol. 97(C), pages 113-126.
    19. Yuan, Yanping & Zhang, Nan & Li, Tianyu & Cao, Xiaoling & Long, Weiyue, 2016. "Thermal performance enhancement of palmitic-stearic acid by adding graphene nanoplatelets and expanded graphite for thermal energy storage: A comparative study," Energy, Elsevier, vol. 97(C), pages 488-497.
    20. AL-Saadi, Saleh Nasser & Zhai, Zhiqiang (John), 2013. "Modeling phase change materials embedded in building enclosure: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 21(C), pages 659-673.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:143:y:2015:i:c:p:383-394. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.