IDEAS home Printed from https://ideas.repec.org/a/eee/rensus/v133y2020ics136403212030647x.html
   My bibliography  Save this article

Progress in the solvent depolymerization of lignin

Author

Listed:
  • Patil, Vivek
  • Adhikari, Sushil
  • Cross, Phillip
  • Jahromi, Hossein

Abstract

Solvent liquefaction of lignin is a simultaneous depolymerization and hydrodeoxygenation process used to generate monomer products for fuel and specialty chemical applications. Lignin source, its isolation technique, and the process conditions play essential roles in overall lignin conversion and product distribution. This paper reviews major structural changes that occur during Kraft, organosolv, soda, and other novel lignin extraction processes and how these structural changes affect the solvent liquefaction performances. Reaction conditions, including temperature, residence time, solvent characteristics, and catalyst, are reviewed. Finally, pathways for getting commercially valuable chemicals from lignin is explored. The role of non-water solvents in achieving high-value products from lignin depolymerization is also discussed. The structure of lignin was found to be more critical than reaction conditions in determining the product yields, and future research should have more emphasis on this aspect. Overall, high temperature and longer residence time were found to be useful for depolymerization under certain conditions, such as the presence of homogeneous catalysts, condensed lignin structure, and water as a solvent.

Suggested Citation

  • Patil, Vivek & Adhikari, Sushil & Cross, Phillip & Jahromi, Hossein, 2020. "Progress in the solvent depolymerization of lignin," Renewable and Sustainable Energy Reviews, Elsevier, vol. 133(C).
    • Handle: RePEc:eee:rensus:v:133:y:2020:i:c:s136403212030647x
    DOI: 10.1016/j.rser.2020.110359
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S136403212030647X
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.rser.2020.110359?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Kang, Shimin & Li, Xianglan & Fan, Juan & Chang, Jie, 2013. "Hydrothermal conversion of lignin: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 27(C), pages 546-558.
    2. Long, Jinxing & Xu, Ying & Wang, Tiejun & Yuan, Zhengqiu & Shu, Riyang & Zhang, Qi & Ma, Longlong, 2015. "Efficient base-catalyzed decomposition and in situ hydrogenolysis process for lignin depolymerization and char elimination," Applied Energy, Elsevier, vol. 141(C), pages 70-79.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Radhakrishnan, Rokesh & Patra, Pradipta & Das, Manali & Ghosh, Amit, 2021. "Recent advancements in the ionic liquid mediated lignin valorization for the production of renewable materials and value-added chemicals," Renewable and Sustainable Energy Reviews, Elsevier, vol. 149(C).
    2. Kong, Xiangchen & Liu, Chao & Wang, Xing & Fan, Yuyang & Xu, Weicong & Xiao, Rui, 2022. "Production of oxygen-containing fuels via supercritical methanol hydrodeoxygenation of lignin bio-oil over Cu/CuZnAlOx catalyst," Applied Energy, Elsevier, vol. 316(C).
    3. Charles A. Mullen & Candice Ellison & Yaseen Elkasabi, 2023. "Pyrolytic Conversion of Cellulosic Pulps from “Lignin-First” Biomass Fractionation," Energies, MDPI, vol. 16(7), pages 1-13, April.
    4. Su, Ying & Guo, Bingfeng & Hornung, Ursel & Dahmen, Nicolaus, 2022. "FeCl3-supported solvothermal liquefaction of Miscanthus in methanol," Energy, Elsevier, vol. 258(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Ha, Jeong-Myeong & Hwang, Kyung-Ran & Kim, Young-Min & Jae, Jungho & Kim, Kwang Ho & Lee, Hyung Won & Kim, Jae-Young & Park, Young-Kwon, 2019. "Recent progress in the thermal and catalytic conversion of lignin," Renewable and Sustainable Energy Reviews, Elsevier, vol. 111(C), pages 422-441.
    2. Matteo Borella & Alessandro A. Casazza & Gabriella Garbarino & Paola Riani & Guido Busca, 2022. "A Study of the Pyrolysis Products of Kraft Lignin," Energies, MDPI, vol. 15(3), pages 1-15, January.
    3. Garlapati, Vijay Kumar & Chandel, Anuj K. & Kumar, S.P. Jeevan & Sharma, Swati & Sevda, Surajbhan & Ingle, Avinash P. & Pant, Deepak, 2020. "Circular economy aspects of lignin: Towards a lignocellulose biorefinery," Renewable and Sustainable Energy Reviews, Elsevier, vol. 130(C).
    4. Scherzinger, Marvin & Kaltschmitt, Martin, 2021. "Thermal pre-treatment options to enhance anaerobic digestibility – A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 137(C).
    5. Wei, Rufei & Feng, Shanghuan & Long, Hongming & Li, Jiaxin & Yuan, Zhongshun & Cang, Daqiang & Xu, Chunbao (Charles), 2017. "Coupled biomass (lignin) gasification and iron ore reduction: A novel approach for biomass conversion and application," Energy, Elsevier, vol. 140(P1), pages 406-414.
    6. Dessbesell, Luana & Paleologou, Michael & Leitch, Mathew & Pulkki, Reino & Xu, Chunbao (Charles), 2020. "Global lignin supply overview and kraft lignin potential as an alternative for petroleum-based polymers," Renewable and Sustainable Energy Reviews, Elsevier, vol. 123(C).
    7. Shen, Yafei & Yu, Shili & Ge, Shun & Chen, Xingming & Ge, Xinlei & Chen, Mindong, 2017. "Hydrothermal carbonization of medical wastes and lignocellulosic biomass for solid fuel production from lab-scale to pilot-scale," Energy, Elsevier, vol. 118(C), pages 312-323.
    8. Lai, Fa-ying & Chang, Yan-chao & Huang, Hua-jun & Wu, Guo-qiang & Xiong, Jiang-bo & Pan, Zi-qian & Zhou, Chun-fei, 2018. "Liquefaction of sewage sludge in ethanol-water mixed solvents for bio-oil and biochar products," Energy, Elsevier, vol. 148(C), pages 629-641.
    9. Bai, Jing & Li, Lefei & Chen, Zhiyong & Chang, Chun & Pang, Shusheng & Li, Pan, 2023. "Study on the optimization of hydrothermal liquefaction performance of tobacco stem and the high value utilization of catalytic products," Energy, Elsevier, vol. 281(C).
    10. Ankit Mathanker & Snehlata Das & Deepak Pudasainee & Monir Khan & Amit Kumar & Rajender Gupta, 2021. "A Review of Hydrothermal Liquefaction of Biomass for Biofuels Production with a Special Focus on the Effect of Process Parameters, Co-Solvents, and Extraction Solvents," Energies, MDPI, vol. 14(16), pages 1-60, August.
    11. Cybulska, Iwona & Brudecki, Grzegorz P. & Zembrzuska, Joanna & Schmidt, Jens Ejbye & Lopez, Celia Garcia-Banos & Thomsen, Mette Hedegaard, 2017. "Organosolv delignification of agricultural residues (date palm fronds, Phoenix dactylifera L.) of the United Arab Emirates," Applied Energy, Elsevier, vol. 185(P2), pages 1040-1050.
    12. Zhuang, Xiuzheng & Liu, Jianguo & Zhang, Qi & Wang, Chenguang & Zhan, Hao & Ma, Longlong, 2022. "A review on the utilization of industrial biowaste via hydrothermal carbonization," Renewable and Sustainable Energy Reviews, Elsevier, vol. 154(C).
    13. Anders Ahlbom & Marco Maschietti & Rudi Nielsen & Huyen Lyckeskog & Merima Hasani & Hans Theliander, 2021. "Using Isopropanol as a Capping Agent in the Hydrothermal Liquefaction of Kraft Lignin in Near-Critical Water," Energies, MDPI, vol. 14(4), pages 1-17, February.
    14. Yang, Jie & (Sophia) He, Quan & Yang, Linxi, 2019. "A review on hydrothermal co-liquefaction of biomass," Applied Energy, Elsevier, vol. 250(C), pages 926-945.
    15. Déniel, Maxime & Haarlemmer, Geert & Roubaud, Anne & Weiss-Hortala, Elsa & Fages, Jacques, 2016. "Energy valorisation of food processing residues and model compounds by hydrothermal liquefaction," Renewable and Sustainable Energy Reviews, Elsevier, vol. 54(C), pages 1632-1652.
    16. Li, Haowei & Ma, Hongwei & Zhao, Weijie & Li, Xuehui & Long, Jinxing, 2019. "Upgrading lignin bio-oil for oxygen-containing fuel production using Ni/MgO: Effect of the catalyst calcination temperature," Applied Energy, Elsevier, vol. 253(C), pages 1-1.
    17. Ma, Zherui & Wang, Jiangjiang & Feng, Yingsong & Wang, Ruikun & Zhao, Zhenghui & Chen, Hongwei, 2023. "Hydrogen yield prediction for supercritical water gasification based on generative adversarial network data augmentation," Applied Energy, Elsevier, vol. 336(C).
    18. Ahmad, Fiaz & Silva, Edson Luiz & Varesche, Maria Bernadete Amâncio, 2018. "Hydrothermal processing of biomass for anaerobic digestion – A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 98(C), pages 108-124.
    19. Zhao, Weijie & Li, Yingwen & Song, Changhua & Liu, Sijie & Li, Xuehui & Long, Jinxing, 2017. "Intensified levulinic acid/ester production from cassava by one-pot cascade prehydrolysis and delignification," Applied Energy, Elsevier, vol. 204(C), pages 1094-1100.
    20. Kirtika Kohli & Ravindra Prajapati & Brajendra K. Sharma, 2019. "Bio-Based Chemicals from Renewable Biomass for Integrated Biorefineries," Energies, MDPI, vol. 12(2), pages 1-40, January.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:rensus:v:133:y:2020:i:c:s136403212030647x. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/600126/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.