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Microencapsulated binary carbonate salt mixture in silica shell with enhanced effective heat capacity for high temperature latent heat storage

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  • Zhang, Hanfei
  • Shin, Donghyun
  • Santhanagopalan, Sunand

Abstract

Microencapsulated phase change materials (MEPCM) with large active surface area can improve the system's effective heat capacity as a thermal storage medium. However, its usage in high temperature applications like concentrated solar power (CSP) has not yet been achieved due to the lack of a feasible microencapsulation method for high temperature compatible materials. This work reports novel process developed to achieve the first microencapsulation of a complex material system with high latent heat such like binary carbonate and its potential usage as a high temperature compatible thermal storage medium for CSP application. The MEPCM was demonstrated to be thermally stable up to 540 °C with a repeatable latent heat of 220 J/g. The MEPCM provides a 134.4% effective heat capacity enhancement for a temperature range from 400 °C to 540 °C compared to solar salt as a thermal storage medium. Finally, the proposed microencapsulation process was also shown to be applicable to other salt systems, showing its great potential for different application temperatures.

Suggested Citation

  • Zhang, Hanfei & Shin, Donghyun & Santhanagopalan, Sunand, 2019. "Microencapsulated binary carbonate salt mixture in silica shell with enhanced effective heat capacity for high temperature latent heat storage," Renewable Energy, Elsevier, vol. 134(C), pages 1156-1162.
  • Handle: RePEc:eee:renene:v:134:y:2019:i:c:p:1156-1162
    DOI: 10.1016/j.renene.2018.09.011
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    5. Saranprabhu, M.K. & Rajan, K.S., 2019. "Magnesium oxide nanoparticles dispersed solar salt with improved solid phase thermal conductivity and specific heat for latent heat thermal energy storage," Renewable Energy, Elsevier, vol. 141(C), pages 451-459.

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