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Biodiesel production from palm oil over monolithic KF/γ-Al2O3/honeycomb ceramic catalyst

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  • Gao, Lijing
  • Wang, Songcheng
  • Xu, Wei
  • Xiao, Guomin

Abstract

During transesterification process in the fixed-bed reactor, traditional heterogeneous catalyst cannot stand the high pressure drop and would easily breaks at the reactor bottom thus blocking the outlets. KF/γ-Al2O3/honeycomb ceramic (HC) monolithic catalyst which was prepared in this research can be utilized because of its thermal and mechanical stability. γ-Al2O3 was deposited on the inert HC surface as a second carrier and KF acted as an active component. Loading ratio and loading intensity were both examined in order to select for catalyst with best catalytic performance. Optima reaction condition in the fixed-bed reactor was studied by investigating the effect of residence time, methanol/oil molar ratio and reaction temperature on oil conversion. Experiment results indicated that when the residence time was 33min, the methanol/oil molar ratio was 18:1, the reaction temperature was 140°C and with saturated vapor pressure, oil conversion could exceed 96%. X-ray diffraction (XRD) and scanning electron microscope (SEM) indicated that the KF/γ-Al2O3/HC monolithic catalyst shared the same alkaline catalytic centers identical to KF/γ-Al2O3.

Suggested Citation

  • Gao, Lijing & Wang, Songcheng & Xu, Wei & Xiao, Guomin, 2015. "Biodiesel production from palm oil over monolithic KF/γ-Al2O3/honeycomb ceramic catalyst," Applied Energy, Elsevier, vol. 146(C), pages 196-201.
    • Handle: RePEc:eee:appene:v:146:y:2015:i:c:p:196-201
    DOI: 10.1016/j.apenergy.2015.02.068
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    References listed on IDEAS

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    1. Christopher, Lew P. & Hemanathan Kumar, & Zambare, Vasudeo P., 2014. "Enzymatic biodiesel: Challenges and opportunities," Applied Energy, Elsevier, vol. 119(C), pages 497-520.
    2. Ajanovic, Amela, 2013. "Renewable fuels – A comparative assessment from economic, energetic and ecological point-of-view up to 2050 in EU-countries," Renewable Energy, Elsevier, vol. 60(C), pages 733-738.
    3. Leung, Dennis Y.C. & Wu, Xuan & Leung, M.K.H., 2010. "A review on biodiesel production using catalyzed transesterification," Applied Energy, Elsevier, vol. 87(4), pages 1083-1095, April.
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    1. Gupta, Anilkumar R. & Rathod, Virendra K., 2018. "Calcium diglyceroxide catalyzed biodiesel production from waste cooking oil in the presence of microwave: Optimization and kinetic studies," Renewable Energy, Elsevier, vol. 121(C), pages 757-767.
    2. Guan, Qingqing & Shang, Hua & Liu, Jing & Gu, Junjie & Li, Bin & Miao, Rongrong & Chen, Qiuling & Ning, Ping, 2016. "Biodiesel from transesterification at low temperature by AlCl3 catalysis in ethanol and carbon dioxide as cosolvent: Process, mechanism and application," Applied Energy, Elsevier, vol. 164(C), pages 380-386.
    3. Essamlali, Younes & Amadine, Othmane & Fihri, Aziz & Zahouily, Mohamed, 2019. "Sodium modified fluorapatite as a sustainable solid bi-functional catalyst for biodiesel production from rapeseed oil," Renewable Energy, Elsevier, vol. 133(C), pages 1295-1307.
    4. Tran, Dang-Thuan & Chang, Jo-Shu & Lee, Duu-Jong, 2017. "Recent insights into continuous-flow biodiesel production via catalytic and non-catalytic transesterification processes," Applied Energy, Elsevier, vol. 185(P1), pages 376-409.
    5. Munir, Mamoona & Ahmad, Mushtaq & Saeed, Muhammad & Waseem, Amir & Rehan, Mohammad & Nizami, Abdul-Sattar & Zafar, Muhammad & Arshad, Muhammad & Sultana, Shazia, 2019. "Sustainable production of bioenergy from novel non-edible seed oil (Prunus cerasoides) using bimetallic impregnated montmorillonite clay catalyst," Renewable and Sustainable Energy Reviews, Elsevier, vol. 109(C), pages 321-332.
    6. Mohamed, Mohamed Mokhatr & Bayoumy, W.A. & El-Faramawy, Hossam & El-Dogdog, Wagdy & Mohamed, Ashraf A., 2020. "A novel α-Fe2O3/AlOOH(γ-Al2O3) nanocatalyst for efficient biodiesel production from waste oil: Kinetic and thermal studies," Renewable Energy, Elsevier, vol. 160(C), pages 450-464.

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