IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v16y2023i6p2883-d1102786.html
   My bibliography  Save this article

Aspects Regarding the Modelling and Optimization of the Transesterification Process through Temperature Control of the Chemical Reactor

Author

Listed:
  • Ruxandra-Cristina Stanescu

    (Department of Automotive and Transport Engineering, Transilvania University of Brasov, 500036 Brasov, Romania)

  • Cristian-Ioan Leahu

    (Department of Automotive and Transport Engineering, Transilvania University of Brasov, 500036 Brasov, Romania)

  • Adrian Soica

    (Department of Automotive and Transport Engineering, Transilvania University of Brasov, 500036 Brasov, Romania)

Abstract

Currently, biofuels represent a solution for the European Union in the transportation sector in order to reduce the greenhouse gas (GHG) emissions and the dependency of fossil fuels. Biodiesel from vegetable oils is a solution for countries with low GDP per capita to strengthen the internal agriculture, provide jobs, and reduce the use of fossil fuels. In this study, we model and simulate a temperature regulator designed for the biodiesel transesterification process in a discontinuous batch reactor, using methanol and a homogenous basic catalyst. The simulation was based on the kinetical model of the transesterification reaction and the mathematical model of the reactor. We considered molar ratios of alcohol/oil of 6:1 and 9:1, respectively, to shift the reaction equilibrium towards the production of fatty acid methyl esters. In the design of the simulation, the methanol boiling point was considered a restriction, therefore, temperatures below 65 °C were imposed. The results demonstrate that the increase in temperature results in a decrease in the reaction time and a higher yield, especially for the 6:1 molar ratio reaction, and that the optimum temperature for the batch reactor is of 60 °C. Automatic control improves the performance and costs of production.

Suggested Citation

  • Ruxandra-Cristina Stanescu & Cristian-Ioan Leahu & Adrian Soica, 2023. "Aspects Regarding the Modelling and Optimization of the Transesterification Process through Temperature Control of the Chemical Reactor," Energies, MDPI, vol. 16(6), pages 1-17, March.
    • Handle: RePEc:gam:jeners:v:16:y:2023:i:6:p:2883-:d:1102786
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/16/6/2883/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/16/6/2883/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Małgorzata Hawrot-Paw & Patryk Ratomski & Adam Koniuszy & Wojciech Golimowski & Mirosława Teleszko & Anna Grygier, 2021. "Fatty Acid Profile of Microalgal Oils as a Criterion for Selection of the Best Feedstock for Biodiesel Production," Energies, MDPI, vol. 14(21), pages 1-14, November.
    2. Leung, Dennis Y.C. & Wu, Xuan & Leung, M.K.H., 2010. "A review on biodiesel production using catalyzed transesterification," Applied Energy, Elsevier, vol. 87(4), pages 1083-1095, April.
    3. Łukasz Muślewski & Marietta Markiewicz & Michał Pająk & Tomasz Kałaczyński & Davor Kolar, 2021. "Analysis of the Use of Fatty Acid Methyl Esters as an Additive to Diesel Fuel for Internal Combustion Engines," Energies, MDPI, vol. 14(21), pages 1-17, October.
    4. Emilia Neag & Zamfira Stupar & S. Andrada Maicaneanu & Cecilia Roman, 2023. "Advances in Biodiesel Production from Microalgae," Energies, MDPI, vol. 16(3), pages 1-18, January.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Mario C. Maya-Rodriguez & Ignacio Carvajal-Mariscal & Raúl López-Muñoz & Mario A. Lopez-Pacheco & René Tolentino-Eslava, 2023. "Temperature Control of a Chemical Reactor Based on Neuro-Fuzzy Tuned with a Metaheuristic Technique to Improve Biodiesel Production," Energies, MDPI, vol. 16(17), pages 1-17, August.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Bateni, Hamed & Karimi, Keikhosro & Zamani, Akram & Benakashani, Fatemeh, 2014. "Castor plant for biodiesel, biogas, and ethanol production with a biorefinery processing perspective," Applied Energy, Elsevier, vol. 136(C), pages 14-22.
    2. Wu, Hong & Li, Yuanyuan & Chen, Lei & Zong, Minhua, 2011. "Production of microbial oil with high oleic acid content by Trichosporon capitatum," Applied Energy, Elsevier, vol. 88(1), pages 138-142, January.
    3. Atadashi, I.M. & Aroua, M.K. & Abdul Aziz, A.R. & Sulaiman, N.M.N., 2011. "Membrane biodiesel production and refining technology: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(9), pages 5051-5062.
    4. Sánchez-Arreola, Eugenio & Martin-Torres, Gerardo & Lozada-Ramírez, José D. & Hernández, Luis R. & Bandala-González, Erick R. & Bach, Horacio, 2015. "Biodiesel production and de-oiled seed cake nutritional values of a Mexican edible Jatropha curcas," Renewable Energy, Elsevier, vol. 76(C), pages 143-147.
    5. Paulina Mitan-Zalewska & Oleh Klyus & Maciej Kozak, 2023. "Effective Parameters of a Compression-Ignition Engine Powered by a Mixture Consisting of Ethyl-Tetra-Butyl Ether and Diesel Fuel," Energies, MDPI, vol. 16(13), pages 1-14, July.
    6. Shunli Feng & Yihan Guo & Yulu Ran & Qingzhuoma Yang & Xiyue Cao & Huahao Yang & Yu Cao & Qingrui Xu & Dairong Qiao & Hui Xu & Yi Cao, 2023. "Production of Microbial Lipids by Saitozyma podzolica Zwy2-3 Using Corn Straw Hydrolysate, the Analysis of Lipid Composition, and the Prediction of Biodiesel Properties," Energies, MDPI, vol. 16(18), pages 1-22, September.
    7. Babatunde Oladipo & Tunde V Ojumu & Lekan M Latinwo & Eriola Betiku, 2020. "Pawpaw ( Carica papaya ) Peel Waste as a Novel Green Heterogeneous Catalyst for Moringa Oil Methyl Esters Synthesis: Process Optimization and Kinetic Study," Energies, MDPI, vol. 13(21), pages 1-25, November.
    8. Talebian-Kiakalaieh, Amin & Amin, Nor Aishah Saidina & Mazaheri, Hossein, 2013. "A review on novel processes of biodiesel production from waste cooking oil," Applied Energy, Elsevier, vol. 104(C), pages 683-710.
    9. Rawat, Devendra S. & Joshi, Girdhar & Lamba, Bhawna Y. & Tiwari, Avanish K. & Kumar, Pankaj, 2015. "The effect of binary antioxidant proportions on antioxidant synergy and oxidation stability of Jatropha and Karanja biodiesels," Energy, Elsevier, vol. 84(C), pages 643-655.
    10. Zhang, X.L. & Yan, S. & Tyagi, R.D. & Surampalli, R.Y., 2013. "Biodiesel production from heterotrophic microalgae through transesterification and nanotechnology application in the production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 26(C), pages 216-223.
    11. Chattopadhyay, Soham & Karemore, Ankush & Das, Sancharini & Deysarkar, Asoke & Sen, Ramkrishna, 2011. "Biocatalytic production of biodiesel from cottonseed oil: Standardization of process parameters and comparison of fuel characteristics," Applied Energy, Elsevier, vol. 88(4), pages 1251-1256, April.
    12. Sojung Kim & Junyoung Seo & Sumin Kim, 2024. "Machine Learning Technologies in the Supply Chain Management Research of Biodiesel: A Review," Energies, MDPI, vol. 17(6), pages 1-15, March.
    13. Ramachandran, K. & Suganya, T. & Nagendra Gandhi, N. & Renganathan, S., 2013. "Recent developments for biodiesel production by ultrasonic assist transesterification using different heterogeneous catalyst: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 22(C), pages 410-418.
    14. Katagi, Kariyappa S. & Munnolli, Ravindra S. & Hosamani, Kallappa M., 2011. "Unique occurrence of unusual fatty acid in the seed oil of Aegle marmelos Corre: Screening the rich source of seed oil for bio-energy production," Applied Energy, Elsevier, vol. 88(5), pages 1797-1802, May.
    15. Lech Nowicki & Dorota Siuta & Maciej Markowski, 2020. "Pyrolysis of Rapeseed Oil Press Cake and Steam Gasification of Solid Residues," Energies, MDPI, vol. 13(17), pages 1-12, August.
    16. Dawodu, Folasegun A. & Ayodele, Olubunmi & Xin, Jiayu & Zhang, Suojiang & Yan, Dongxia, 2014. "Effective conversion of non-edible oil with high free fatty acid into biodiesel by sulphonated carbon catalyst," Applied Energy, Elsevier, vol. 114(C), pages 819-826.
    17. Lian, Shuang & Li, Huijuan & Tang, Jinqiang & Tong, Dongmei & Hu, Changwei, 2012. "Integration of extraction and transesterification of lipid from jatropha seeds for the production of biodiesel," Applied Energy, Elsevier, vol. 98(C), pages 540-547.
    18. Lin, Lin & Cunshan, Zhou & Vittayapadung, Saritporn & Xiangqian, Shen & Mingdong, Dong, 2011. "Opportunities and challenges for biodiesel fuel," Applied Energy, Elsevier, vol. 88(4), pages 1020-1031, April.
    19. Blanco-Marigorta, A.M. & Suárez-Medina, J. & Vera-Castellano, A., 2013. "Exergetic analysis of a biodiesel production process from Jatropha curcas," Applied Energy, Elsevier, vol. 101(C), pages 218-225.
    20. Verma, Puneet & Sharma, M.P., 2016. "Review of process parameters for biodiesel production from different feedstocks," Renewable and Sustainable Energy Reviews, Elsevier, vol. 62(C), pages 1063-1071.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:16:y:2023:i:6:p:2883-:d:1102786. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.