IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v220y2018icp408-418.html
   My bibliography  Save this article

Kinetics of synergistic effects in co-pyrolysis of biomass with plastic wastes

Author

Listed:
  • Burra, K.G.
  • Gupta, A.K.

Abstract

Co-pyrolysis of pinewood and different kinds of plastic wastes in different mass fractions using polypropylene (PP), polyethylene terephthalate (PETE), and polycarbonate (BPC) were investigated. The results compared with the pyrolysis of individual components revealed non-additive synergistic effects from co-pyrolysis. Differential thermography (DTG) results showed enhanced decomposition peaks of biomass along with longer evolution of syngas and decreased peak of plastic polymers using BPC or PETE. Char residue was non-additively reduced by some 5% (dry wt. basis) using PP and BPC, and by 2–3% using PETE when pyrolyzed with biomass. This suggests increased carbon conversion efficiency and volatiles yield during co-pyrolysis compared to individual component pyrolysis. First order distributed activation energy modeling (DAEM) with 5 pseudo-components revealed that the synergistic effects of biomass with PP or PETE were mainly due to physical nature of the polymers as observed from increased activation energy bandwidth of biomass decomposition. BPC and pinewood mixtures showed an overlap in their activation energy distribution between 100 and 150 kJ/mol. This overlap caused the set of reaction with similar energetics to mutually interact chemically and enhance the composite mixture pyrolysis. Activation energy of BPC in the presence of pinewood was reduced by some 50 kJ/mol compared to individually examined polymer decomposition. The observed quantitative synergistic kinetics results in co-pyrolysis of biomass-plastic wastes mixtures as compared to individual component pyrolysis provide vital information towards the development of feed-flexible, clean pyrolysis and gasification system for efficient fuels production.

Suggested Citation

  • Burra, K.G. & Gupta, A.K., 2018. "Kinetics of synergistic effects in co-pyrolysis of biomass with plastic wastes," Applied Energy, Elsevier, vol. 220(C), pages 408-418.
    • Handle: RePEc:eee:appene:v:220:y:2018:i:c:p:408-418
    DOI: 10.1016/j.apenergy.2018.03.117
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261918304550
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2018.03.117?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Ahmed, I.I. & Nipattummakul, N. & Gupta, A.K., 2011. "Characteristics of syngas from co-gasification of polyethylene and woodchips," Applied Energy, Elsevier, vol. 88(1), pages 165-174, January.
    2. Burra, K.G. & Hussein, M.S. & Amano, R.S. & Gupta, A.K., 2016. "Syngas evolutionary behavior during chicken manure pyrolysis and air gasification," Applied Energy, Elsevier, vol. 181(C), pages 408-415.
    3. Burra, K.G. & Gupta, A.K., 2018. "Synergistic effects in steam gasification of combined biomass and plastic waste mixtures," Applied Energy, Elsevier, vol. 211(C), pages 230-236.
    4. Cai, Junmeng & Wu, Weixuan & Liu, Ronghou, 2014. "An overview of distributed activation energy model and its application in the pyrolysis of lignocellulosic biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 36(C), pages 236-246.
    5. Ajay Kumar & David D. Jones & Milford A. Hanna, 2009. "Thermochemical Biomass Gasification: A Review of the Current Status of the Technology," Energies, MDPI, vol. 2(3), pages 1-26, July.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Burra, K.G. & Gupta, A.K., 2018. "Synergistic effects in steam gasification of combined biomass and plastic waste mixtures," Applied Energy, Elsevier, vol. 211(C), pages 230-236.
    2. Li, Jinhu & Burra, Kiran Raj G. & Wang, Zhiwei & Liu, Xuan & Gupta, Ashwani K., 2021. "Co-gasification of high-density polyethylene and pretreated pine wood," Applied Energy, Elsevier, vol. 285(C).
    3. Huang, Jijiang & Veksha, Andrei & Chan, Wei Ping & Giannis, Apostolos & Lisak, Grzegorz, 2022. "Chemical recycling of plastic waste for sustainable material management: A prospective review on catalysts and processes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 154(C).
    4. Buentello-Montoya, D.A. & Duarte-Ruiz, C.A. & Maldonado-Escalante, J.F., 2023. "Co-gasification of waste PET, PP and biomass for energy recovery: A thermodynamic model to assess the produced syngas quality," Energy, Elsevier, vol. 266(C).
    5. Zhang, Shiyu & Bie, Xuan & Qian, Zheng & Wu, Mengna & Li, Kaile & Li, Qinghai & Zhang, Yanguo & Zhou, Hui, 2024. "Synergistic interactions between cellulose and plastics (PET, HDPE, and PS) during CO2 gasification-catalytic reforming on Ni/CeO2 nanorod catalyst," Applied Energy, Elsevier, vol. 361(C).
    6. Zaini, Ilman Nuran & Gomez-Rueda, Yamid & García López, Cristina & Ratnasari, Devy Kartika & Helsen, Lieve & Pretz, Thomas & Jönsson, Pär Göran & Yang, Weihong, 2020. "Production of H2-rich syngas from excavated landfill waste through steam co-gasification with biochar," Energy, Elsevier, vol. 207(C).
    7. Aktas, Fatih & Mavukwana, Athi-enkosi & Burra, Kiran Raj Goud & Gupta, Ashwani K., 2024. "Role of spent FCC catalyst in pyrolysis and CO2-assisted gasification of pinewood," Applied Energy, Elsevier, vol. 366(C).
    8. Liu, Xuan & Burra, Kiran G. & Wang, Zhiwei & Li, Jinhu & Che, Defu & Gupta, Ashwani K., 2020. "On deconvolution for understanding synergistic effects in co-pyrolysis of pinewood and polypropylene," Applied Energy, Elsevier, vol. 279(C).
    9. Burra, Kiran Raj G. & Liu, Xuan & Wang, Zhiwei & Li, Jinhu & Che, Defu & Gupta, Ashwani K., 2021. "Quantifying the sources of synergistic effects in co-pyrolysis of pinewood and polystyrene," Applied Energy, Elsevier, vol. 302(C).
    10. Zuhal Akyürek, 2019. "Sustainable Valorization of Animal Manure and Recycled Polyester: Co-pyrolysis Synergy," Sustainability, MDPI, vol. 11(8), pages 1-14, April.
    11. Fazil, A. & Kumar, Sandeep & Mahajani, Sanjay M., 2022. "Downdraft co-gasification of high ash biomass and plastics," Energy, Elsevier, vol. 243(C).
    12. Ajorloo, Mojtaba & Ghodrat, Maryam & Scott, Jason & Strezov, Vladimir, 2022. "Modelling and statistical analysis of plastic biomass mixture co-gasification," Energy, Elsevier, vol. 256(C).
    13. Déparrois, N. & Singh, P. & Burra, K.G. & Gupta, A.K., 2019. "Syngas production from co-pyrolysis and co-gasification of polystyrene and paper with CO2," Applied Energy, Elsevier, vol. 246(C), pages 1-10.
    14. Dmitry Porshnov, 2022. "Evolution of pyrolysis and gasification as waste to energy tools for low carbon economy," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 11(1), January.
    15. Liu, Qian & Sun, Jianguo & Gu, Yonghua & Zhong, Wenqi & Gao, Ke, 2024. "Experimental study on CO2 co-gasification characteristics of biomass and waste plastics: Insight into interaction and targeted regulation method," Energy, Elsevier, vol. 292(C).
    16. Ramos, Ana & Monteiro, Eliseu & Silva, Valter & Rouboa, Abel, 2018. "Co-gasification and recent developments on waste-to-energy conversion: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P1), pages 380-398.
    17. Ramos, Ana & Rouboa, Abel, 2020. "Syngas production strategies from biomass gasification: Numerical studies for operational conditions and quality indexes," Renewable Energy, Elsevier, vol. 155(C), pages 1211-1221.
    18. AlNouss, Ahmed & McKay, Gordon & Al-Ansari, Tareq, 2020. "Enhancing waste to hydrogen production through biomass feedstock blending: A techno-economic-environmental evaluation," Applied Energy, Elsevier, vol. 266(C).
    19. Octávio Alves & Luís Calado & Roberta M. Panizio & Catarina Nobre & Eliseu Monteiro & Paulo Brito & Margarida Gonçalves, 2022. "Gasification of Solid Recovered Fuels with Variable Fractions of Polymeric Materials," Energies, MDPI, vol. 15(21), pages 1-19, November.
    20. Xia Liu & Juntao Wei & Wei Huo & Guangsuo Yu, 2017. "Gasification under CO 2 –Steam Mixture: Kinetic Model Study Based on Shared Active Sites," Energies, MDPI, vol. 10(11), pages 1-10, November.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:220:y:2018:i:c:p:408-418. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.