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Paraffin/expanded vermiculite composite phase change material as aggregate for developing lightweight thermal energy storage cement-based composites

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  • Xu, Biwan
  • Ma, Hongyan
  • Lu, Zeyu
  • Li, Zongjin

Abstract

In this study, a new paraffin/expanded vermiculite composite phase change material (PCM) was tailor-made as aggregate for developing lightweight thermal energy storage cement-based composites (LW-TESCCs). Vermiculite calcined at 800°C for 1h (EVM-800) can be considered as the optimum paraffin supporting matrix candidate, as it has the best expanded microstructure and crystallization. The composite PCM was fabricated at a paraffin-to-EVM-800 weight ratio of 0.6:1.0 by the vacuum impregnation method. The results of scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FT-IR) show that the paraffin can be well vacuum drawn into the expanded interlayer spaces of EVM-800, and that the paraffin and EVM-800 are chemically inert. The differential scanning calorimetry (DSC) results reveal that the composite PCM has an onset melting temperature of 27.0±0.1°C and latent heat of 77.6±4.3J/g, and good thermal stability is clearly suggested by the thermogravimetric analysis (TGA) results. Moreover, the LW-TESCCs with bulk densities below 1500kg/m3 were further developed by incorporating the composite PCM as sand replacement. It is found that the LW-TESCCs have significantly improved thermal resistance performance and well-endowed thermal storage capabilities. Thus, it can be expected that the potential applications of the LW-TESCCs in building envelopes would significantly contribute to reducing indoor air temperature fluctuations and in saving energy.

Suggested Citation

  • Xu, Biwan & Ma, Hongyan & Lu, Zeyu & Li, Zongjin, 2015. "Paraffin/expanded vermiculite composite phase change material as aggregate for developing lightweight thermal energy storage cement-based composites," Applied Energy, Elsevier, vol. 160(C), pages 358-367.
    • Handle: RePEc:eee:appene:v:160:y:2015:i:c:p:358-367
    DOI: 10.1016/j.apenergy.2015.09.069
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    References listed on IDEAS

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    14. Li, Chuanchang & Wang, Mengfan & Xie, Baoshan & Ma, Huan & Chen, Jian, 2020. "Enhanced properties of diatomite-based composite phase change materials for thermal energy storage," Renewable Energy, Elsevier, vol. 147(P1), pages 265-274.
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    16. Lin, Yaxue & Zhu, Chuqiao & Alva, Guruprasad & Fang, Guiyin, 2018. "Palmitic acid/polyvinyl butyral/expanded graphite composites as form-stable phase change materials for solar thermal energy storage," Applied Energy, Elsevier, vol. 228(C), pages 1801-1809.
    17. Vasu, Anusuiah & Hagos, Ftwi Y. & Noor, M.M. & Mamat, R. & Azmi, W.H. & Abdullah, Abdul A. & Ibrahim, Thamir K., 2017. "Corrosion effect of phase change materials in solar thermal energy storage application," Renewable and Sustainable Energy Reviews, Elsevier, vol. 76(C), pages 19-33.
    18. Lv, Peizhao & Liu, Chenzhen & Rao, Zhonghao, 2016. "Experiment study on the thermal properties of paraffin/kaolin thermal energy storage form-stable phase change materials," Applied Energy, Elsevier, vol. 182(C), pages 475-487.
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    20. Zhao, Manxiang & Zhang, Xu & Kong, Xiangfei, 2020. "Preparation and characterization of a novel composite phase change material with double phase change points based on nanocapsules," Renewable Energy, Elsevier, vol. 147(P1), pages 374-383.

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