IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v168y2016icp534-543.html
   My bibliography  Save this article

Micro-Solid Oxide Fuel Cell: A multi-fuel approach for portable applications

Author

Listed:
  • Patil, Tarkeshwar C.
  • Duttagupta, Siddhartha P.

Abstract

The impact of oxygen ion transport at the electrolyte–electrode interface of a micro-solid oxide fuel cell using different fuels is investigated. Model validation is performed to verify the results versus the reported values. Furthermore, as the hydrogen-to-carbon ratio decreases, the diffusivity of the oxygen ion increases. This increase in diffusivity is observed because the number of hydrogen atoms available as the reacting species increases in fuels with lower hydrogen-to-carbon ratios. The oxygen ion conductivity and output power density decrease as the hydrogen-to-carbon ratio of the fuels decreases. The reason behind this impact is the formation of a gas-induced ion barrier at the electrode–electrolyte interface by the CO2 molecules formed during the reaction at the interface, thus blocking the flow of oxygen ions. As the oxygen ions become blocked, the output current contribution from the reaction also decreases and thereby affects the overall performance of the micro-solid oxide fuel cell. The experimental verification confirms this because of a significant decrease in the output power density. Furthermore, as per the application in portable devices, the appropriate choice of fuel can be chosen so that the micro-solid oxide fuel cell operates at the maximum power density.

Suggested Citation

  • Patil, Tarkeshwar C. & Duttagupta, Siddhartha P., 2016. "Micro-Solid Oxide Fuel Cell: A multi-fuel approach for portable applications," Applied Energy, Elsevier, vol. 168(C), pages 534-543.
    • Handle: RePEc:eee:appene:v:168:y:2016:i:c:p:534-543
    DOI: 10.1016/j.apenergy.2016.01.111
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S030626191630099X
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2016.01.111?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Zhu, Bin & Fan, Liangdong & Lund, Peter, 2013. "Breakthrough fuel cell technology using ceria-based multi-functional nanocomposites," Applied Energy, Elsevier, vol. 106(C), pages 163-175.
    2. Cinti, Giovanni & Desideri, Umberto, 2015. "SOFC fuelled with reformed urea," Applied Energy, Elsevier, vol. 154(C), pages 242-253.
    3. Andersson, Martin & Yuan, Jinliang & Sundén, Bengt, 2010. "Review on modeling development for multiscale chemical reactions coupled transport phenomena in solid oxide fuel cells," Applied Energy, Elsevier, vol. 87(5), pages 1461-1476, May.
    4. Navasa, Maria & Yuan, Jinliang & Sundén, Bengt, 2015. "Computational fluid dynamics approach for performance evaluation of a solid oxide electrolysis cell for hydrogen production," Applied Energy, Elsevier, vol. 137(C), pages 867-876.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Sharifzadeh, Mahdi & Meghdari, Mojtaba & Rashtchian, Davood, 2017. "Multi-objective design and operation of Solid Oxide Fuel Cell (SOFC) Triple Combined-cycle Power Generation systems: Integrating energy efficiency and operational safety," Applied Energy, Elsevier, vol. 185(P1), pages 345-361.
    2. Terracciano, Anthony Carmine & Vasu, Subith S. & Orlovskaya, Nina, 2016. "Design and development of a porous heterogeneous combustor for efficient heat production by combustion of liquid and gaseous fuels," Applied Energy, Elsevier, vol. 179(C), pages 228-236.
    3. Chen, Bin & Xu, Haoran & Tan, Peng & Zhang, Yuan & Xu, Xiaoming & Cai, Weizi & Chen, Meina & Ni, Meng, 2019. "Thermal modelling of ethanol-fuelled Solid Oxide Fuel Cells," Applied Energy, Elsevier, vol. 237(C), pages 476-486.
    4. Pavelka, Michal & Klika, Václav & Vágner, Petr & Maršík, František, 2015. "Generalization of exergy analysis," Applied Energy, Elsevier, vol. 137(C), pages 158-172.
    5. Sorce, A. & Greco, A. & Magistri, L. & Costamagna, P., 2014. "FDI oriented modeling of an experimental SOFC system, model validation and simulation of faulty states," Applied Energy, Elsevier, vol. 136(C), pages 894-908.
    6. Chen, Daifen & Zeng, Qice & Su, Shichuan & Bi, Wuxi & Ren, Zhiqiang, 2013. "Geometric optimization of a 10-cell modular planar solid oxide fuel cell stack manifold," Applied Energy, Elsevier, vol. 112(C), pages 1100-1107.
    7. He, Zhongjie & Birgersson, E. & Li, Hua, 2014. "Reduced non-isothermal model for the planar solid oxide fuel cell and stack," Energy, Elsevier, vol. 70(C), pages 478-492.
    8. Wang, Junye, 2015. "Theory and practice of flow field designs for fuel cell scaling-up: A critical review," Applied Energy, Elsevier, vol. 157(C), pages 640-663.
    9. Tong, Zi-Xiang & Li, Ming-Jia & He, Ya-Ling & Tan, Hou-Zhang, 2017. "Simulation of real time particle deposition and removal processes on tubes by coupled numerical method," Applied Energy, Elsevier, vol. 185(P2), pages 2181-2193.
    10. Tzelepis, Stefanos & Kavadias, Kosmas A. & Marnellos, George E. & Xydis, George, 2021. "A review study on proton exchange membrane fuel cell electrochemical performance focusing on anode and cathode catalyst layer modelling at macroscopic level," Renewable and Sustainable Energy Reviews, Elsevier, vol. 151(C).
    11. Wang, Baoxuan & Zhu, Jiang & Lin, Zijing, 2016. "A theoretical framework for multiphysics modeling of methane fueled solid oxide fuel cell and analysis of low steam methane reforming kinetics," Applied Energy, Elsevier, vol. 176(C), pages 1-11.
    12. Paola Costamagna & Simone Grosso & Rowland Travis & Loredana Magistri, 2015. "Integrated Planar Solid Oxide Fuel Cell: Steady-State Model of a Bundle and Validation through Single Tube Experimental Data," Energies, MDPI, vol. 8(11), pages 1-24, November.
    13. Komatsu, Y. & Brus, G. & Kimijima, S. & Szmyd, J.S., 2014. "The effect of overpotentials on the transient response of the 300W SOFC cell stack voltage," Applied Energy, Elsevier, vol. 115(C), pages 352-359.
    14. Razbani, Omid & Wærnhus, Ivar & Assadi, Mohsen, 2013. "Experimental investigation of temperature distribution over a planar solid oxide fuel cell," Applied Energy, Elsevier, vol. 105(C), pages 155-160.
    15. Chaoyu Liang & Chao Yang & Jiatang Wang & Peijian Lin & Xinke Li & Xuyang Wu & Jinliang Yuan, 2020. "Sintering Process and Effects on LST and LST-GDC Particles Simulated by Molecular Dynamics Modeling Method," Energies, MDPI, vol. 13(16), pages 1-18, August.
    16. Silva-Mosqueda, Dulce María & Elizalde-Blancas, Francisco & Pumiglia, Davide & Santoni, Francesca & Boigues-Muñoz, Carlos & McPhail, Stephen J., 2019. "Intermediate temperature solid oxide fuel cell under internal reforming: Critical operating conditions, associated problems and their impact on the performance," Applied Energy, Elsevier, vol. 235(C), pages 625-640.
    17. Li, Zheng & Zhang, Hao & Xu, Haoran & Xuan, Jin, 2021. "Advancing the multiscale understanding on solid oxide electrolysis cells via modelling approaches: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 141(C).
    18. Zhen Zhang & Chengzhi Guan & Leidong Xie & Jian-Qiang Wang, 2022. "Design and Analysis of a Novel Opposite Trapezoidal Flow Channel for Solid Oxide Electrolysis Cell Stack," Energies, MDPI, vol. 16(1), pages 1-11, December.
    19. Xing, Xuetao & Lin, Jin & Song, Yonghua & Hu, Qiang & Zhou, You & Mu, Shujun, 2018. "Optimization of hydrogen yield of a high-temperature electrolysis system with coordinated temperature and feed factors at various loading conditions: A model-based study," Applied Energy, Elsevier, vol. 232(C), pages 368-385.
    20. Rashid, Kashif & Dong, Sang Keun & Mehran, Muhammad Taqi & Lee, Dong Won, 2017. "Design and analysis of compact hotbox for solid oxide fuel cell based 1kW-class power generation system," Applied Energy, Elsevier, vol. 208(C), pages 620-636.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:168:y:2016:i:c:p:534-543. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.