IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v13y2020i18p4864-d414984.html
   My bibliography  Save this article

The Role of Ionic Liquids in the Lignin Separation from Lignocellulosic Biomass

Author

Listed:
  • Isa Hasanov

    (Institute of Technology, Chair of Biosystems Engineering, Estonian University of Life Sciences, Kreutzwaldi 56, 51006 Tartu, Estonia)

  • Merlin Raud

    (Institute of Technology, Chair of Biosystems Engineering, Estonian University of Life Sciences, Kreutzwaldi 56, 51006 Tartu, Estonia)

  • Timo Kikas

    (Institute of Technology, Chair of Biosystems Engineering, Estonian University of Life Sciences, Kreutzwaldi 56, 51006 Tartu, Estonia)

Abstract

Lignin is a natural polymer, one that has an abundant and renewable resource in biomass. Due to a tendency towards the use of biochemicals, the efficient utilization of lignin has gained wide attention. The delignification of lignocellulosic biomass makes its fractions (cellulose, hemicellulose, and lignin) susceptible to easier transformation to many different commodities like energy, chemicals, and materials that could be produced using the biorefinery concept. This review gives an overview of the field of lignin separation from lignocellulosic biomass and changes that occur in the biomass during this process, as well as taking a detailed look at the influence of parameters that lead the process of dissolution. According to recent studies, a number of ionic liquids (ILs) have shown a level of potential for industrial scale production in terms of the pretreatment of biomass. ILs are perspective green solvents for pretreatment of lignocellulosic biomass. These properties in ILs enable one to disrupt the complex structure of lignocellulose. In addition, the physicochemical properties of aprotic and protic ionic liquids (PILs) are summarized, with those properties making them suitable solvents for lignocellulose pretreatment which, especially, target lignin. The aim of the paper is to focus on the separation of lignin from lignocellulosic biomass, by keeping all components susceptible for biorefinery processes. The discussion includes interaction mechanisms between lignocellulosic biomass subcomponents and ILs to increase the lignin yield. According to our research, certain PILs have potential for the cost reduction of LC biomass pretreatment on the feasible separation of lignin.

Suggested Citation

  • Isa Hasanov & Merlin Raud & Timo Kikas, 2020. "The Role of Ionic Liquids in the Lignin Separation from Lignocellulosic Biomass," Energies, MDPI, vol. 13(18), pages 1-24, September.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:18:p:4864-:d:414984
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/13/18/4864/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/13/18/4864/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Chio, Chonlong & Sain, Mohini & Qin, Wensheng, 2019. "Lignin utilization: A review of lignin depolymerization from various aspects," Renewable and Sustainable Energy Reviews, Elsevier, vol. 107(C), pages 232-249.
    2. Raud, M. & Kikas, T. & Sippula, O. & Shurpali, N.J., 2019. "Potentials and challenges in lignocellulosic biofuel production technology," Renewable and Sustainable Energy Reviews, Elsevier, vol. 111(C), pages 44-56.
    3. Wen, Jia-Long & Sun, Shao-Long & Yuan, Tong-Qi & Xu, Feng & Sun, Run-Cang, 2014. "Understanding the chemical and structural transformations of lignin macromolecule during torrefaction," Applied Energy, Elsevier, vol. 121(C), pages 1-9.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Pin, Thaynara C. & Nakasu, Pedro S.Y. & Rabelo, Sarita C. & Costa, Aline C., 2021. "Structural features of protic ionic liquids and their impact on pretreatment performance for 2G ethanol production," Energy, Elsevier, vol. 235(C).
    2. Radhakrishnan, Rokesh & Patra, Pradipta & Das, Manali & Ghosh, Amit, 2021. "Recent advancements in the ionic liquid mediated lignin valorization for the production of renewable materials and value-added chemicals," Renewable and Sustainable Energy Reviews, Elsevier, vol. 149(C).
    3. Małgorzata Hawrot-Paw & Aleksander Stańczuk, 2022. "From Waste Biomass to Cellulosic Ethanol by Separate Hydrolysis and Fermentation (SHF) with Trichoderma viride," Sustainability, MDPI, vol. 15(1), pages 1-10, December.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Yek, Peter Nai Yuh & Cheng, Yoke Wang & Liew, Rock Keey & Wan Mahari, Wan Adibah & Ong, Hwai Chyuan & Chen, Wei-Hsin & Peng, Wanxi & Park, Young-Kwon & Sonne, Christian & Kong, Sieng Huat & Tabatabaei, 2021. "Progress in the torrefaction technology for upgrading oil palm wastes to energy-dense biochar: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 151(C).
    2. Liu, Ruo-Ying & Lan, Hai-Na & Liu, Zhi-Hua & Li, Bing-Zhi & Yuan, Ying-Jin, 2024. "Microbial valorization of lignin toward coumarins: Challenges and perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 191(C).
    3. Artem A. Medvedev & Daria A. Beldova & Konstantin B. Kalmykov & Alexey V. Kravtsov & Marina A. Tedeeva & Leonid M. Kustov & Sergey F. Dunaev & Alexander L. Kustov, 2022. "Carbon Dioxide Assisted Conversion of Hydrolysis Lignin Catalyzed by Nickel Compounds," Energies, MDPI, vol. 15(18), pages 1-12, September.
    4. Ko, Ja Kyong & Lee, Jae Hoon & Jung, Je Hyeong & Lee, Sun-Mi, 2020. "Recent advances and future directions in plant and yeast engineering to improve lignocellulosic biofuel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 134(C).
    5. Mayank Patel & Nick Hill & Charles A. Mullen & Sampath Gunukula & William J. DeSisto, 2020. "Fast Pyrolysis of Lignin Pretreated with Magnesium Formate and Magnesium Hydroxide," Energies, MDPI, vol. 13(19), pages 1-10, September.
    6. Djukić-Vuković, A. & Mladenović, D. & Ivanović, J. & Pejin, J. & Mojović, L., 2019. "Towards sustainability of lactic acid and poly-lactic acid polymers production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 108(C), pages 238-252.
    7. Zhao, Xuebing & Wen, Jialong & Chen, Hongmei & Liu, Dehua, 2018. "The fate of lignin during atmospheric acetic acid pretreatment of sugarcane bagasse and the impacts on cellulose enzymatic hydrolyzability for bioethanol production," Renewable Energy, Elsevier, vol. 128(PA), pages 200-209.
    8. Abdul Waheed & Salman Raza Naqvi & Imtiaz Ali, 2022. "Co-Torrefaction Progress of Biomass Residue/Waste Obtained for High-Value Bio-Solid Products," Energies, MDPI, vol. 15(21), pages 1-20, November.
    9. Therasme, Obste & Volk, Timothy A. & Fortier, Marie-Odile & Kim, Youngwoon & Wood, Christopher D. & Ha, HakSoo & Ali, Atif & Brown, Tristan & Malmsheimer, Robert, 2022. "Carbon footprint of biofuels production from forest biomass using hot water extraction and biochemical conversion in the Northeast United States," Energy, Elsevier, vol. 241(C).
    10. Liu, Zhijia & Hu, Wanhe & Jiang, Zehui & Mi, Bingbing & Fei, Benhua, 2016. "Investigating combustion behaviors of bamboo, torrefied bamboo, coal and their respective blends by thermogravimetric analysis," Renewable Energy, Elsevier, vol. 87(P1), pages 346-352.
    11. Liu, Tian & Wang, Peipei & Tian, Jing & Guo, Jiaqi & Zhu, Wenyuan & Bushra, Rani & Huang, Caoxing & Jin, Yongcan & Xiao, Huining & Song, Junlong, 2024. "Emerging role of additives in lignocellulose enzymatic saccharification: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 197(C).
    12. Ghiasi, Bahman & Kumar, Linoj & Furubayashi, Takaaki & Lim, C. Jim & Bi, Xiaotao & Kim, Chang Soo & Sokhansanj, Shahab, 2014. "Densified biocoal from woodchips: Is it better to do torrefaction before or after densification?," Applied Energy, Elsevier, vol. 134(C), pages 133-142.
    13. Tran, Khanh-Quang & Bach, Quang-Vu & Trinh, Thuat T. & Seisenbaeva, Gulaim, 2014. "Non-isothermal pyrolysis of torrefied stump – A comparative kinetic evaluation," Applied Energy, Elsevier, vol. 136(C), pages 759-766.
    14. Fan, Meishan & Li, Jun & Liu, Zhu & Li, Caiqun & Zhang, Hongdan & Xie, Jun & Chen, Yong, 2023. "Evaluating performance of CrCl3-catalyzed ethanol pretreatment of poplar on cellulose conversion," Renewable Energy, Elsevier, vol. 216(C).
    15. Mostafa, Mohamed E. & Hu, Song & Wang, Yi & Su, Sheng & Hu, Xun & Elsayed, Saad A. & Xiang, Jun, 2019. "The significance of pelletization operating conditions: An analysis of physical and mechanical characteristics as well as energy consumption of biomass pellets," Renewable and Sustainable Energy Reviews, Elsevier, vol. 105(C), pages 332-348.
    16. Yiquan Zhao & Le Xue & Zhiyi Huang & Zixian Lei & Shiyu Xie & Zhenzhen Cai & Xinran Rao & Ze Zheng & Ning Xiao & Xiaoyu Zhang & Fuying Ma & Hongbo Yu & Shangxian Xie, 2024. "Lignin valorization to bioplastics with an aromatic hub metabolite-based autoregulation system," Nature Communications, Nature, vol. 15(1), pages 1-17, December.
    17. Adeleke, Adekunle A. & Ikubanni, Peter P. & Emmanuel, Stephen S. & Fajobi, Moses O. & Nwachukwu, Praise & Adesibikan, Ademidun A. & Odusote, Jamiu K. & Adeyemi, Emmanuel O. & Abioye, Oluwaseyi M. & Ok, 2024. "A comprehensive review on the similarity and disparity of torrefied biomass and coal properties," Renewable and Sustainable Energy Reviews, Elsevier, vol. 199(C).
    18. Yang, Pan & Cai, Ximing & Hu, Xinchen & Zhao, Qiankun & Lee, Yuanyao & Khanna, Madhu & Cortés-Peña, Yoel R. & Guest, Jeremy S. & Kent, Jeffrey & Hudiburg, Tara W. & Du, Erhu & John, Steve & Iutzi, Fre, 2022. "An agent-based modeling tool supporting bioenergy and bio-product community communication regarding cellulosic bioeconomy development," Renewable and Sustainable Energy Reviews, Elsevier, vol. 167(C).
    19. Rudolfsson, Magnus & Stelte, Wolfgang & Lestander, Torbjörn A., 2015. "Process optimization of combined biomass torrefaction and pelletization for fuel pellet production – A parametric study," Applied Energy, Elsevier, vol. 140(C), pages 378-384.
    20. Yang, Yang & Sun, Mingman & Zhang, Meng & Zhang, Ke & Wang, Donghai & Lei, Catherine, 2019. "A fundamental research on synchronized torrefaction and pelleting of biomass," Renewable Energy, Elsevier, vol. 142(C), pages 668-676.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:13:y:2020:i:18:p:4864-:d:414984. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.