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Ca-looping for postcombustion CO2 capture: A comparative analysis on the performances of dolomite and limestone

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  • Valverde, J.M.
  • Sanchez-Jimenez, P.E.
  • Perez-Maqueda, L.A.

Abstract

The low cost and wide availability of natural limestone (CaCO3) is at the basis of the industrial competitiveness of the Ca-looping (CaL) technology for postcombustion CO2 capture as already demonstrated by ∼1Mwt scale pilot projects. A major focus of studies oriented towards further improving the efficiency of the CaL technology is how to prevent the gradual loss of capture capacity of limestone derived CaO as the number of carbonation/calcination cycles is increased. Natural dolomite (MgCa(CO3)2) has been proposed as an alternative sorbent precursor to limestone. Yet, carbonation of MgO is not thermodynamically favorable at CaL conditions, which may hinder the capture performance of dolomite. In the work described in this paper we carried out a thermogravimetric analysis on the multicyclic capture performance of natural dolomite under realistic regeneration conditions necessarily implying high calcination temperature, high CO2 concentration and fast transitions between the carbonation and calcination stages. Our study demonstrates that the sorbent derived from dolomite has a greater capture capacity as compared to limestone. SEM analysis shows that MgO grains in the decomposed dolomite are resistant to sintering under severe calcination conditions and segregate from CaO acting as a thermally stable support which mitigates the multicyclic loss of CaO conversion. Moreover, full decomposition of dolomite is achieved at significantly lower calcination temperatures as compared to limestone, which would help improving further the industrial competitiveness of the technology.

Suggested Citation

  • Valverde, J.M. & Sanchez-Jimenez, P.E. & Perez-Maqueda, L.A., 2015. "Ca-looping for postcombustion CO2 capture: A comparative analysis on the performances of dolomite and limestone," Applied Energy, Elsevier, vol. 138(C), pages 202-215.
    • Handle: RePEc:eee:appene:v:138:y:2015:i:c:p:202-215
    DOI: 10.1016/j.apenergy.2014.10.087
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    1. Valverde, J.M. & Sanchez-Jimenez, P.E. & Perez-Maqueda, L.A., 2014. "Calcium-looping for post-combustion CO2 capture. On the adverse effect of sorbent regeneration under CO2," Applied Energy, Elsevier, vol. 126(C), pages 161-171.
    2. Valverde, J.M. & Sanchez-Jimenez, P.E. & Perez-Maqueda, L.A. & Quintanilla, M.A.S. & Perez-Vaquero, J., 2014. "Role of crystal structure on CO2 capture by limestone derived CaO subjected to carbonation/recarbonation/calcination cycles at Ca-looping conditions," Applied Energy, Elsevier, vol. 125(C), pages 264-275.
    3. Wang, Jinsheng & Manovic, Vasilije & Wu, Yinghai & Anthony, Edward J., 2010. "A study on the activity of CaO-based sorbents for capturing CO2 in clean energy processes," Applied Energy, Elsevier, vol. 87(4), pages 1453-1458, April.
    4. Sanchez-Jimenez, P.E. & Perez-Maqueda, L.A. & Valverde, J.M., 2014. "Nanosilica supported CaO: A regenerable and mechanically hard CO2 sorbent at Ca-looping conditions," Applied Energy, Elsevier, vol. 118(C), pages 92-99.
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    1. Ortiz, C. & Valverde, J.M. & Chacartegui, R. & Perez-Maqueda, L.A. & Giménez, P., 2019. "The Calcium-Looping (CaCO3/CaO) process for thermochemical energy storage in Concentrating Solar Power plants," Renewable and Sustainable Energy Reviews, Elsevier, vol. 113(C), pages 1-1.
    2. Harnpon Phungrassami & Phairat Usubharatana, 2021. "Environmental Problem Shifting Analysis of Pollution Control Units in a Coal-Fired Powerplant Based on Multiple Regression and LCA Methodology," Sustainability, MDPI, vol. 13(9), pages 1-17, May.
    3. Perejón, Antonio & Romeo, Luis M. & Lara, Yolanda & Lisbona, Pilar & Martínez, Ana & Valverde, Jose Manuel, 2016. "The Calcium-Looping technology for CO2 capture: On the important roles of energy integration and sorbent behavior," Applied Energy, Elsevier, vol. 162(C), pages 787-807.
    4. Sánchez Jiménez, Pedro E. & Perejón, Antonio & Benítez Guerrero, Mónica & Valverde, José M. & Ortiz, Carlos & Pérez Maqueda, Luis A., 2019. "High-performance and low-cost macroporous calcium oxide based materials for thermochemical energy storage in concentrated solar power plants," Applied Energy, Elsevier, vol. 235(C), pages 543-552.
    5. Kelly Atkinson & Robin Hughes & Arturo Macchi, 2023. "Application of the Calcium Looping Process for Thermochemical Storage of Variable Energy," Energies, MDPI, vol. 16(7), pages 1-19, April.
    6. Wang, Ke & Hu, Xiumeng & Zhao, Pengfei & Yin, Zeguang, 2016. "Natural dolomite modified with carbon coating for cyclic high-temperature CO2 capture," Applied Energy, Elsevier, vol. 165(C), pages 14-21.
    7. Ma, Xiaotong & Li, Yingjie & Shi, Lei & He, Zirui & Wang, Zeyan, 2016. "Fabrication and CO2 capture performance of magnesia-stabilized carbide slag by by-product of biodiesel during calcium looping process," Applied Energy, Elsevier, vol. 168(C), pages 85-95.
    8. Khosravi, Soheil & Hossainpour, Siamak & Farajollahi, Hossein & Abolzadeh, Nemat, 2022. "Integration of a coal fired power plant with calcium looping CO2 capture and concentrated solar power generation: Energy, exergy and economic analysis," Energy, Elsevier, vol. 240(C).
    9. Erans, María & Manovic, Vasilije & Anthony, Edward J., 2016. "Calcium looping sorbents for CO2 capture," Applied Energy, Elsevier, vol. 180(C), pages 722-742.
    10. Su, Chenglin & Duan, Lunbo & Donat, Felix & Anthony, Edward John, 2018. "From waste to high value utilization of spent bleaching clay in synthesizing high-performance calcium-based sorbent for CO2 capture," Applied Energy, Elsevier, vol. 210(C), pages 117-126.
    11. Han, Rui & Xing, Shuang & Wu, Xueqian & Pang, Caihong & Lu, Shuangchun & Su, Yun & Liu, Qingling & Song, Chunfeng & Gao, Jihui, 2022. "Relevant influence of alkali carbonate doping on the thermochemical energy storage of Ca-based natural minerals during CaO/CaCO3 cycles," Renewable Energy, Elsevier, vol. 181(C), pages 267-277.
    12. Ortiz, C. & Romano, M.C. & Valverde, J.M. & Binotti, M. & Chacartegui, R., 2018. "Process integration of Calcium-Looping thermochemical energy storage system in concentrating solar power plants," Energy, Elsevier, vol. 155(C), pages 535-551.
    13. Ortiz, C. & Chacartegui, R. & Valverde, J.M. & Becerra, J.A., 2016. "A new integration model of the calcium looping technology into coal fired power plants for CO2 capture," Applied Energy, Elsevier, vol. 169(C), pages 408-420.
    14. Larissa Fedunik-Hofman & Alicia Bayon & Scott W. Donne, 2019. "Kinetics of Solid-Gas Reactions and Their Application to Carbonate Looping Systems," Energies, MDPI, vol. 12(15), pages 1-35, August.
    15. Tiskatine, R. & Eddemani, A. & Gourdo, L. & Abnay, B. & Ihlal, A. & Aharoune, A. & Bouirden, L., 2016. "Experimental evaluation of thermo-mechanical performances of candidate rocks for use in high temperature thermal storage," Applied Energy, Elsevier, vol. 171(C), pages 243-255.

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    Keywords

    CO2 capture; Calcium looping; Limestone; Dolomite;
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