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Sustainable production of bioenergy from novel non-edible seed oil (Prunus cerasoides) using bimetallic impregnated montmorillonite clay catalyst

Author

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  • Munir, Mamoona
  • Ahmad, Mushtaq
  • Saeed, Muhammad
  • Waseem, Amir
  • Rehan, Mohammad
  • Nizami, Abdul-Sattar
  • Zafar, Muhammad
  • Arshad, Muhammad
  • Sultana, Shazia

Abstract

The current study examines the efficiency of double metals (Cd and Mn) impregnated montmorillonite clay (Cd-Mn-Mmt) catalyst for the cleaner synthesis of biodiesel from novel non-edible seed oil of Prunus Cerasoides D. Don. (seed oil content 54.5%, and FFA content 0.45 mg KOH/g). X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Energy Dispersive X-Ray (EDX) and Fourier Transform Infrared Radiation Spectroscopy (FTIR) were used for characterizing the newly synthesized catalyst. The highest (85%) fatty acid methyl ester yield (FAME) of Prunus Cerasoides D. Don. biodiesel was obtained at optimized transesterification reaction conditions; 5 h of reaction time at 120 °C, 12:1 M ratio of methanol to oil and 4% catalyst loading. Synthesized biodiesel was further characterized via FTIR, Gas Chromatography/Mass spectroscopy (GC/MS), and Nuclear magnetic resonance (NMR (1H, 13C)). Additionally, the determined fuel properties, such as density (0.8612 kg/L), kinematic viscosity (4.11 mm2/s), flash point (73 °C), cloud point (−9 °C) and pour point (−10 °C), of synthesized biodiesel, agreed with International Standards of China GB/T 20828 (2007), American (ASTM-951, 6751) and European Union (EU-14214). Pseudo-first-order kinetics fitted well with the experimental data (R2 = 0.9172). The study findings recommended that the modified montmorillonite clay catalyst is a cleaner, cheaper, and easy to use along with high stability and catalytic performance in the transesterification process.

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  • Munir, Mamoona & Ahmad, Mushtaq & Saeed, Muhammad & Waseem, Amir & Rehan, Mohammad & Nizami, Abdul-Sattar & Zafar, Muhammad & Arshad, Muhammad & Sultana, Shazia, 2019. "Sustainable production of bioenergy from novel non-edible seed oil (Prunus cerasoides) using bimetallic impregnated montmorillonite clay catalyst," Renewable and Sustainable Energy Reviews, Elsevier, vol. 109(C), pages 321-332.
    • Handle: RePEc:eee:rensus:v:109:y:2019:i:c:p:321-332
    DOI: 10.1016/j.rser.2019.04.029
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    2. Long, Feng & Liu, Weiguo & Jiang, Xia & Zhai, Qiaolong & Cao, Xincheng & Jiang, Jianchun & Xu, Junming, 2021. "State-of-the-art technologies for biofuel production from triglycerides: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 148(C).
    3. Maria Ameen & Mushtaq Ahmad & Muhammad Zafar & Mamoona Munir & Muhammad Mujtaba Mujtaba & Shazia Sultana & Rozina . & Samah Elsayed El-Khatib & Manzoore Elahi M. Soudagar & M. A. Kalam, 2022. "Prospects of Catalysis for Process Sustainability of Eco-Green Biodiesel Synthesis via Transesterification: A State-Of-The-Art Review," Sustainability, MDPI, vol. 14(12), pages 1-38, June.
    4. Munir, Mamoona & Ahmad, Mushtaq & Saeed, Muhammad & Waseem, Amir & Nizami, Abdul-Sattar & Sultana, Shazia & Zafar, Muhammad & Rehan, Mohammad & Srinivasan, Gokul Raghavendra & Ali, Arshid Mahmood & Al, 2021. "Biodiesel production from novel non-edible caper (Capparis spinosa L.) seeds oil employing Cu–Ni doped ZrO2 catalyst," Renewable and Sustainable Energy Reviews, Elsevier, vol. 138(C).
    5. Munazza Jabeen & Mamoona Munir & Muhammad Mujtaba Abbas & Mushtaq Ahmad & Amir Waseem & Muhammad Saeed & Md Abul Kalam & Muhammad Zafar & Shazia Sultana & Abdullah Mohamed & Bisha Chaudhry, 2022. "Sustainable Production of Biodiesel from Novel and Non-Edible Ailanthus altissima (Mill.) Seed Oil from Green and Recyclable Potassium Hydroxide Activated Ailanthus Cake and Cadmium Sulfide Catalyst," Sustainability, MDPI, vol. 14(17), pages 1-12, September.
    6. Maryam Tanveer Akhtar & Mushtaq Ahmad & Maliha Asma & Mamoona Munir & Muhammad Zafar & Shazia Sultana & M. A. Mujtaba & Abdullah Mohamed & Md Abul Kalam, 2022. "Efficient Production of Wild and Non-Edible Brassica juncea (L.) Czern. Seed Oil into High-Quality Biodiesel via Novel, Green and Recyclable NiSO 4 Nano-Catalyst," Sustainability, MDPI, vol. 14(16), pages 1-26, August.

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