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Synthesis of hierarchically porous MnO2/rice husks derived carbon composite as high-performance electrode material for supercapacitors

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  • Yuan, Chuanjun
  • Lin, Haibo
  • Lu, Haiyan
  • Xing, Endong
  • Zhang, Yusi
  • Xie, Bingyao

Abstract

Hierarchically porous MnO2/rice husks derived carbon (MnO2/RHC) composite with excellent electrochemical properties has been prepared as active material for supercapacitors. In this study, a two-step process was utilized for constructing this composite, involving carbonization–activation of rice husks to obtain RHC and in situ chemical precipitation to incorporate MnO2. Ultimately, MnO2 was uniformly distributed on the surface of RHC and hierarchically porous structure was well retained in the resultant MnO2/RHC composite. Based on cyclic voltammetry and galvanostatic charge–discharge measurements in 0.5M Na2SO4 solution, MnO2/RHC composite exhibits much higher specific capacitance than that of RHC. The specific capacitance of MnO2/RHC composite reaches 197.6Fg−1 at the scan rate of 5mVs−1 and 210.3Fg−1 at the current density of 0.5Ag−1. MnO2/RHC composite also displays favorable cycling stability with 80.2% capacitance retention after 5000 galvanostatic charge–discharge cycles. Therefore, taking advantage of the interconnected hierarchical pores that exist in its microstructure, MnO2/RHC composite is supposed to be a promising electrode material for high-performance supercapacitors.

Suggested Citation

  • Yuan, Chuanjun & Lin, Haibo & Lu, Haiyan & Xing, Endong & Zhang, Yusi & Xie, Bingyao, 2016. "Synthesis of hierarchically porous MnO2/rice husks derived carbon composite as high-performance electrode material for supercapacitors," Applied Energy, Elsevier, vol. 178(C), pages 260-268.
    • Handle: RePEc:eee:appene:v:178:y:2016:i:c:p:260-268
    DOI: 10.1016/j.apenergy.2016.06.057
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    2. Bao, Jinpeng & Liang, Chen & Lu, Haiyan & Lin, Haibo & Shi, Zhan & Feng, Shouhua & Bu, Qijing, 2018. "Facile fabrication of porous carbon microtube with surrounding carbon skeleton for long-life electrochemical capacitive energy storage," Energy, Elsevier, vol. 155(C), pages 899-908.
    3. Nahed Ahmed Hussien, 2023. "Antimicrobial Potential of Biosynthesized Zinc Oxide Nanoparticles Using Banana Peel and Date Seeds Extracts," Sustainability, MDPI, vol. 15(11), pages 1-12, June.
    4. Barzegar, Farshad & Bello, Abdulhakeem & Dangbegnon, Julien K. & Manyala, Ncholu & Xia, Xiaohua, 2017. "Asymmetric supercapacitor based on activated expanded graphite and pinecone tree activated carbon with excellent stability," Applied Energy, Elsevier, vol. 207(C), pages 417-426.
    5. Cuong, Dinh Viet & Matsagar, Babasaheb M. & Lee, Mengshan & Hossain, Md. Shahriar A. & Yamauchi, Yusuke & Vithanage, Meththika & Sarkar, Binoy & Ok, Yong Sik & Wu, Kevin C.-W. & Hou, Chia-Hung, 2021. "A critical review on biochar-based engineered hierarchical porous carbon for capacitive charge storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).
    6. Li, Dezhi & Li, Shuo & Zhang, Shubo & Sun, Jianrui & Wang, Licheng & Wang, Kai, 2022. "Aging state prediction for supercapacitors based on heuristic kalman filter optimization extreme learning machine," Energy, Elsevier, vol. 250(C).
    7. Sun, Bingkang & Zhang, Xiaoyun & Fan, Xing & Wang, Ruiyu & Bai, Hongcun & Wei, Xianyong, 2022. "Interface modification based on MnO2@N-doped activated carbon composites for flexible solid-state asymmetric supercapacitors," Energy, Elsevier, vol. 249(C).
    8. Mukhtar Yeleuov & Christopher Seidl & Tolganay Temirgaliyeva & Azamat Taurbekov & Nicholay Prikhodko & Bakytzhan Lesbayev & Fail Sultanov & Chingis Daulbayev & Serik Kumekov, 2020. "Modified Activated Graphene-Based Carbon Electrodes from Rice Husk for Supercapacitor Applications," Energies, MDPI, vol. 13(18), pages 1-10, September.

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