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Design and synthesis of magnetic microcapsules based on n-eicosane core and Fe3O4/SiO2 hybrid shell for dual-functional phase change materials

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  • Jiang, Fuyun
  • Wang, Xiaodong
  • Wu, Dezhen

Abstract

Magnetic microcapsules based on an n-eicosane core and Fe3O4/SiO2 hybrid shell were designed as a new type of dual-functional phase change materials. A series of magnetic microcapsule samples were synthesized through a two-step route. Fe3O4 nanoparticles were first self-assembled on the interface of n-eicosane droplets in a Pickering emulsion system, and then the silica matrix was fabricated through interfacial polycondensation of tetraethyl orthosilicate in the sol–gel process. On the basis of scanning and transmission electron microscopic investigations, the resultant magnetic microcapsules were found to present a perfect spherical morphology with a uniform particle size of 4–6μm, and they also showed a well-defined core–shell structure constructed by a smooth and compact shell. The chemical structures of the magnetic microcapsules were confirmed by Fourier transform infrared spectroscopy, and meanwhile, their chemical compositions from surface to inner layer were determined by X-ray photoelectron spectroscopy, energy-dispersive X-ray spectroscopy, and Raman scattering spectroscopy. These magnetic microcapsules achieved a good thermal-storage capability and high thermal reliability according to their phase-change performance detected by differential scanning calorimetry (DSC). The encapsulation efficiency and energy-storage efficiency were also deduced from the DSC data of the magnetic microcapsules synthesized with different mass ratios of core to shell. Most of all, the magnetic microcapsules exhibited a superparamagnetic nature with extremely low magnetic retentivity and coercivity. With such a dual-functional feature, the magnetic microcapsules developed by this study could provide a new applicable route for some high-tech fields to fulfill both thermal energy storage and magnetic effectiveness.

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  • Jiang, Fuyun & Wang, Xiaodong & Wu, Dezhen, 2014. "Design and synthesis of magnetic microcapsules based on n-eicosane core and Fe3O4/SiO2 hybrid shell for dual-functional phase change materials," Applied Energy, Elsevier, vol. 134(C), pages 456-468.
  • Handle: RePEc:eee:appene:v:134:y:2014:i:c:p:456-468
    DOI: 10.1016/j.apenergy.2014.08.061
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    1. Zhao, C.Y. & Zhang, G.H., 2011. "Review on microencapsulated phase change materials (MEPCMs): Fabrication, characterization and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(8), pages 3813-3832.
    2. Tyagi, V.V. & Kaushik, S.C. & Tyagi, S.K. & Akiyama, T., 2011. "Development of phase change materials based microencapsulated technology for buildings: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(2), pages 1373-1391, February.
    3. He, Fang & Wang, Xiaodong & Wu, Dezhen, 2014. "New approach for sol–gel synthesis of microencapsulated n-octadecane phase change material with silica wall using sodium silicate precursor," Energy, Elsevier, vol. 67(C), pages 223-233.
    4. SarI, Ahmet & Alkan, Cemil & Karaipekli, Ali, 2010. "Preparation, characterization and thermal properties of PMMA/n-heptadecane microcapsules as novel solid-liquid microPCM for thermal energy storage," Applied Energy, Elsevier, vol. 87(5), pages 1529-1534, May.
    5. Jamekhorshid, A. & Sadrameli, S.M. & Farid, M., 2014. "A review of microencapsulation methods of phase change materials (PCMs) as a thermal energy storage (TES) medium," Renewable and Sustainable Energy Reviews, Elsevier, vol. 31(C), pages 531-542.
    6. Yu, Shiyu & Wang, Xiaodong & Wu, Dezhen, 2014. "Microencapsulation of n-octadecane phase change material with calcium carbonate shell for enhancement of thermal conductivity and serving durability: Synthesis, microstructure, and performance evaluat," Applied Energy, Elsevier, vol. 114(C), pages 632-643.
    7. Sharma, Atul & Tyagi, V.V. & Chen, C.R. & Buddhi, D., 2009. "Review on thermal energy storage with phase change materials and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(2), pages 318-345, February.
    8. Cao, Fangyu & Yang, Bao, 2014. "Supercooling suppression of microencapsulated phase change materials by optimizing shell composition and structure," Applied Energy, Elsevier, vol. 113(C), pages 1512-1518.
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    16. Yataganbaba, Alptug & Ozkahraman, Bengi & Kurtbas, Irfan, 2017. "Worldwide trends on encapsulation of phase change materials: A bibliometric analysis (1990–2015)," Applied Energy, Elsevier, vol. 185(P1), pages 720-731.
    17. Vélez, C. & Khayet, M. & Ortiz de Zárate, J.M., 2015. "Temperature-dependent thermal properties of solid/liquid phase change even-numbered n-alkanes: n-Hexadecane, n-octadecane and n-eicosane," Applied Energy, Elsevier, vol. 143(C), pages 383-394.
    18. Wang, Tingyu & Wang, Shuangfeng & Luo, Ruilian & Zhu, Chunyu & Akiyama, Tomohiro & Zhang, Zhengguo, 2016. "Microencapsulation of phase change materials with binary cores and calcium carbonate shell for thermal energy storage," Applied Energy, Elsevier, vol. 171(C), pages 113-119.
    19. Zhang, Xiaoyu & Wang, Xiaodong & Wu, Dezhen, 2016. "Design and synthesis of multifunctional microencapsulated phase change materials with silver/silica double-layered shell for thermal energy storage, electrical conduction and antimicrobial effectivene," Energy, Elsevier, vol. 111(C), pages 498-512.
    20. Zhang, Ya & Liu, Huan & Niu, Jinfei & Wang, Xiaodong & Wu, Dezhen, 2020. "Development of reversible and durable thermochromic phase-change microcapsules for real-time indication of thermal energy storage and management," Applied Energy, Elsevier, vol. 264(C).
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