IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v142y2018icp608-616.html
   My bibliography  Save this article

Simple and novel strategy to fabricate ultra-thin, lightweight, stackable solid-state supercapacitors based on MnO2-incorporated CNT-web paper

Author

Listed:
  • Patil, Bebi
  • Ahn, Suhyun
  • Park, Changyong
  • Song, Hyeonjun
  • Jeong, Youngjin
  • Ahn, Heejoon

Abstract

Thin, lightweight, stackable, solid-state supercapacitors are in great demand in the electronics industry because of their use in miniaturized devices. Herein, we report a simple and novel strategy to fabricate ultra-thin, lightweight, and stackable symmetric supercapacitors using MnO2-incorporated carbon nanotube (CNT)-web paper. SEM and TEM analyses revealed a uniform nanometer-scale coating of MnO2 on the individual fibers of the CNT-web paper after simple deposition at room temperature. The network structure of free-standing conductive CNT-web paper provides a short diffusion path, allowing for complete utilization of MnO2 in the charge storage process. A MnO2/CNT-web paper electrode showed an excellent areal capacitance of 135 mF cm−2 at 5 mV s−1 with a remarkable capacitance retention of 95% after 10,000 cycles. A symmetric solid-state supercapacitor containing MnO2/CNT-web paper displayed a high areal capacitance of 57 mF cm−2 with an energy density of 0.018 mWh cm−2 and a capacitance retention as high as 86% after 10,000 cycles. In addition, the voltage and capacitance were tripled by simply stacking three symmetric supercapacitors and connecting them in series and in parallel, respectively. We are optimistic that the excellent performance of the ultra-thin CNT-web paper-based supercapacitors demonstrated here will facilitate the development of compact supercapacitor banks in the near future.

Suggested Citation

  • Patil, Bebi & Ahn, Suhyun & Park, Changyong & Song, Hyeonjun & Jeong, Youngjin & Ahn, Heejoon, 2018. "Simple and novel strategy to fabricate ultra-thin, lightweight, stackable solid-state supercapacitors based on MnO2-incorporated CNT-web paper," Energy, Elsevier, vol. 142(C), pages 608-616.
    • Handle: RePEc:eee:energy:v:142:y:2018:i:c:p:608-616
    DOI: 10.1016/j.energy.2017.10.041
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544217317103
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2017.10.041?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Dubal, Deepak P. & Holze, Rudolf, 2013. "All-solid-state flexible thin film supercapacitor based on Mn3O4 stacked nanosheets with gel electrolyte," Energy, Elsevier, vol. 51(C), pages 407-412.
    2. Xu Peng & Huili Liu & Qin Yin & Junchi Wu & Pengzuo Chen & Guangzhao Zhang & Guangming Liu & Changzheng Wu & Yi Xie, 2016. "A zwitterionic gel electrolyte for efficient solid-state supercapacitors," Nature Communications, Nature, vol. 7(1), pages 1-8, September.
    3. Nguyen, Tuyen & Boudard, Michel & João Carmezim, M. & Fátima Montemor, M., 2017. "NixCo1-x(OH)2 nanosheets on carbon nanofoam paper as high areal capacity electrodes for hybrid supercapacitors," Energy, Elsevier, vol. 126(C), pages 208-216.
    4. Sieben, J.M. & Morallón, E. & Cazorla-Amorós, D., 2013. "Flexible ruthenium oxide-activated carbon cloth composites prepared by simple electrodeposition methods," Energy, Elsevier, vol. 58(C), pages 519-526.
    5. Miao, Fujun & Shao, Changlu & Li, Xinghua & Lu, Na & Wang, Kexin & Zhang, Xin & Liu, Yichun, 2016. "Polyaniline-coated electrospun carbon nanofibers with high mass loading and enhanced capacitive performance as freestanding electrodes for flexible solid-state supercapacitors," Energy, Elsevier, vol. 95(C), pages 233-241.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Pourjavadi, Ali & Doroudian, Mohadeseh & Ahadpour, Amirkhashayar & Pourbadiei, Behzad, 2018. "Preparation of flexible and free-standing graphene-based current collector via a new and facile self-assembly approach: Leading to a high performance porous graphene/polyaniline supercapacitor," Energy, Elsevier, vol. 152(C), pages 178-189.
    2. Dou, Shumei & Li, Ping & Tan, Dan & Li, Huiqin & Ren, Lijun & Wei, Fenyan, 2021. "Synthesis and capacitance performances of Ni–Mn-Oxides as electrode materials for high-performance supercapacitors," Energy, Elsevier, vol. 227(C).
    3. Iqbal, Muhammad Faisal & Ashiq, Muhammad Naeem & Hassan, Mahmood-Ul & Nawaz, Rahat & Masood, Aneeqa & Razaq, Aamir, 2018. "Excellent electrochemical behavior of graphene oxide based aluminum sulfide nanowalls for supercapacitor applications," Energy, Elsevier, vol. 159(C), pages 151-159.
    4. Scalia, Alberto & Bella, Federico & Lamberti, Andrea & Gerbaldi, Claudio & Tresso, Elena, 2019. "Innovative multipolymer electrolyte membrane designed by oxygen inhibited UV-crosslinking enables solid-state in plane integration of energy conversion and storage devices," Energy, Elsevier, vol. 166(C), pages 789-795.
    5. Pappu, Samhita & Rao, Tata N. & Martha, Surendra K. & Bulusu, Sarada V., 2022. "Electrodeposited Manganese Oxide based Redox Mediator Driven 2.2 V High Energy Density Aqueous Supercapacitor," Energy, Elsevier, vol. 243(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Mohd Nor, Najah Syahirah & Deraman, Mohamad & Omar, Ramli & Awitdrus, & Farma, Rakhmawati & Basri, Nur Hamizah & Mohd Dolah, Besek Nurdiana & Mamat, Nurul Fatin & Yatim, Baharudin & Md Daud, Mohd Nori, 2015. "Influence of gamma irradiation exposure on the performance of supercapacitor electrodes made from oil palm empty fruit bunches," Energy, Elsevier, vol. 79(C), pages 183-194.
    2. Li, Zijiong & Liu, Ping & Yun, Gaoqian & Shi, Kai & Lv, Xiaowei & Li, Kun & Xing, Jianhua & Yang, Baocheng, 2014. "3D (Three-dimensional) sandwich-structured of ZnO (zinc oxide)/rGO (reduced graphene oxide)/ZnO for high performance supercapacitors," Energy, Elsevier, vol. 69(C), pages 266-271.
    3. Kim, Jongmin & Ju, Haeri & Inamdar, Akbar I. & Jo, Yongcheol & Han, J. & Kim, Hyungsang & Im, Hyunsik, 2014. "Synthesis and enhanced electrochemical supercapacitor properties of Ag–MnO2–polyaniline nanocomposite electrodes," Energy, Elsevier, vol. 70(C), pages 473-477.
    4. Mirzaeian, Mojtaba & Abbas, Qaisar & Gibson, Des & Mazur, Michal, 2019. "Effect of nitrogen doping on the electrochemical performance of resorcinol-formaldehyde based carbon aerogels as electrode material for supercapacitor applications," Energy, Elsevier, vol. 173(C), pages 809-819.
    5. Yuan, Chuanjun & Lin, Haibo & Lu, Haiyan & Xing, Endong & Zhang, Yusi & Xie, Bingyao, 2016. "Synthesis of hierarchically porous MnO2/rice husks derived carbon composite as high-performance electrode material for supercapacitors," Applied Energy, Elsevier, vol. 178(C), pages 260-268.
    6. Ghosh, Sampad & Withanage, Sajeevi S. & Chamlagain, Bhim & Khondaker, Saiful I. & Harish, Sivasankaran & Saha, Bidyut Baran, 2020. "Low pressure sulfurization and characterization of multilayer MoS2 for potential applications in supercapacitors," Energy, Elsevier, vol. 203(C).
    7. Muhammad Yaseen & Muhammad Arif Khan Khattak & Muhammad Humayun & Muhammad Usman & Syed Shaheen Shah & Shaista Bibi & Bakhtiar Syed Ul Hasnain & Shah Masood Ahmad & Abbas Khan & Nasrullah Shah & Asif , 2021. "A Review of Supercapacitors: Materials Design, Modification, and Applications," Energies, MDPI, vol. 14(22), pages 1-40, November.
    8. Lo, An-Ya & Jheng, Yu & Huang, Tsao-Cheng & Tseng, Chuan-Ming, 2015. "Study on RuO2/CMK-3/CNTs composites for high power and high energy density supercapacitor," Applied Energy, Elsevier, vol. 153(C), pages 15-21.
    9. Yang, Yang & Xing, Kai & Yan, Minyue & Zhu, Xun & Ye, Dingding & Chen, Rong & Liao, Qiang, 2023. "A potential flexible fuel cell with dual-functional hydrogel based on multi-component crosslinked hybrid polyvinyl alcohol," Energy, Elsevier, vol. 265(C).
    10. Mei, Junfeng & Fu, Wenbin & Zhang, Zemin & Jiang, Xiao & Bu, Han & Jiang, Changjun & Xie, Erqing & Han, Weihua, 2017. "Vertically-aligned Co3O4 nanowires interconnected with Co(OH)2 nanosheets as supercapacitor electrode," Energy, Elsevier, vol. 139(C), pages 1153-1158.
    11. Park, Taehyun & Chang, Ikwhang & Jung, Ju Hae & Lee, Ha Beom & Ko, Seung Hwan & O'Hayre, Ryan & Yoo, Sung Jong & Cha, Suk Won, 2017. "Effect of assembly pressure on the performance of a bendable polymer electrolyte fuel cell based on a silver nanowire current collector," Energy, Elsevier, vol. 134(C), pages 412-419.
    12. Faraji, Soheila & Ani, Farid Nasir, 2015. "The development supercapacitor from activated carbon by electroless plating—A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 823-834.
    13. Maitra, Anirban & Bera, Ranadip & Halder, Lopamudra & Bera, Aswini & Paria, Sarbaranjan & Karan, Sumanta Kumar & Si, Suman Kumar & De, Anurima & Ojha, Suparna & Khatua, Bhanu Bhusan, 2021. "Photovoltaic and triboelectrification empowered light-weight flexible self-charging asymmetric supercapacitor cell for self-powered multifunctional electronics," Renewable and Sustainable Energy Reviews, Elsevier, vol. 151(C).
    14. Iqbal, Muhammad Faisal & Ashiq, Muhammad Naeem & Hassan, Mahmood-Ul & Nawaz, Rahat & Masood, Aneeqa & Razaq, Aamir, 2018. "Excellent electrochemical behavior of graphene oxide based aluminum sulfide nanowalls for supercapacitor applications," Energy, Elsevier, vol. 159(C), pages 151-159.
    15. Rath, Tanmoy & Pramanik, Nilkamal & Kumar, Sandeep, 2017. "High electrochemical performance flexible solid-state supercapacitor based on Co-doped reduced graphene oxide and silk fibroin composites," Energy, Elsevier, vol. 141(C), pages 1982-1988.
    16. Wang, Kai & Li, Liwei & Zhang, Tiezhu & Liu, Zaifei, 2014. "Nitrogen-doped graphene for supercapacitor with long-term electrochemical stability," Energy, Elsevier, vol. 70(C), pages 612-617.
    17. Huang, Ke-Jing & Wang, Lan & Zhang, Ji-Zong & Wang, Ling-Ling & Mo, Yan-Ping, 2014. "One-step preparation of layered molybdenum disulfide/multi-walled carbon nanotube composites for enhanced performance supercapacitor," Energy, Elsevier, vol. 67(C), pages 234-240.
    18. He, Yapeng & Wang, Xue & Zhang, Panpan & Huang, Hui & Li, Xiaobo & Shui, Yuan & Chen, Buming & Guo, Zhongcheng, 2019. "A versatile integrated rechargeable lead dioxide-polyaniline system with energy storage mechanism transformation," Energy, Elsevier, vol. 183(C), pages 358-367.
    19. Sieben, J.M. & Morallón, E. & Cazorla-Amorós, D., 2013. "Flexible ruthenium oxide-activated carbon cloth composites prepared by simple electrodeposition methods," Energy, Elsevier, vol. 58(C), pages 519-526.
    20. Pourjavadi, Ali & Doroudian, Mohadeseh & Ahadpour, Amirkhashayar & Pourbadiei, Behzad, 2018. "Preparation of flexible and free-standing graphene-based current collector via a new and facile self-assembly approach: Leading to a high performance porous graphene/polyaniline supercapacitor," Energy, Elsevier, vol. 152(C), pages 178-189.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:142:y:2018:i:c:p:608-616. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.