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High-performance α-MnO2 nanowire electrode for supercapacitors

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Listed:
  • Su, Xiaohui
  • Yu, Lin
  • Cheng, Gao
  • Zhang, Huanhua
  • Sun, Ming
  • Zhang, Xiaofei

Abstract

Nanowired α-MnO2 material supported on carbon fiber paper (α-MnO2/CFP) is synthesized using a facile hydrothermal method for supercapacitor electrode. The α-MnO2/CFP material is characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and BET for its composition, structure/morphology, and BET surface area. The electrochemical properties of the α-MnO2/CFP electrode are studied by cyclic voltammetry (CV), galvanostatic charge/discharge and electrochemical impedance spectroscopy (EIS) in 1M Na2SO4 solution. The porous α-MnO2/CFP material electrode shows a high specific capacitance of 251Fg−1 at the current density of 1Ag−1, and also exhibits a good rate capability and an excellent cycling stability. It is testified that even after 3000cycles, the capacitance retention of the porous α-MnO2/CFP material electrode can still maintain over 98.9% of the capacitance at the high current density of 4Ag−1, demonstrating its excellent cycling stability. The high electrochemical performance of the porous α-MnO2/CFP material nanowire electrode may be attributed to the 2×2 tunnel structure, high active surface area, and high porosity of the of α-MnO2 material.

Suggested Citation

  • Su, Xiaohui & Yu, Lin & Cheng, Gao & Zhang, Huanhua & Sun, Ming & Zhang, Xiaofei, 2015. "High-performance α-MnO2 nanowire electrode for supercapacitors," Applied Energy, Elsevier, vol. 153(C), pages 94-100.
    • Handle: RePEc:eee:appene:v:153:y:2015:i:c:p:94-100
    DOI: 10.1016/j.apenergy.2014.07.094
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    References listed on IDEAS

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    Cited by:

    1. Yuan, Chuanjun & Lin, Haibo & Lu, Haiyan & Xing, Endong & Zhang, Yusi & Xie, Bingyao, 2016. "Synthesis of hierarchically porous MnO2/rice husks derived carbon composite as high-performance electrode material for supercapacitors," Applied Energy, Elsevier, vol. 178(C), pages 260-268.
    2. Ramachandran, Rajendran & Saranya, Murugan & Velmurugan, Venugopal & Raghupathy, Bala P.C. & Jeong, Soon Kwan & Grace, Andrews Nirmala, 2015. "Effect of reducing agent on graphene synthesis and its influence on charge storage towards supercapacitor applications," Applied Energy, Elsevier, vol. 153(C), pages 22-31.
    3. Wang, Xue & Deng, Jinxing & Duan, Xiaojuan & Liu, Dong & Liu, Peng, 2015. "Fluorescent brightener CBS-X doped polypyrrole as smart electrode material for supercapacitors," Applied Energy, Elsevier, vol. 153(C), pages 70-77.
    4. Su, Y. & Zhitomirsky, I., 2015. "Asymmetric electrochemical supercapacitor, based on polypyrrole coated carbon nanotube electrodes," Applied Energy, Elsevier, vol. 153(C), pages 48-55.

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