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A comparative assessment of Power-to-Fuel production pathways

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  • Bargiacchi, Eleonora
  • Antonelli, Marco
  • Desideri, Umberto

Abstract

As the share of intermittent renewable power generation is increasing, energy storage is expected to play a key role in ensuring efficiency, resilience and stability of energy systems. Besides reducing surplus energy curtailments and addressing the issue of seasonal storage, the implementation of some Power-to-X technologies could be an effective supporting tool to decarbonization policies. This paper aims at quantifying Power-to-X process efficiencies and assessing under which conditions they could be carbon neutral during the conversion phase from electricity to a chemical storage, particularly a hydrogen carrier. For this purpose, four synthetic fuel production chains were modelled and simulated with the software Aspen Plus: methane synthesis by means of the Sabatier process, methanol synthesis by carbon dioxide hydrogenation, ammonia production with the Haber-Bosch process and urea synthesis with the Stamicarbon CO2 stripping process. The production pathways were compared in terms of energy and exergy efficiencies, net CO2 emissions and specific energy consumption. Emission intensity threshold values for these technologies to be carbon neutral were also estimated. Assuming that the feed hydrogen is produced by electrolysis, the impact of an upstram electrolyzer upon the aforementioned parameters was assessed and discussed. The further processing of the produced fuels (X-to-Power) is not included in the present work.

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  • Bargiacchi, Eleonora & Antonelli, Marco & Desideri, Umberto, 2019. "A comparative assessment of Power-to-Fuel production pathways," Energy, Elsevier, vol. 183(C), pages 1253-1265.
    • Handle: RePEc:eee:energy:v:183:y:2019:i:c:p:1253-1265
    DOI: 10.1016/j.energy.2019.06.149
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    3. Ramirez-Corredores, M.M. & Diaz, Luis A. & Gaffney, Anne M. & Zarzana, Christopher A., 2021. "Identification of opportunities for integrating chemical processes for carbon (dioxide) utilization to nuclear power plants," Renewable and Sustainable Energy Reviews, Elsevier, vol. 150(C).
    4. Piciu Gabriela-Cornelia, 2021. "Decarbonisation Of Economy In Romania," Annals - Economy Series, Constantin Brancusi University, Faculty of Economics, vol. 5, pages 98-104, October.
    5. Kim, Jeongdong & Qi, Meng & Park, Jinwoo & Moon, Il, 2023. "Revealing the impact of renewable uncertainty on grid-assisted power-to-X: A data-driven reliability-based design optimization approach," Applied Energy, Elsevier, vol. 339(C).
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    7. Pivetta, D. & Dall’Armi, C. & Sandrin, P. & Bogar, M. & Taccani, R., 2024. "The role of hydrogen as enabler of industrial port area decarbonization," Renewable and Sustainable Energy Reviews, Elsevier, vol. 189(PB).
    8. Sillman, Jani & Havukainen, Jouni & Alfasfos, Rami & Elyasi, Nashmin & Lilja, Miro & Ruuskanen, Vesa & Laasonen, Emma & Leppäkoski, Lauri & Uusitalo, Ville & Soukka, Risto, 2024. "Meta-analysis of climate impact reduction potential of hydrogen usage in 9 Power-to-X pathways," Applied Energy, Elsevier, vol. 359(C).
    9. Grubert, E. & Zacarias, M., 2022. "Paradigm shifts for environmental assessment of decarbonizing energy systems: Emerging dominance of embodied impacts and design-oriented decision support needs," Renewable and Sustainable Energy Reviews, Elsevier, vol. 159(C).
    10. Qi, Meng & Vo, Dat Nguyen & Yu, Haoshui & Shu, Chi-Min & Cui, Chengtian & Liu, Yi & Park, Jinwoo & Moon, Il, 2023. "Strategies for flexible operation of power-to-X processes coupled with renewables," Renewable and Sustainable Energy Reviews, Elsevier, vol. 179(C).
    11. Eleonora Bargiacchi & Nils Thonemann & Jutta Geldermann & Marco Antonelli & Umberto Desideri, 2020. "Life Cycle Assessment of Synthetic Natural Gas Production from Different CO 2 Sources: A Cradle-to-Gate Study," Energies, MDPI, vol. 13(17), pages 1-17, September.

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