IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v147y2020ip1p374-383.html
   My bibliography  Save this article

Preparation and characterization of a novel composite phase change material with double phase change points based on nanocapsules

Author

Listed:
  • Zhao, Manxiang
  • Zhang, Xu
  • Kong, Xiangfei

Abstract

In this study, a kind of novel double phase change energy storage materials (DPCESM) based on two kinds of phase change nanocapsules and bentonite was reported. The nanocapsules (n-ODE@CLPS and n-ESE@CLPS) were synthesized with n-octadecane (n-ODE) and n-eicosane (n-ESE) as phase change material (PCM), respectively, crosslinked polystyrene (CLPS) as shell, and DNS-86 as polymerizable emulsifier via soap-free miniemulsion polymerization method. The morphology, thermal energy storage capacity, and structure of nanocapsules and DPCESM were characterized and analyzed, respectively. Besides, the effects of DNS-86 on the thermal storage performance of nanocapsules were investigated. The results showed that the encapsulation efficiency of nanocapsules was the highest along with the excellent chemical stability and heat storage capacity when the percentage of polymerizable emulsifier was 2 wt%. The average diameter of n-ODE@CLPS was 136 nm, and the latent heat of phase change and encapsulation efficiency were 140.39 J/g and 91.28%, respectively. Meanwhile, the average diameter of n-ESE@CLPS was 134 nm, the latent heat of phase change and encapsulation efficiency were 148.32 J/g and 91.77%, respectively. Besides, the melting points of DPCESM were 26.25 °C and 34.58 °C, and the heat storage capacity was 90.17 J/g. Moreover, because of the doping of bentonite, the thermal conductivity of DPCESM can reach to 0.45 W/(m·K), which is 104.5% and 150% larger than pure n-ODE and n-ESE, respectively. The DPCESM can be used to adjust the indoor temperature and would be widely used as a promising composite phase change material.

Suggested Citation

  • Zhao, Manxiang & Zhang, Xu & Kong, Xiangfei, 2020. "Preparation and characterization of a novel composite phase change material with double phase change points based on nanocapsules," Renewable Energy, Elsevier, vol. 147(P1), pages 374-383.
    • Handle: RePEc:eee:renene:v:147:y:2020:i:p1:p:374-383
    DOI: 10.1016/j.renene.2019.08.117
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148119313047
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2019.08.117?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Su, Weiguang & Darkwa, Jo & Kokogiannakis, Georgios, 2015. "Review of solid–liquid phase change materials and their encapsulation technologies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 48(C), pages 373-391.
    2. Giro-Paloma, Jessica & Oncins, Gerard & Barreneche, Camila & Martínez, Mònica & Fernández, A. Inés & Cabeza, Luisa F., 2013. "Physico-chemical and mechanical properties of microencapsulated phase change material," Applied Energy, Elsevier, vol. 109(C), pages 441-448.
    3. Li, Min, 2013. "A nano-graphite/paraffin phase change material with high thermal conductivity," Applied Energy, Elsevier, vol. 106(C), pages 25-30.
    4. Cai, Yibing & Ke, Huizhen & Dong, Ju & Wei, Qufu & Lin, Jiulong & Zhao, Yong & Song, Lei & Hu, Yuan & Huang, Fenglin & Gao, Weidong & Fong, Hao, 2011. "Effects of nano-SiO2 on morphology, thermal energy storage, thermal stability, and combustion properties of electrospun lauric acid/PET ultrafine composite fibers as form-stable phase change materials," Applied Energy, Elsevier, vol. 88(6), pages 2106-2112, June.
    5. Xu, Biwan & Ma, Hongyan & Lu, Zeyu & Li, Zongjin, 2015. "Paraffin/expanded vermiculite composite phase change material as aggregate for developing lightweight thermal energy storage cement-based composites," Applied Energy, Elsevier, vol. 160(C), pages 358-367.
    6. Yu, Shiyu & Wang, Xiaodong & Wu, Dezhen, 2014. "Microencapsulation of n-octadecane phase change material with calcium carbonate shell for enhancement of thermal conductivity and serving durability: Synthesis, microstructure, and performance evaluat," Applied Energy, Elsevier, vol. 114(C), pages 632-643.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Kong, Xiangfei & Jiang, Lina & Yuan, Ye & Qiao, Xu, 2022. "Experimental study on the performance of an active novel vertical partition thermal storage wallboard based on composite phase change material with porous silica and microencapsulation," Energy, Elsevier, vol. 239(PE).
    2. Wang, Lu & Kong, Xiangfei & Ren, Jianlin & Fan, Man & Li, Han, 2022. "Novel hybrid composite phase change materials with high thermal performance based on aluminium nitride and nanocapsules," Energy, Elsevier, vol. 238(PB).
    3. Yuan, Shunpan & Yan, Rui & Ren, Bibo & Du, Zongliang & Cheng, Xu & Du, Xiaosheng & Wang, Haibo, 2021. "Robust, double-layered phase-changing microcapsules with superior solar-thermal conversion capability and extremely high energy storage density for efficient solar energy storage," Renewable Energy, Elsevier, vol. 180(C), pages 725-733.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Fang, Yutang & Liu, Xin & Liang, Xianghui & Liu, Hong & Gao, Xuenong & Zhang, Zhengguo, 2014. "Ultrasonic synthesis and characterization of polystyrene/n-dotriacontane composite nanoencapsulated phase change material for thermal energy storage," Applied Energy, Elsevier, vol. 132(C), pages 551-556.
    2. Umair, Malik Muhammad & Zhang, Yuang & Iqbal, Kashif & Zhang, Shufen & Tang, Bingtao, 2019. "Novel strategies and supporting materials applied to shape-stabilize organic phase change materials for thermal energy storage–A review," Applied Energy, Elsevier, vol. 235(C), pages 846-873.
    3. Drissi, Sarra & Ling, Tung-Chai & Mo, Kim Hung & Eddhahak, Anissa, 2019. "A review of microencapsulated and composite phase change materials: Alteration of strength and thermal properties of cement-based materials," Renewable and Sustainable Energy Reviews, Elsevier, vol. 110(C), pages 467-484.
    4. Ahmed Hassan & Mohammad Shakeel Laghari & Yasir Rashid, 2016. "Micro-Encapsulated Phase Change Materials: A Review of Encapsulation, Safety and Thermal Characteristics," Sustainability, MDPI, vol. 8(10), pages 1-32, October.
    5. Lashgari, Somayeh & Arabi, Hassan & Mahdavian, Ali Reza & Ambrogi, Veronica, 2017. "Thermal and morphological studies on novel PCM microcapsules containing n-hexadecane as the core in a flexible shell," Applied Energy, Elsevier, vol. 190(C), pages 612-622.
    6. Mishra, Amit Kumar & Lahiri, B.B. & Philip, John, 2020. "Carbon black nano particle loaded lauric acid-based form-stable phase change material with enhanced thermal conductivity and photo-thermal conversion for thermal energy storage," Energy, Elsevier, vol. 191(C).
    7. Wang, Tingyu & Wang, Shuangfeng & Luo, Ruilian & Zhu, Chunyu & Akiyama, Tomohiro & Zhang, Zhengguo, 2016. "Microencapsulation of phase change materials with binary cores and calcium carbonate shell for thermal energy storage," Applied Energy, Elsevier, vol. 171(C), pages 113-119.
    8. Golestaneh, S.I. & Mosallanejad, A. & Karimi, G. & Khorram, M. & Khashi, M., 2016. "Fabrication and characterization of phase change material composite fibers with wide phase-transition temperature range by co-electrospinning method," Applied Energy, Elsevier, vol. 182(C), pages 409-417.
    9. Xiong, Teng & Shah, Kwok Wei & Kua, Harn Wei, 2021. "Thermal performance enhancement of cementitious composite containing polystyrene/n-octadecane microcapsules: An experimental and numerical study," Renewable Energy, Elsevier, vol. 169(C), pages 335-357.
    10. Lin, Yaxue & Jia, Yuting & Alva, Guruprasad & Fang, Guiyin, 2018. "Review on thermal conductivity enhancement, thermal properties and applications of phase change materials in thermal energy storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 2730-2742.
    11. Memon, Shazim Ali & Cui, H.Z. & Zhang, Hang & Xing, Feng, 2015. "Utilization of macro encapsulated phase change materials for the development of thermal energy storage and structural lightweight aggregate concrete," Applied Energy, Elsevier, vol. 139(C), pages 43-55.
    12. Amaral, C. & Vicente, R. & Marques, P.A.A.P. & Barros-Timmons, A., 2017. "Phase change materials and carbon nanostructures for thermal energy storage: A literature review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1212-1228.
    13. Zhang, Xiaoyu & Wang, Xiaodong & Wu, Dezhen, 2016. "Design and synthesis of multifunctional microencapsulated phase change materials with silver/silica double-layered shell for thermal energy storage, electrical conduction and antimicrobial effectivene," Energy, Elsevier, vol. 111(C), pages 498-512.
    14. Sarı, Ahmet & Alkan, Cemil & Bilgin, Cahit, 2014. "Micro/nano encapsulation of some paraffin eutectic mixtures with poly(methyl methacrylate) shell: Preparation, characterization and latent heat thermal energy storage properties," Applied Energy, Elsevier, vol. 136(C), pages 217-227.
    15. Chen, Renjie & Yao, Ruimin & Xia, Wei & Zou, Ruqiang, 2015. "Electro/photo to heat conversion system based on polyurethane embedded graphite foam," Applied Energy, Elsevier, vol. 152(C), pages 183-188.
    16. Qiu, Lin & Ouyang, Yuxin & Feng, Yanhui & Zhang, Xinxin, 2019. "Review on micro/nano phase change materials for solar thermal applications," Renewable Energy, Elsevier, vol. 140(C), pages 513-538.
    17. Kylili, Angeliki & Fokaides, Paris A. & Christou, Petros & Kalogirou, Soteris A., 2014. "Infrared thermography (IRT) applications for building diagnostics: A review," Applied Energy, Elsevier, vol. 134(C), pages 531-549.
    18. Alva, Guruprasad & Huang, Xiang & Liu, Lingkun & Fang, Guiyin, 2017. "Synthesis and characterization of microencapsulated myristic acid–palmitic acid eutectic mixture as phase change material for thermal energy storage," Applied Energy, Elsevier, vol. 203(C), pages 677-685.
    19. Jiang, Fuyun & Wang, Xiaodong & Wu, Dezhen, 2016. "Magnetic microencapsulated phase change materials with an organo-silica shell: Design, synthesis and application for electromagnetic shielding and thermal regulating polyimide films," Energy, Elsevier, vol. 98(C), pages 225-239.
    20. Xu, Biwan & Ma, Hongyan & Lu, Zeyu & Li, Zongjin, 2015. "Paraffin/expanded vermiculite composite phase change material as aggregate for developing lightweight thermal energy storage cement-based composites," Applied Energy, Elsevier, vol. 160(C), pages 358-367.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:147:y:2020:i:p1:p:374-383. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.